Chiang Mai Journal of Science, Faculty of Science, Chiang Mai University

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Cathodic Stripping Voltammetric Procedure for Determination of Some Inorganic Arsenic Species in Water, Soil and Ores Samples

Paper Type	Contributed Paper
Title	Cathodic Stripping Voltammetric Procedure for Determination of Some Inorganic Arsenic Species in Water, Soil and Ores Samples
Author	Jaroon Junsomboon, Ponlayuth Sooksamiti, Kate Grudpan, Somchai Lapanantnoppakhun, Prasak Thavornyuth
Email	scijjkmn@chiangmai.ac.th
Abstract: Square wave cathodic stripping voltammetry was developed for determination of As(III) and/or As(V) in water, soil, and ore samples. The method was based on electrodeposition of As(III) on a hanging mercury drop electrode (HMDE) as a copper-arsenic intermetallic compound, which was further reduced to arsine at a higher negative potential in the stripping step. Deposition was performed in an electrolyte solution of 1 M HCl with 10 mg L^-1Cu(II), by applying a constant potential of -0.40 V vs Ag/AgCl to the HMDE for 60 s at a stirring rate of 2,000 rpm. Stripping step was carried out by applying a square wave waveform in the potential range from -0.40 to -1.00 V. A voltammogram was obtained with peak potential at -0.78 V giving peak current linearly proportional to As(III) concentration up to 50 μg L-1 The concentration of Cu(II) and deposition time were interrelated affecting. the sensitivity of arsenic determination. With a fixed deposition time of 60 s, a narrow concentration range of Cu(II), 5-10 mg L^-1gave the highest sensitivity. Standard addition method was applied for quantification in order to account for effect of sample matrix. The detection limit of the method was 0.3 μg L^-1 As(III) and the relative standard deviation for 5 μg L^-1 As(III) (n =11) was 3.6%. As(V) concentration was determined after reduction to As(III) by using 80 mg L^-1 of thiosulfate. The developed method was applied to the analysis of water, soil, ores leachate and ores digest samples. The results were in good agreement with those obtained by HG-AAS method and the certified value of soil certified reference material. Recoveries in range of 83-108% were obtained for water samples. The proposed method is simple, convenient, and low reagent consumption.
Start & End Page	369 - 383
Received Date	2009-01-12
Revised Date
Accepted Date	2009-04-30
Full Text	Download
Keyword	cathodic stripping voltammetry, CSV, square wave, arsenic, water, soil, ores
Volume	Vol.36 No.3 (SEPTEMBER 2009)
DOI
Citation	Junsomboon J., Sooksamiti P., Grudpan K., Lapanantnoppakhun S. and Thavornyuth P., Cathodic Stripping Voltammetric Procedure for Determination of Some Inorganic Arsenic Species in Water, Soil and Ores Samples, Chiang Mai Journal of Science, 2009; 36(3): 369-383.
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Author:Natthawud Dussadee, Rameshprabu Ramaraj and Nyanakorn Sutassanamarlee
Vol.45 No.1 (January 2018) View: 629 Download:328

Optimizing NaCl and KNO3 Concentrations for High b-carotene Production in Photobioreactor by Dunaliella salina KU11 Isolated from Saline Soil Sample
page: 106 - 115
Author:Ramaraj Sathasivam, Piyawat Pongpadung, Jantana Praiboon, Anong Chirapart, Savitr Trakulnaleamsai, Sittiruk Roytrakul and Niran Juntawong
Vol.45 No.1 (January 2018) View: 720 Download:296

Selection of Coagulant with Consideration of Sludge Characteristics for Treatment of Industrial Wastewater Containing High Strength Mixed Surfactants
page: 1654 - 1668
Author:Tongchai Sriwiriyarat*, Rapeepan Wongvian and Sinchai Kuhakaew
Vol.44 No.4 (October 2017) View: 680 Download:384

Subcritical Water Extraction Technique for Selective Extraction of Pentacyclic Triterpenoids from Dry Loquat (Eriobotrya japonica) Leaves
page: 1534 - 1547
Author:Erasto Mlyuka, Shuang Zhang, Zongping Zheng, Zhiyong He, Maomao Zeng, Martha Mbifile and Jie Chen*
Vol.44 No.4 (October 2017) View: 702 Download:301

