Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

1,647
Articles
Q3 0.80
Impact Factor
Q3 1.3
CiteScore
7 days
Avg. First Decision
Outline
Figures and Tables
ARTICLE METRICS
Views 1,608
Downloads 620

Water-based Synthesis of MIL-53(Al) at Room Temperature: An Effective Adsorbent for Oxytetracycline (OTC) Antibiotic Removal from Water

Parnuch Hongsawat, Phuri Kalnaowakul and Panida Prarat
* Author for corresponding; e-mail address: panida.p@sciee.kmutnb.ac.th
Volume: Vol.51 No.1 (January 2024)
Research Article
DOI: https://doi.org/10.12982/CMJS.2024.010
Received: 11 July 2023, Revised: 21 December 2023, Accepted: 28 December 2023, Published: -

Citation: Hongsawat P., Kalnaowakul P. and Prarat P., Water-based synthesis of MIL-53(Al) at room temperature: An effective adsorbent for oxytetracycline (OTC) antibiotic removal from water, Chiang Mai Journal of Science, 2024; 51(1): e2024010. DOI 10.12982/CMJS.2024.010.

Abstract

     MIL-53(Al), a flexible metal-organic framework, was synthesized by a facile method through a water-based method at room temperature, aligning with the principles of green chemistry. The objective was to investigate its effectiveness in removing pharmaceuticals and personal care products (PPCPs), specifically focusing on oxytetracycline (OTC). Our findings revealed that MIL-53(Al) possesses a structure with both micropores and mesopores, with a specific surface area of 916 m2/g. MIL-53(Al) notably exhibited a higher OTC adsorption capacity than commercially available powder activated carbon (PAC). The adsorption kinetics followed a pseudo-second-order model, while the Langmuir model accurately described the experimental isotherms for OTC adsorption. MIL-53(Al) outperformed previously reported MOF-based adsorbents with a maximum of 1005 mg/g capacity at pH 7. The flexible structure induces a breathing effect that significantly improves intraparticle diffusion for OTC, contributing to its adsorption efficiency. The adsorption of OTC was influenced by the solution pH, the acid dissociation constants of OTC, and the charged surface of the adsorbent. Pore filling, hydrogen bonding, π-π interaction, electrostatic interaction, and hydrophobic interaction were all associated with the adsorptive interaction between OTC and MIL-53(Al). The MIL-53(Al) also demonstrated good regeneration and reuse, with just a little decreased adsorption capacity after three reuse cycles. These findings indicate that green material MIL-53(Al) has the potential to be an effective adsorbent for removing OTC from water matrices.

Keywords: adsorption, oxytetracycline antibiotic, metal-organic framework, MIL-53(Al), water-based synthesis

Related Articles

Adsorption Performance of Spherical Porous SiO2 on Heavy Metal Cu2+ in Wastewater
DOI: 10.12982/CMJS.2025.075.

Yan-Min Chen, Zhen-Zhen Chen, Bei-Bei Qi, Ye-Xuan Cai, Jia-Meng Li and Yi-Fan Han

Vol.52 No.5 (September 2025)
Research Article View: 1,188 Download: 106
Synthesis, Characterization, and Ethylene Removal of Silver-Zeolite (LTA, MFI) for Fruit Preservation
DOI: 10.12982/CMJS.2025.071.

Ta Diem Quynh, Ho Nguyen Van Khanh, Ho Gia Quynh, Nguyen Manh Khang , Vo Tran Minh Khoa, Ngo Tran Hoang Duong and Nguyen Quang Long

Vol.52 No.5 (September 2025)
Research Article View: 501 Download: 147
Barite Adsorption Efficiency for Removal of Mannose. Experimental Measurements and Equilibrium Study
DOI: 10.12982/CMJS.2025.034.

Mustafa Jaip Allah Abdelmageed Abualreish

Vol.52 No.3 (May 2025)
Research Article View: 464 Download: 247
A Rhizobacterium Kitasatospora nipponensis Demonstrates Antifungal Activity against Basal Stem Rot Disease and Promotes Plant Growth in Oil Palm (Elaeis guineensis) Seedlings
DOI: 10.12982/CMJS.2025.033.

Anurag Sunpapao, Supaporn Pithakkit and Prisana Wonglom

Vol.52 No.3 (May 2025)
Research Article View: 775 Download: 333
Removal of Chromium (III) Heavy Metal Ions from Aqueous Solutions by Green Synthesized Calix[6]arene
DOI: 10.12982/CMJS.2025.005.

