Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

1,647
Articles
Q3 0.80
Impact Factor
Q3 1.3
CiteScore
7 days
Avg. First Decision
Outline
Figures and Tables
ARTICLE METRICS
Views 1,873
Downloads 640

Water-based Synthesis of MIL-53(Al) at Room Temperature: An Effective Adsorbent for Oxytetracycline (OTC) Antibiotic Removal from Water

Parnuch Hongsawat, Phuri Kalnaowakul and Panida Prarat
* Author for corresponding; e-mail address: panida.p@sciee.kmutnb.ac.th
Volume: Vol.51 No.1 (January 2024)
Research Article
DOI: https://doi.org/10.12982/CMJS.2024.010
Received: 11 July 2023, Revised: 21 December 2023, Accepted: 28 December 2023, Published: -

Citation: Hongsawat P., Kalnaowakul P. and Prarat P., Water-based synthesis of MIL-53(Al) at room temperature: An effective adsorbent for oxytetracycline (OTC) antibiotic removal from water, Chiang Mai Journal of Science, 2024; 51(1): e2024010. DOI 10.12982/CMJS.2024.010.

Abstract

     MIL-53(Al), a flexible metal-organic framework, was synthesized by a facile method through a water-based method at room temperature, aligning with the principles of green chemistry. The objective was to investigate its effectiveness in removing pharmaceuticals and personal care products (PPCPs), specifically focusing on oxytetracycline (OTC). Our findings revealed that MIL-53(Al) possesses a structure with both micropores and mesopores, with a specific surface area of 916 m2/g. MIL-53(Al) notably exhibited a higher OTC adsorption capacity than commercially available powder activated carbon (PAC). The adsorption kinetics followed a pseudo-second-order model, while the Langmuir model accurately described the experimental isotherms for OTC adsorption. MIL-53(Al) outperformed previously reported MOF-based adsorbents with a maximum of 1005 mg/g capacity at pH 7. The flexible structure induces a breathing effect that significantly improves intraparticle diffusion for OTC, contributing to its adsorption efficiency. The adsorption of OTC was influenced by the solution pH, the acid dissociation constants of OTC, and the charged surface of the adsorbent. Pore filling, hydrogen bonding, π-π interaction, electrostatic interaction, and hydrophobic interaction were all associated with the adsorptive interaction between OTC and MIL-53(Al). The MIL-53(Al) also demonstrated good regeneration and reuse, with just a little decreased adsorption capacity after three reuse cycles. These findings indicate that green material MIL-53(Al) has the potential to be an effective adsorbent for removing OTC from water matrices.

Keywords: adsorption, oxytetracycline antibiotic, metal-organic framework, MIL-53(Al), water-based synthesis

Related Articles

Adsorption Performance of Spherical Porous SiO2 on Heavy Metal Cu2+ in Wastewater
DOI: 10.12982/CMJS.2025.075.

Yan-Min Chen, Zhen-Zhen Chen, Bei-Bei Qi, Ye-Xuan Cai, Jia-Meng Li and Yi-Fan Han

Vol.52 No.5 (September 2025)
Research Article View: 1,345 Download: 113
Barite Adsorption Efficiency for Removal of Mannose. Experimental Measurements and Equilibrium Study
DOI: 10.12982/CMJS.2025.034.

Mustafa Jaip Allah Abdelmageed Abualreish

Vol.52 No.3 (May 2025)
Research Article View: 578 Download: 262
A Rhizobacterium Kitasatospora nipponensis Demonstrates Antifungal Activity against Basal Stem Rot Disease and Promotes Plant Growth in Oil Palm (Elaeis guineensis) Seedlings
DOI: 10.12982/CMJS.2025.033.

Anurag Sunpapao, Supaporn Pithakkit and Prisana Wonglom

Vol.52 No.3 (May 2025)
Research Article View: 970 Download: 347
Removal of Chromium (III) Heavy Metal Ions from Aqueous Solutions by Green Synthesized Calix[6]arene
DOI: 10.12982/CMJS.2025.005.

Susy Yunita Prabawati, Nina Hamidah and Afifah Mufidati

Vol.52 No.1 (January 2025)
Research Article View: 916 Download: 375
H2S Removal from Biogas using Steel Wool (Fe2O3) Adsorption Combined with Water Absorption: Experimental and Modelling via RSM
DOI: 10.12982/CMJS.2024.027.

Jiraporn Paoaiang, Prukraya Pongyeela, Nirana Chairerk and Juntima Chungsiriporn

Vol.51 No.2 (March 2024)
Research Article View: 1,699 Download: 1,732
Development and Optimization of an Amperometric Bi-enzyme Biosensor for Aspartame Determination
DOI: 10.12982/CMJS.2023.064.

Tanaporn Tangtawewipat and Saipin Thanachasai

Vol.50 No.6 (November 2023)
Research Article View: 1,390 Download: 588
Preparation of Porous Silica Nanoparticles by Chemical Etching for Removal of Paraquat from Aqueous Solution
DOI: 10.12982/CMJS.2023.009.