Comparative analysis of protein profiles of toxic and non-toxic Jatropha curcas latex
page: 1379 - 1391
Author:Lucsame Gurnecka, Eleni Gentekakia, Janthima Jaresitthikunchaib, Teerawit Waratrujiwonga, Sittiruk R
Vol.44 No.4 (October 2017) View: 636 Download:395

Use of Benthic Macroinvertebrates as Bioindicators of Anthropogenic Impacts on Water Quality of Mae Klong River, Western Thailand
page: 1356 - 1366
Author:Songyot Kullasoot, Piyamas Intrarasattayapong and Chitchol Phalaraksh*
Vol.44 No.4 (October 2017) View: 1,207 Download:409

Effectiveness of Granular Activated Carbon for Removal of Sulfamethoxazole during Ozonation
page: 1040 - 1048
Author:Javaid Akhtar, NorAishah Saidina Amin* and Muhammad Usman Rashid
Vol.44 No.3 (July 2017) View: 706 Download:150

Nickel-catalyzed One-pot, Three-component Synthesis of 3,4-Disubstituted Isoxazole-5(4H)-ones in Aqueous Medium
page: 1011 - 1021
Author:Hamzeh Kiyani* and Heshmat Allah Samimi
Vol.44 No.3 (July 2017) View: 730 Download:255

An Expeditious and Green Synthesis of 3,3¢-(Arylmethylene)-bis-(4-hydroxycoumarins) Catalyzed by 5-Sulfosalicylic Acid
page: 1002 - 1010
Author:Hamzeh Kiyani* and Hassan Darbandi
Vol.44 No.3 (July 2017) View: 718 Download:191

Hydrolysis of Konjac Flour under Subcritical Water Conditions
page: 988 - 992
Author:Pramote Khuwijitjaru*, Intira Koomyart, Takashi Kobayashi and Shuji Adachi
Vol.44 No.3 (July 2017) View: 858 Download:453

Diversity of Polychaetes in Mangrove Forest, Prasae Estuary, Rayong Province, Thailand
page: 816 - 823
Author:Somtawin Jaritkhuan*, Pongrat Damrongrojwattana, Benchawan Chewprecha and Vichaya Kunbou
Vol.44 No.3 (July 2017) View: 1,080 Download:295

Detection of Bacterial Communities in Volatile-organic-compound (VOC)-contaminated Soil in an Industrial Estate in Eastern Thailand by PCR-DGGE Analysis
page: 742 - 750
Author:Manatsawat Sriwichai, Fairda Malem, Mujalin K. Pholchan and Sakunnee Bovonsombut*
Vol.44 No.3 (July 2017) View: 727 Download:245

Detection of Helicobacter pylori in Aquatic Environments and Drinking Waters in Northeastern Thailand
page: 731 - 741
Author:Chariya Chomvarin*, Warawan Wongboot, Aschana Tirapattanun, Sakawrat Kanthawong, Suwin Wongwajana,
Vol.44 No.3 (July 2017) View: 654 Download:403

Assessment of Indicator Microorganisms and Fungi: Health Risk in the Saen Saeb Canal, Thailand
page: 309 - 321
Author:Onanong Pringsulaka* [a], Nuttika Suwannasai [a], Sirinthorn Sunthornthummas [b], Sukhumaporn Krajan
Vol.44 No.2 (April 2017) View: 669 Download:534

Geological Mapping and Multi-Electrode Resistivity Survey for Potential Groundwater Exploration in Ayer Lanas Village and Its Surroundings, Jeli District, Kelantan, Malaysia
page: 1335 - 1345
Author:Dony Adriansyah Nazaruddin*, ZafirahSakinah Amiruzan, Hamzah Hussin, Mohammad Muqtada Ali Khan,...
Vol.43 No.6 (SPECIAL ISSUE 2) View: 666 Download:391

Removal of Microcystin from Lake Water Using an Internal Airlift Loop Ceramic Honeycomb Support Bioreactor
page: 1048 - 1058
Author:Theerasak Somdee* [a], Anchana Somdee [a], John Ruck [b], Margaret Allison [b] and Rachel Page [b]
Vol.43 No.5 (OCTOBER 2016) View: 621 Download:649