Susy Yunita Prabawati, Nina Hamidah and Afifah Mufidati

Vol.52 No.1 (January 2025)
Research Article View: 771 Download: 366
H2S Removal from Biogas using Steel Wool (Fe2O3) Adsorption Combined with Water Absorption: Experimental and Modelling via RSM
DOI: 10.12982/CMJS.2024.027.

Jiraporn Paoaiang, Prukraya Pongyeela, Nirana Chairerk and Juntima Chungsiriporn

Vol.51 No.2 (March 2024)
Research Article View: 1,464 Download: 1,722
Development and Optimization of an Amperometric Bi-enzyme Biosensor for Aspartame Determination
DOI: 10.12982/CMJS.2023.064.

Tanaporn Tangtawewipat and Saipin Thanachasai

Vol.50 No.6 (November 2023)
Research Article View: 1,272 Download: 583
Preparation of Porous Silica Nanoparticles by Chemical Etching for Removal of Paraquat from Aqueous Solution
DOI: 10.12982/CMJS.2023.009.

Kanokwan Darasoon, Supawitch Hoijang, Tanapong Kunakham, Sorapong Janhom, Supon Ananta, Gyu Leem and Laongnuan Srisombat

Vol.50 No.1 (January 2023)
Research Article View: 1,610 Download: 1,187
Hydrochar from Lansium domesticum and Salacca zalacca Peel as Adsorbent on Rhodamine-B Removal: Adsorption Process and Regeneration Studies
DOI: 10.12982/CMJS.2022.108.

Mauizatul Hasanah, Alfan Wijaya, Risfidian Mohadi, Fitri Suryani Arsyad and Aldes Lesbani

Vol.49 No.6 (November 2022)
Research Article View: 1,656 Download: 446
2-Methylimidazole-modified Iron Metal-organic Framework as an Efficient Methylene Blue Adsorbent
DOI: 10.12982/CMJS.2022.104.

Yingxin Zhao, Hao Hu, Shengyu Zhang, Shiya Feng, Yun Yang, Xiongjian Li and Shuijin Yang

Vol.49 No.6 (November 2022)
Research Article View: 1,591 Download: 478
Process Optimization and Modeling of Low-cost Activated Carbon Preparation and Its Application in Chromium(VI) Removal
DOI: 10.12982/CMJS.2022.100.

Theeradit Phothitontimongkol and Kanyarak Prasertboonyai

Vol.49 No.6 (November 2022)
Research Article View: 1,527 Download: 529
Sorption Studies of Cesium on Kunipia-F Bentonite and Silicon Dioxide
DOI: 10.12982/CMJS.2022.093.

Anan O-Manee, Youichi Enokida and Kayo Sawada

Vol.49 No.5 (September 2022)
Research Article View: 1,602 Download: 637
Cigarette Butts Valorization: Activated Hydrochar for Methylene Blue Removal
DOI: 10.12982/CMJS.2022.062.

Naphatsarnan Phasukarratchai, Budsarin Yattipat, Parichat Muengkrajang, Sasishai Permpoon and Alissara Reungsang

Vol.49 No.4 (July 2022)
Research Article View: 1,862 Download: 1,291
Non-Covalent Interactions between Graphene and Cluster of Ruthenium Oxides and Vanadium Oxides : A Dispersioncorrected Density Functional Theory Study
page: 1606 - 1619

Paphawarin Kheownil, Parameat Seesopha, Sawitree Chuaychoocherd, Panichakorn Jaiyong and Yuthana Tantirungrotechai

Vol.48 No.6 (November 2021)
Research Article View: 1,608 Download: 942
Density Functional Theory Study of Methane Adsorption on LaCoO3 (001) Surface
page: 1645 - 1656

Xuefeng Wang, Hongyan Zhang,Cunbao Deng, Ling Qiao and Shuangli Du

Vol.48 No.6 (November 2021)
Research Article View: 1,561 Download: 487
Preparation of Cattail-derived Activated Carbon and Its Adsorption Performance toward Ibuprofen and Diclofenac in Water
page: 1538 - 1554

Suhua Han, Qiannan Cao, Dongxu Qian, Ye Yang and Minbo Lu

Vol.48 No.6 (November 2021)
Research Article View: 1,556 Download: 327
Intercalated Zn-Cr-[α-SiW12O40] as Removal Agents of Cobalt (II) in Watery Phase: Adsorption and Regeneration Study
page: 545 - 556

Luna Silaen, Neza Rahayu Palapa, Elfita, Risfidian Mohadi and Aldes Lesbani

Vol.48 No.2 (March 2021)
Research Article View: 1,492 Download: 386
A Novel Polyacrylamide-divinylbenzene Functionalized Fe3O4/Coconut Shell Adsorbent with Superior Capacity for Removal of Acridine Orange
page: 520 - 532