Kanokwan Darasoon, Supawitch Hoijang, Tanapong Kunakham, Sorapong Janhom, Supon Ananta, Gyu Leem and Laongnuan Srisombat

Vol.50 No.1 (January 2023)
Research Article View: 1,763 Download: 1,203
Hydrochar from Lansium domesticum and Salacca zalacca Peel as Adsorbent on Rhodamine-B Removal: Adsorption Process and Regeneration Studies
DOI: 10.12982/CMJS.2022.108.

Mauizatul Hasanah, Alfan Wijaya, Risfidian Mohadi, Fitri Suryani Arsyad and Aldes Lesbani

Vol.49 No.6 (November 2022)
Research Article View: 1,791 Download: 452
2-Methylimidazole-modified Iron Metal-organic Framework as an Efficient Methylene Blue Adsorbent
DOI: 10.12982/CMJS.2022.104.

Yingxin Zhao, Hao Hu, Shengyu Zhang, Shiya Feng, Yun Yang, Xiongjian Li and Shuijin Yang

Vol.49 No.6 (November 2022)
Research Article View: 1,751 Download: 489
Process Optimization and Modeling of Low-cost Activated Carbon Preparation and Its Application in Chromium(VI) Removal
DOI: 10.12982/CMJS.2022.100.

Theeradit Phothitontimongkol and Kanyarak Prasertboonyai

Vol.49 No.6 (November 2022)
Research Article View: 1,652 Download: 537
Sorption Studies of Cesium on Kunipia-F Bentonite and Silicon Dioxide
DOI: 10.12982/CMJS.2022.093.

Anan O-Manee, Youichi Enokida and Kayo Sawada

Vol.49 No.5 (September 2022)
Research Article View: 1,757 Download: 644
Cigarette Butts Valorization: Activated Hydrochar for Methylene Blue Removal
DOI: 10.12982/CMJS.2022.062.

Naphatsarnan Phasukarratchai, Budsarin Yattipat, Parichat Muengkrajang, Sasishai Permpoon and Alissara Reungsang

Vol.49 No.4 (July 2022)
Research Article View: 2,011 Download: 1,305
Non-Covalent Interactions between Graphene and Cluster of Ruthenium Oxides and Vanadium Oxides : A Dispersioncorrected Density Functional Theory Study
page: 1606 - 1619

Paphawarin Kheownil, Parameat Seesopha, Sawitree Chuaychoocherd, Panichakorn Jaiyong and Yuthana Tantirungrotechai

Vol.48 No.6 (November 2021)
Research Article View: 1,694 Download: 944
Density Functional Theory Study of Methane Adsorption on LaCoO3 (001) Surface
page: 1645 - 1656

Xuefeng Wang, Hongyan Zhang,Cunbao Deng, Ling Qiao and Shuangli Du

Vol.48 No.6 (November 2021)
Research Article View: 1,670 Download: 491
Preparation of Cattail-derived Activated Carbon and Its Adsorption Performance toward Ibuprofen and Diclofenac in Water
page: 1538 - 1554

Suhua Han, Qiannan Cao, Dongxu Qian, Ye Yang and Minbo Lu

Vol.48 No.6 (November 2021)
Research Article View: 1,665 Download: 331
Intercalated Zn-Cr-[α-SiW12O40] as Removal Agents of Cobalt (II) in Watery Phase: Adsorption and Regeneration Study
page: 545 - 556

Luna Silaen, Neza Rahayu Palapa, Elfita, Risfidian Mohadi and Aldes Lesbani

Vol.48 No.2 (March 2021)
Research Article View: 1,592 Download: 388
A Novel Polyacrylamide-divinylbenzene Functionalized Fe3O4/Coconut Shell Adsorbent with Superior Capacity for Removal of Acridine Orange
page: 520 - 532

Huan Wang*, Wei Zhao, Youning Chen, Xiaoling Yang and Xiaohua Meng

Vol.48 No.2 (March 2021)
Research Article View: 1,413 Download: 355
A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
page: 1055 - 1067

Wei Zhao, Youning Chen and Yuhong Li

Vol.47 No.5 (September 2020)
Research Article View: 1,531 Download: 420
Batch Removal of Pb (II) from Aqueous Solution using Activated Carbon Prepared from Mangosteen Shell Activated with H2SO4
page: 554 - 566

Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy

Vol.47 No.3 (May 2020)
Research Article View: 1,761 Download: 637
Adsorption of 2,4-Dichlorophenoxyacetic acid by Magnesium Ferrite Magnetic Nanoparticles Modified with Amine Functional Groups
page: 137 - 146

Supawitch Hoijang, Jeeranan Nonkumwong, Burapol Singhana, Sunanta Wangkarn, Supon Ananta and Laongnuan Srisombat