Cultivation of Arthrospira (Spirulina) platensis Using Low Cost Medium Supplemented with Lac Wastewater
page: 1037 - 1047
Author:Pamon Pumas* [a] and Chayakorn Pumas [b,c]
Vol.43 No.5 (OCTOBER 2016) View: 670 Download:362

Forensic Soil Investigation from the 16S rDNA Profiles of Soil Bacteria Obtained by Denaturing Gradient Gel Electrophoresis
page: 748 - 755
Author:Anothai Sanachai [a], Somporn Katekeaw [b] and Khemika Lomthaisong [a]*
Vol.43 No.4 (JULY 2016) View: 659 Download:406

Physical and Mechanical Properties of Zirconia Toughened Alumina (ZTA) Composites Fabricated by Powder Injection Moulding
page: 375 - 380
Author:Nutthita Chuankrerkkul*[a], Kritkaew Somton [b], Thassanee Wonglom [b], Kannigar Dateraksa [b] and P
Vol.43 No.2 (SPECIAL ISSUE 1) View: 664 Download:342

Spectroscopic Properties of Lithium Borate Glass Material with Neodymium Ions
page: 311 - 319
Author:Yogesh Kumar Sharma, Rajendra Prasad Joshi, Sudha Pal and Priyanka Goyal
Vol.43 No.2 (SPECIAL ISSUE 1) View: 7,732 Download:529

Development of Statistical Models for Maximum Daily Rainfall in Upper Northern Region of Thailand
page: 1044 - 1053
Author:Manad Khamkong*[a] and Putipong Bookkamana[a]
Vol.42 No.4 (OCTOBER 2015) View: 704 Download:256

Soil-gas Thoron Concentration Associated with Seismic Activity
page: 972 - 979
Author:Hari Prasad Jaishi [a], Sanjay Singh [a], Raghavendra Prasad Tiwari [b] and Ramesh Chandra Tiwari*
Vol.42 No.4 (OCTOBER 2015) View: 698 Download:227

Toxic Algae as a Component of Phytoplankton in Irrigation Canals (Thailand)
page: 560 - 577
Author:Sirikhae Pongswat and Sutthawan Suphan
Vol.42 No.3 (JULY 2015) View: 583 Download:260

Detention Time Study of Algal Biomass Production with Natural Water Medium
page: 549 - 559
Author:Rameshprabu Ramaraj, David Da-Wei Tsai and Paris Honglay Chen
Vol.42 No.3 (JULY 2015) View: 649 Download:223

Effect of Solvent and Processing Parameters on Electrospun Polyvinylpyrrolidone Ultra-fine Fibers
page: 436 - 442
Author:Thammasit Vongsetskul, Thanaphorn Chantarodsakun, Preeyaphorn Wongsomboon, Ratth Rangk
Vol.42 No.2 (APRIL 2015) View: 708 Download:210

Application of Cloud Point Extraction for the Determination of Manganese (II) in Water Samples
page: 417 - 428
Author:Shahram. Nekouei, Farzin.Nekouei
Vol.42 No.2 (APRIL 2015) View: 653 Download:224

Moult in the Stripe-throated Bulbul, Pycnonotus finlaysoni: sexual differences and timing
page: 339 - 348
Author:Somboon Kamtaeja, Chatmongkol Suwannapoom, Narit Sitasuwan and Siriwadee Chomdej
Vol.42 No.2 (APRIL 2015) View: 642 Download:206

Above- and Below-Ground Ectomycorrhizal Diversity in a Pine-Oak Forest in Northeastern Thailand
page: 79 - 87
Author:Preeyaporn Dokmai, Cherdchai Phosri, Rungpetch Khangrang, Nuttika Suwannasai
Vol.42 No.1 (JANUARY 2015) View: 642 Download:228

Enhanced Production of Polysaccharides and Protein Content in Cyanobacterium, Oscillatoria limnetica as a Defense Mechanism Against Low pH and Pb2+
page: 34 - 43
Author:Suneerat Ruangsomboon*
Vol.42 No.1 (JANUARY 2015) View: 1,076 Download:194