Huan Wang*, Wei Zhao, Youning Chen, Xiaoling Yang and Xiaohua Meng

Vol.48 No.2 (March 2021)
Research Article View: 1,330 Download: 350
A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
page: 1055 - 1067

Wei Zhao, Youning Chen and Yuhong Li

Vol.47 No.5 (September 2020)
Research Article View: 1,437 Download: 419
Batch Removal of Pb (II) from Aqueous Solution using Activated Carbon Prepared from Mangosteen Shell Activated with H2SO4
page: 554 - 566

Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy

Vol.47 No.3 (May 2020)
Research Article View: 1,657 Download: 632
Catalytic Activity of Bimetallic Au@Pt Core-Shell Over CeO2-Al2O3 for CO Oxidation Reaction
page: 278 - 287

Wichet Lamai and Akkarat Wongkaew*

Vol.47 No.2 (Special Issue I : March 2020)
Research Article View: 1,798 Download: 930
Adsorption of 2,4-Dichlorophenoxyacetic acid by Magnesium Ferrite Magnetic Nanoparticles Modified with Amine Functional Groups
page: 137 - 146

Supawitch Hoijang, Jeeranan Nonkumwong, Burapol Singhana, Sunanta Wangkarn, Supon Ananta and Laongnuan Srisombat

Vol.47 No.1 (January 2020)
Research Article View: 1,557 Download: 484
Modified Mangosteen Shell in the Removal of Hg (II) from Aqueous Solution-Isotherm and Kinetic Studies
page: 127 - 136

Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy

Vol.47 No.1 (January 2020)
Research Article View: 1,510 Download: 1,591
Prospective Sorption Evaluation of Hydrothermally Carbonized Lepironia Articulata (Grey sedge) for the Removal of Ni (II) from Aqueous Solution
page: 2220 - 2231

Asadullah, Lupong Kaewsichan and Kanogwan Tohdee

Vol.45 No.5 (Special 2018)
Research Article View: 1,490 Download: 603
Achieving Adsorption of Cationic Dyes by the Composites Based on H3PMo12O40 Decorating Metal Organic Frameworks
page: 1486 - 1498

Wenpeng Gong, Xiaogang Du, Xiaoxia Liu, Xiaofen Ke and Shuijin Yang*

Vol.45 No.3 (May 2018)
Research Article View: 1,553 Download: 367
Adsorption of a Highly Toxic Aromatic Pollutant From Aqueous Solution Using Low Cost Activated Carbon: Equilibrium, Kinetic and Thermodynamic Aspects
page: 1471 - 1485

Muhammad Hamayun*, Sonia Sherazi, Shah Zareen, Abdul Naeem, Muhammad Saeed, Khizar Hussain Shah, Ataf Ali Altaf, Shahzad Murtaza and Muhammad Zubair

Vol.45 No.3 (May 2018)
Research Article View: 1,491 Download: 412
Preparation of Eco-friendly and Low-cost Activated Carbon from Gracilaria corticata Seaweeds for the Removal of Crystal Violet Dye from Aqueous Solution: Equilibrium and Modeling Studies
page: 1039 - 1051

Duraipandian Jayganesh, Rengasamy Tamilarasan*, Muthiyan Kumar, Mani Murugavelu and Vadivelu Sivakumar

Vol.45 No.2 (March 2018)
Research Article View: 1,491 Download: 334
Effect of Calcination Temperature on the Magnetic Characteristics of Synthetic Iron Oxide Magnetic Nanoparticles for Arsenic Adsorption
page: 528 - 539

Nucharee Chomchoey, Darunee Bhongsuwan and Tripob Bhongsuwan

Vol.45 No.1 (January 2018)
Research Article View: 1,362 Download: 373
Agrowaste Based Ecofriendly Bio-adsorbent for the Removal of Phenol: Adsorption and Kinetic Study by Acacia Tortilis Pod Shell
page: 355 - 368

Mohammad Malakootian, Amir Hossein Mahvi, Hossein Jafari Mansoorian and Narges Khanjani

Vol.45 No.1 (January 2018)
Research Article View: 1,478 Download: 411
Laboratory-based Investigation into the Removal Behaviour of Asphalt in Porous Asphalt Mixture on Zinc Ions from Road Runoff
page: 1601 - 1610

Yao Zhao*, Chen Zhao, Kelly Hill and Xun Qian Xu

Vol.44 No.4 (October 2017)
Research Article View: 1,454 Download: 306
Removal of p-Nitrophenol from Aqueous Solution Using Synthesized Silica-Magnetite Composite
page: 1028 - 1039

Adekola F.A.*, Orimolade B.O.** and Adebayo G.B.

