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Validating Adsorptive Capacity of Areca Husk Carbon onto Methylene Blue & ANOVA Modelling


Paper Type 
 Contributed Paper
Title 
 Validating Adsorptive Capacity of Areca Husk Carbon onto Methylene Blue & ANOVA Modelling
Author 
 Arumugam Basker[a]*, Syed shabudeen[b], Appavoo Ponnuraju Shekhar[c] and Savarimuthu Daniel[b]
Email 
 baskerchemistry@gmail.com
Abstract:
         ANOVA and chemical kinetics parameters are attempted effectively to optimize the absorptive capacity of an indigenously prepared adsorbent. In this study, the ability of Areca Husk Carbon to adsorb Methylene Blue (MB) dye from aqueous solution was investigated. Batch experiments were carried out for the adsorption of dye molecules onto AHC at room temperature. The influences of various factors such as particle size, adsorbent dosage, initial dye concentration, contact time, pH and temperature on the adsorption capacity were investigated and optimal experimental conditions were ascertained. Adsorption data were modelled using Langmuir, Freundlich and Temkin adsorption isotherms. Adsorption kinetics were verified by pseudo-first order, pseudo-second order and intraparticle diffusion models. The kinetic adsorption data fitted the pseudo-first order kinetic model well and also followed the intra-particle diffusion model. Thermodynamic parameters have also been evaluated.  The structural and morphological of activated carbon were characterized by FTIR and SEM studies respectively. Main and interaction effects were analysed by analysis of variance (ANOVA), F-test and p-values to define most important process variables affecting the dye adsorption. The results indicated that AHC could be employed as a low cost adsorbent in wastewater treatment for the removal of MB.

Start & End Page 
 183 - 194
Received Date 
 2013-12-11
Revised Date 
Accepted Date 
 2014-10-07
Full Text 
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Keyword 
 adsorption, areca husk, methylene blue
Volume 
 Vol.43 No.1 (JANUARY 2016)
DOI 
Citation 
 Basker A., Shabudeen S., Shekhar A.P. and Daniel S., Validating Adsorptive Capacity of Areca Husk Carbon onto Methylene Blue & ANOVA Modelling , Chiang Mai J. Sci., 2016; 43(1): 183-194.
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