Diversity, New and Rare Taxa of Pediastrum spp. in Some Freshwater Resources in Thailand
page: 1065 - 1076
Author:Tippawan Prasertsin, Jeeraporn Pekkoh, Wasu Pathom- aree and Yuwadee Peerapornpisal*
Vol.41 No.5/1 (OCTOBER 2014) View: 634 Download:148

A Novel Moisturizer Extracted from Freshwater Macroalga [Rhizoclonium hieroglyphicum (C.Agardh) Kützing] for Skin Care Cosmetic
page: 1195 - 1207
Author:Pimporn Leelapornpisid, Lapatrada Mungmai, Busabun Sirithunyalug, Supat Jiranusornkul and Yuwadee Peerapornpisal
Vol.41 No.5/2 (OCTOBER 2014) View: 734 Download:349

Spatial Distribution of Wood-Decaying Fungi in an Old-Growth Temperate Forest
page: 822 - 837
Author:Yu-Lian Wei, Hai-Sheng Yuan, Xu-Gao Wang and Wen-Min Qin
Vol.41 No.4 (SPECIAL ISSUE 1) View: 623 Download:263

Phytoplankton as a Bio-indicator of Water Quality in the Freshwater Fishing Area of Pak Phanang River Basin (Southern Thailand)
page: 344 - 355
Author:Amphorn Sakset* [a] and Wanninee Chankaew* [b]
Vol.40 No.3 (JULY 2013) View: 665 Download:288

Production of Probiotics Streptomyces Biomass from Starchy Wastewater
page: 294 - 298
Author:Suteera Srisamai, Phonlawat Srikhampa, and Wasu Pathom-aree*
Vol.40 No.2 (APRIL 2013) View: 1,102 Download:192

Characteristics of Phosphate Solubilization by Phosphate-Solubilizing Bacteria Isolated from Agricultural Chili Soil and Their Efficiency on the Growth of Chili (Capsicum frutescens L. cv. Hua Rua)
page: 11 - 25
Author:Worapon Surapat[a], Charida Pukahuta[a], Pongsak Rattanachaikunsopon[a], Tadanori Aimi[b], and Sopho
Vol.40 No.1 (JANUARY 2013) View: 662 Download:257

Investigation of Horizontal Sightline Offset on Horizontal Curves in Hyrcanian Forest Roads
page: 639 - 647
Author:Mehran Nasiri [a]*
Vol.39 No.4 (OCTOBER 2012) View: 737 Download:173

Weather Research and Forecasting (WRF) Model Performance for a Simulation of the 5 November 2009 Heavy Rainfall over Southeast of Thailand
page: 511 - 523
Author:Sukrit Kirtsaeng*[a,b],JiemjaiKreasuwun[b], Somporn Chantara[a], Supap Kirtsaeng[c],Pattara Sukthawe
Vol.39 No.3 (JULY 2012) View: 616 Download:272

Seasonal and Post-Rainfall Dynamics of Soil CO2 Efflux in Wheat and Peanut Fields
page: 410 - 428
Author:Chompunut Chayawat*[a], Chuckree Senthong[a], Monique Y.Leclerc[b], Gengsheng Zhang[b] and John P. B
Vol.39 No.3 (JULY 2012) View: 601 Download:246

Anti-gastric ulcer and acute oral toxicity of aqueous extract of Turbinaria conoides from the Gulf of Thailand
page: 292 - 299
Author:Walailuck Boonchum[a], Panmuk Vacharapiyasophon[a], Duangta Kanjanapothi[b], Jeeraporn Pekkoh[a], Do
Vol.39 No.2 (APRIL 2012) View: 639 Download:220

Stability of Vancomycin 31 mg/mL in Extemporaneous Eye Drops Determined with Capillary Electrophoresis
page: 533 - 540
Author:Anutra Khangtragool, Sineenart Santidherakul and Phuriwat Leesawat
Vol.38 No.4 (OCTOBER 2011) View: 728 Download:375

Water Quality and Trophic Status in Main Rivers of Thailand
page: 280 - 294
Author:Pongpan Leelahakriengkrai*[a] and Yuwadee Peerapornpisal [a,b]
Vol.38 No.2 (APRIL 2011) View: 650 Download:414