Vol.44 No.3 (July 2017)
Research Article View: 1,506 Download: 402
Evaluation of Treated and Untreated Sludge from Yarn Processing Factory as Adsorbent Candidates for Dye Removal
page: 508 - 517

Muhammad Abbas Ahmad Zaini* [a,b] and Noor Yuhana Jusoh [b]

Vol.44 No.2 (April 2017)
Research Article View: 1,430 Download: 261
Towards the Adsorption of Propylene and Propane on Cu(I)X and Cu(I)Y Zeolites: Effects of Zeolite Preparation
page: 591 - 599

Suwichak Phutthapatimok [a,b], Pattaraporn Sridechparsat [a,b], Pramoch Rangsunvigit* [a,b] and Santi Kulprathipanja [c]

Vol.43 No.3 (APRIL 2016)
Research Article View: 1,450 Download: 334
Validating Adsorptive Capacity of Areca Husk Carbon onto Methylene Blue & ANOVA Modelling
page: 183 - 194

Arumugam Basker[a]*, Syed shabudeen[b], Appavoo Ponnuraju Shekhar[c] and Savarimuthu Daniel[b]

Vol.43 No.1 (JANUARY 2016)
Research Article View: 1,449 Download: 280
Pt/Al2O3Catalyzed Decolorization of Rhodamine B Dye in Aqueous Medium
page: 730 - 744

Muhammad Saeed, Shahid Adeel, Muhammad Azhar Shahzad, Atta Ul-Haq, Majid Muneer, Muhammad Younas

Vol.42 No.3 (JULY 2015)
Research Article View: 1,430 Download: 293
Enhanced Production of Polysaccharides and Protein Content in Cyanobacterium, Oscillatoria limnetica as a Defense Mechanism Against Low pH and Pb2+
page: 34 - 43

Suneerat Ruangsomboon*

Vol.42 No.1 (JANUARY 2015)
Research Article View: 1,362 Download: 300
Modeling and Optimization of Removal of Rhodamine – B from Wastewaters by Adsorption on Modified Clay
page: 1230 - 1240

Morteza Bahram, Robabeh Talebi, Abdolhossein Naseri* , Sirous Nouri

Vol.41 No.5/2 (OCTOBER 2014)
Research Article View: 1,379 Download: 519
Synthesis and Use of Zeolite Na-A from Waste Sludge of Water Treatment Plant for Ammonium Removal
page: 1262 - 1273

Jeatana Wongwichien [a], Suwimol Asavapisit [a] and Kwannate Sombatsompop* [b]

Vol.41 No.5/2 (OCTOBER 2014)
Research Article View: 1,358 Download: 275
Energy Conversion Efficiency Improvement of ZnO Dye-sensitized Solar Cells by Dye Re-adsorption and N-P Junction Technique
page: 783 - 788

Surat Futemvong [a,b], Niyom Hongsith [b,d], Duangmanee Wongratanaphisan [b,c], Atcharawon Gardchare

Vol.40 No.4 (OCTOBER 2013)
Research Article View: 1,493 Download: 326
Adsorption Equilibrium of Zinc Ions from Aqueous Solution by Using Modified Clinoptilolite
page: 56 - 62

Achanai Buasri, Phetcharat Yongbut, Nattawut Chaiyut and Kittiya Phattarasirichot

Vol.35 No.1 (JANUARY 2008)
Research Article View: 1,406 Download: 337
Use of Natural Clinoptilolite for the Removal of Lead (II) from Wastewater in Batch Experiment
page: 447 - 456

Achanai Buasri, Nattawut Chaiyut, Kittiya Phattarasirichot, Phetcharat Yongbut and Lalita Nammueng

Vol.35 No.3 (SEPTEMBER 2008)
Research Article View: 1,403 Download: 985
Smart Chemical Sensors Based on Ceramic Heterocontacts
page: 239 - 244

David Cann and Seymen Aygün

Vol.32 No.3 (SEPTEMBER 2005)
Research Article View: 1,352 Download: 271
Thermodynamics Study of Natural Indigo Adsorption on Silk Yarn
page: 363 - 367

Paisan Kongkachuichay, Aroonsiri Shitangkoon, and Sakowrath Hirunkitmonkon

Vol.37 No.2 (MAY 2010)
Short Communication View: 1,434 Download: 359
Effects of Inorganic and Organic Phases on Specific Surface Area of Ball Clay
page: 141 - 154

Apinon Nuntiya*[a], Frank L. Riley [b] and Brian Rand [b]

Vol.29 No.3 (DECEMBER 2002)
Research Article View: 1,453 Download: 263
Outline
Figures