Vol.47 No.1 (January 2020)
Research Article View: 1,650 Download: 485
Modified Mangosteen Shell in the Removal of Hg (II) from Aqueous Solution-Isotherm and Kinetic Studies
page: 127 - 136

Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy

Vol.47 No.1 (January 2020)
Research Article View: 1,599 Download: 1,596
Prospective Sorption Evaluation of Hydrothermally Carbonized Lepironia Articulata (Grey sedge) for the Removal of Ni (II) from Aqueous Solution
page: 2220 - 2231

Asadullah, Lupong Kaewsichan and Kanogwan Tohdee

Vol.45 No.5 (Special 2018)
Research Article View: 1,587 Download: 605
Achieving Adsorption of Cationic Dyes by the Composites Based on H3PMo12O40 Decorating Metal Organic Frameworks
page: 1486 - 1498

Wenpeng Gong, Xiaogang Du, Xiaoxia Liu, Xiaofen Ke and Shuijin Yang*

Vol.45 No.3 (May 2018)
Research Article View: 1,672 Download: 372
Adsorption of a Highly Toxic Aromatic Pollutant From Aqueous Solution Using Low Cost Activated Carbon: Equilibrium, Kinetic and Thermodynamic Aspects
page: 1471 - 1485

Muhammad Hamayun*, Sonia Sherazi, Shah Zareen, Abdul Naeem, Muhammad Saeed, Khizar Hussain Shah, Ataf Ali Altaf, Shahzad Murtaza and Muhammad Zubair

Vol.45 No.3 (May 2018)
Research Article View: 1,581 Download: 412
Preparation of Eco-friendly and Low-cost Activated Carbon from Gracilaria corticata Seaweeds for the Removal of Crystal Violet Dye from Aqueous Solution: Equilibrium and Modeling Studies
page: 1039 - 1051

Duraipandian Jayganesh, Rengasamy Tamilarasan*, Muthiyan Kumar, Mani Murugavelu and Vadivelu Sivakumar

Vol.45 No.2 (March 2018)
Research Article View: 1,597 Download: 337
Laboratory-based Investigation into the Removal Behaviour of Asphalt in Porous Asphalt Mixture on Zinc Ions from Road Runoff
page: 1601 - 1610

Yao Zhao*, Chen Zhao, Kelly Hill and Xun Qian Xu

Vol.44 No.4 (October 2017)
Research Article View: 1,555 Download: 310
Removal of p-Nitrophenol from Aqueous Solution Using Synthesized Silica-Magnetite Composite
page: 1028 - 1039

Adekola F.A.*, Orimolade B.O.** and Adebayo G.B.

Vol.44 No.3 (July 2017)
Research Article View: 1,615 Download: 403
Evaluation of Treated and Untreated Sludge from Yarn Processing Factory as Adsorbent Candidates for Dye Removal
page: 508 - 517

Muhammad Abbas Ahmad Zaini* [a,b] and Noor Yuhana Jusoh [b]

Vol.44 No.2 (April 2017)
Research Article View: 1,529 Download: 266
Towards the Adsorption of Propylene and Propane on Cu(I)X and Cu(I)Y Zeolites: Effects of Zeolite Preparation
page: 591 - 599

Suwichak Phutthapatimok [a,b], Pattaraporn Sridechparsat [a,b], Pramoch Rangsunvigit* [a,b] and Santi Kulprathipanja [c]

Vol.43 No.3 (APRIL 2016)
Research Article View: 1,566 Download: 339
Validating Adsorptive Capacity of Areca Husk Carbon onto Methylene Blue & ANOVA Modelling
page: 183 - 194

Arumugam Basker[a]*, Syed shabudeen[b], Appavoo Ponnuraju Shekhar[c] and Savarimuthu Daniel[b]

Vol.43 No.1 (JANUARY 2016)
Research Article View: 1,535 Download: 281
Modeling and Optimization of Removal of Rhodamine – B from Wastewaters by Adsorption on Modified Clay
page: 1230 - 1240

Morteza Bahram, Robabeh Talebi, Abdolhossein Naseri* , Sirous Nouri

Vol.41 No.5/2 (OCTOBER 2014)
Research Article View: 1,476 Download: 524
Synthesis and Use of Zeolite Na-A from Waste Sludge of Water Treatment Plant for Ammonium Removal
page: 1262 - 1273

Jeatana Wongwichien [a], Suwimol Asavapisit [a] and Kwannate Sombatsompop* [b]

Vol.41 No.5/2 (OCTOBER 2014)
Research Article View: 1,449 Download: 275
Adsorption Equilibrium of Zinc Ions from Aqueous Solution by Using Modified Clinoptilolite
page: 56 - 62

Achanai Buasri, Phetcharat Yongbut, Nattawut Chaiyut and Kittiya Phattarasirichot

Vol.35 No.1 (JANUARY 2008)
Research Article View: 1,515 Download: 341
Outline
Figures