Composite Poly(ethylene oxide) Electrolyte Modified with Ethanol for Dye-sensitized Solar Cells
page: 223 - 230
Author:Voranuch Somsongkul [a], Chaiyuth Saekung [b], San H. Thang [c], Atchana Wongchaisuwat [a] and Mari
Vol.38 No.2 (APRIL 2011) View: 738 Download:189

Influence of Seasonality on the Occurrence of Myxomycetes
page: 71 - 84
Author:Thida Win Ko Ko, Steven L. Stephenson, Kevin D. Hyde, and Saisamorn Lumyong
Vol.38 No.1 (JANUARY 2011) View: 1,092 Download:186

Moisture Enhancement of Niosomes Entrapped with Mineral Water in Pig Ear Skin
page: 126 - 138
Author:Aranya Manosroi, Walailak Witkittilak, Romchat Chutoprapat, Hiroaki Todo, Kenji Sugibayashi, Worapak
Vol.38 No.1 (JANUARY 2011) View: 634 Download:183

Ethnobotanical Studies in Muslim Thai Communities Located Around Toh-Daeng Peat Swamp Forest in Thailand
page: 157 - 170
Author:Ubonwan Upho* [a], Chusie Trisonthi [b] and Kongkanda Chayamarit [c]
Vol.31 No.2 May 2004 View: 721 Download:242

Performance of Giant Freshwater Prawn (Macrobrachium rosenbergii de Man) Reared in Earthen Ponds Beneath Plastic Film Shelters
page: 89 - 96
Author:Niwooti Whangchai, Thepparath Ungsethaphand, Chanagun Chitmanat, Kriangsak Mengumphan and Supattra
Vol.34 No.1 (JANUARY 2007) View: 630 Download:227

Vulnerability Assessment of Groundwation Resources, Chinag Mai Basin
page: 73 - 78
Author:Terdsak Subtavewung, and Fongsaward S. Singharajwarapan
Vol.34 No.1 (JANUARY 2007) View: 674 Download:292

Effect of Nitrogen and Phosphorus on the Dynamics of Blue-green Algae in the Mae Ngat Somboonchol Reservoir, Chiang Mai, Thailand
page: 253 - 268
Author:Khajornkiat Saeton, and Siripen Traichaiyaporn
Vol.34 No.2 (MAY 2007) View: 644 Download:214

Proteomic Analysis of Bradyrhizobium japonicum USDA110 in Acidic Condition
page: 335 - 345
Author:Napat Puranamaneewiwat [a,b] Shigeyuki Tajima [c] and Hataichanoke Niamsup* [b]
Vol.33 No.3 (SEPTEMBER 2006) View: 684 Download:190

Estimation of Water Content in PEM Fuel Cell
page: 212 - 220
Author:Chinnavat Thawornkuno and Chanin Panjapornpon
Vol.35 No.1 (JANUARY 2008) View: 627 Download:906

Applying of Aluminium Deoxidation in Iron Roll Casting
page: 196 - 198
Author:Teerapong Harnwirojkul, Mana Polboon, John Pearce and Thanaporn Korad
Vol.35 No.1 (JANUARY 2008) View: 641 Download:255

Extraction of Phenolic Compounds from Fruits of Bitter Melon (Momordica charantia ) with Subcritical Water Extraction and Antioxidant Activities of These Extracts
page: 123 - 130
Author:Parichat Budrat and Artiwan Shotipruk
Vol.35 No.1 (JANUARY 2008) View: 663 Download:421

Value Added Products from By-products of Rice Bran Oil Processing
page: 116 - 122
Author:Wasinee Kaewboonnum, Ketmanee Wachararuji and Artiwan Shotipruk
Vol.35 No.1 (JANUARY 2008) View: 677 Download:212

Subcritical Water Extraction of Polyphenolic Compounds from Terminalia chebula Fruits
page: 103 - 108
Author:Rangsriwong P., Rangkadilok N., and Shotipruk A
Vol.35 No.1 (JANUARY 2008) View: 629 Download:193

Biosorption of Lead (II) and Copper (II) from Aqueous Solution
page: 69 - 81
Author:Woranart Jonglertjunya
Vol.35 No.1 (JANUARY 2008) View: 663 Download:211

Proteomic Study of Recombinant Escherichia coli Expressing Beauveria bassiana Chitinase Gene
page: 324 - 330
Author:Khemika Lomthaisong, Kanchanit Boonmaleerat and Aphinya Wongpia
Vol.35 No.2 (MAY 2008) View: 672 Download:173

Proteomic Analysis of Deglycosylated Proteins in Normal Human Serum Using Anhydrous Hydrogen Fluoride Treatment
page: 311 - 323
Author:Supawadee Sriyam, Supachok Sinchaikul, Payungsak Tantipaiboonwong, Suree Phutrakul and Shui-Tein Che
Vol.35 No.2 (MAY 2008) View: 672 Download:202

Developing Indicators for Floodplain Wetlands: Managing Water in Agricultural Landscapes
page: 224 - 235
Author:Kim Jenkins, Richard Kingsford, and Darren Ryder
Vol.36 No.2 (MAY 2009) View: 656 Download:236

Treatment of Fermented Fish Production Wastewater by Constructed Wetland System in Thailand
page: 149 - 157
Author:Suwasa Kantawanichkul, Seni Karnchanawong, and Shuh Ren Jing
Vol.36 No.2 (MAY 2009) View: 676 Download:246

Fertility Evaluation of Old Meghna River Floodplain Soils in Bangladesh for Sustainable Agriculture
page: 127 - 137
Author:Md. Mizanur Rahman* and Mohammad G. Azam
Vol.32 No.2 (MAY 2005) View: 649 Download:268

Calculation of Weighted Averages Approach for the Estimation of Ping Tolerance Values
page: 151 - 159
Author:Somyot Silalom, James L. Carter, and Porntip Chantaramongkol
Vol.37 No.1 (JANUARY 2010) View: 660 Download:176

Immunoproteomic Assay of Streptococcus suis Serotype 2 Isolated from Patients
page: 134 - 150
Author:Kanruethai Wongsawan, Aphinya Wongpia, Khemika Lomthaisong, Anuson Boonthum, Volaluck Supjatura, and
Vol.37 No.1 (JANUARY 2010) View: 663 Download:236

Aggregation and Pedogenesis of Seasonally Inundated Soils of a Tropical Watershed
page: 74 - 84
Author:Emmanuel U. Onweremadu, Ogochukwu P. Izuogu, and Frank O.R. Akamigbo
Vol.37 No.1 (JANUARY 2010) View: 684 Download:217

Concentrations of Arsenic in Water, Soil, Hair, and Biological Samples in Hizla, Bangladesh
page: 7 - 13
Author:Abu Sayed Md. Kamal* and Preeda Parkpian
Vol.29 No.1 (APRIL 2002) View: 669 Download:249

Fifty One New Record Species of Freshwater Diatoms in Thailand
page: 97 - 112
Author:Trai Pekthong and Yuwadee Peerapornpisal
Vol.28 No.2 (DECEMBER 2001) View: 671 Download:215

Solid Phase Extraction of Carbamate and Organochlorine Pesticides in Water
page: 9 - 15
Author:Wanna Kanchanamayoon, Sirichai Hathongkam and Amnat Laothong
Vol.28 No.1 (JUNE 2001) View: 647 Download:247

Benthic Macroinvertebrates Diversity and Water Quality of Some Main Wetlands in Chiang Mai-Lamphun Basin
page: 102 - 113
Author:Weerasak Roongruangwongse [a], Pongpor Asnachinda [b] and Wanchai Sonthichai [a]
Vol.27 No.2 (DECEMBER 2000) View: 662 Download:188

Population Dynamics of the Green-Lipped Mussel, Perna viridis from the Offshore Waters of Naf River Coast, Bangladesh
page: 344 - 354
Author:Mohammed A.A. Khan, Zaini B. Assim, and Norhadi Ismail
Vol.37 No.2 (MAY 2010) View: 689 Download:236

Diversity of Arbuscular Mycorrhizal Fungi in Mimosa invisa and Effect of the Soil pH on the Symbiosis
page: 517 - 527
Author:Saengdao Kittiworawat, Somchit Youpensuk, and Benjavan Rerkasem
Vol.37 No.3 (SEPTEMBER 2010) View: 668 Download:211

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Cathodic Stripping Voltammetric Procedure for Determination of Some Inorganic Arsenic Species in Water, Soil and Ores Samples

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