Submit your paper 
Download Template JOURNAL DETAIL
Thermal and Acid Activation (TAA) of Bentonite as Adsorbent for Removal of Methylene Blue: A Kinetics and Thermodynamic Study
Paper Type  |
Contributed Paper |
Title |
Thermal and Acid Activation (TAA) of Bentonite as Adsorbent for Removal of Methylene Blue: A Kinetics and Thermodynamic Study |
Author |
Tarmizi Taher, Dedi Rohendi, Risfidian Mohadi and Aldes Lesbani |
Email |
aldeslesbani@pps.unsri.ac.id |
|
Abstract: Natural bentonite grounded from Sarolangun District of Jambi Province has been modified based on Thermal and Acid Activation (TAA). The thermal activation was conducted by calcination at temperature 400 oC and followed by chemical activation using H2SO4. In order to investigate the change of the bentonite structure before and after activation process, the chemical analysis by XRF, XRD powder, BET, and FTIR was conducted. The TAA bentonite then used as an adsorbent to remove the methylene blue dye from aqueous solution by studying the kinetics and thermodynamic of the adsorption process. The result of the structural analysis showed that during the activation process, the structure of bentonite was not changed significantly and the surface area of the activated bentonite has increased from 55.6 to 75.6 m2/g. The kinetics studies of adsorption methylene blue onto TAA bentonite revealed that the adsorption process followed the pseudo-second-order kinetic equation rather than the pseudo-first order kinetics. The kinetic data obtained presented that by increasing the initial dye concentration, the adsorption speed was reduced. The thermodynamic adsorption study revealed that the adsorption process was spontaneous showed with the negative value of free Gibbs energy. |
|
Start & End Page |
1770 - 1781 |
Received Date |
2017-01-24 |
Revised Date |
|
Accepted Date |
2017-06-14 |
Full Text |
Download |
Keyword |
Bentonite, thermal and acid activation (TAA), methylene blue, kinetics, thermodynamic |
Volume |
Vol.45 No.4 (July 2018) |
DOI |
|
Citation |
Taher T., Rohendi D., Mohadi R. and Lesbani A., Thermal and Acid Activation (TAA) of Bentonite as Adsorbent for Removal of Methylene Blue: A Kinetics and Thermodynamic Study, Chiang Mai Journal of Science, 2018; 45(4): 1770-1781. |
SDGs |
|
| View:764 Download:250 | |
RELATED ARTICLE
2-Methylimidazole-modified Iron Metal-organic Framework as an Efficient Methylene Blue Adsorbent
page: 1576 - 1593
Author:Yingxin Zhao, Hao Hu, Shengyu Zhang, Shiya Feng, Yun Yang, Xiongjian Li and Shuijin Yang
Vol.49 No.6 (November 2022) View: 1,174 Download:331
page: 1576 - 1593
Author:Yingxin Zhao, Hao Hu, Shengyu Zhang, Shiya Feng, Yun Yang, Xiongjian Li and Shuijin Yang
Vol.49 No.6 (November 2022) View: 1,174 Download:331
Sorption Studies of Cesium on Kunipia-F Bentonite and Silicon Dioxide
page: 1452 - 1457
Author:Anan O-Manee, Youichi Enokida and Kayo Sawada
Vol.49 No.5 (September 2022) View: 1,134 Download:359
page: 1452 - 1457
Author:Anan O-Manee, Youichi Enokida and Kayo Sawada
Vol.49 No.5 (September 2022) View: 1,134 Download:359
Cigarette Butts Valorization: Activated Hydrochar for Methylene Blue Removal
page: 1063 - 1075
Author:Naphatsarnan Phasukarratchai, Budsarin Yattipat, Parichat Muengkrajang, Sasishai Permpoon and Alissara Reungsang
Vol.49 No.4 (July 2022) View: 1,430 Download:827
page: 1063 - 1075
Author:Naphatsarnan Phasukarratchai, Budsarin Yattipat, Parichat Muengkrajang, Sasishai Permpoon and Alissara Reungsang
Vol.49 No.4 (July 2022) View: 1,430 Download:827
Synthesis, Characterization and In Silico Biological and Anticancer Activity of 3-(2-Fluorophenyl)-N-(4-Fluorophenyl)- 7H-[1,2,4] Triazolo[3,4-b] [1,3,4] Thiadiazin-6-Amine
page: 377 - 386
Author:Fahad Hassan Shah, Balasaheb Daniyal Vanjare and Song Ja Kim
Vol.49 No.2 (March 2022) View: 927 Download:460
page: 377 - 386
Author:Fahad Hassan Shah, Balasaheb Daniyal Vanjare and Song Ja Kim
Vol.49 No.2 (March 2022) View: 927 Download:460
Investigation of the Initiating and Catalytic Behavior of Tri-n-butyltin(IV) n-Butoxide in Ring-Opening Polymerization of ε-Caprolactone and Transesterification of Poly(L-lactic acid)
page: 27 - 38
Author:Winita Punyodom, Puttinan Meepowpan, Boontharika Thapsukhon, Manita Dumklang and Wanich Limwanich
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,376 Download:323
page: 27 - 38
Author:Winita Punyodom, Puttinan Meepowpan, Boontharika Thapsukhon, Manita Dumklang and Wanich Limwanich
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,376 Download:323
SDGs:
Adsorptive Removal of Malachite Green from Aqueous Solution over Graphite-layered Double Hydroxides Composite
page: 1351 - 1362
Author:Neza Rahayu Palapa, Tarmizi Taher, Shahibul Fajri and Aldes Lesbani
Vol.48 No.5 (September 2021) View: 1,277 Download:938
page: 1351 - 1362
Author:Neza Rahayu Palapa, Tarmizi Taher, Shahibul Fajri and Aldes Lesbani
Vol.48 No.5 (September 2021) View: 1,277 Download:938
Kinetic and Mechanistic Studies of Bulk Copolymerization of L-lactide and Glycolide Initiated by Liquid Tin(II) n-Butoxide
page: 489 - 505
Author:Tawan Chaiwon, Montira Sriyai, Puttinan Meepowpan, Robert Molloy, Kanarat Nalampang, Narin Kaabbuathong and Winita Punyodom*
Vol.48 No.2 (March 2021) View: 715 Download:434
page: 489 - 505
Author:Tawan Chaiwon, Montira Sriyai, Puttinan Meepowpan, Robert Molloy, Kanarat Nalampang, Narin Kaabbuathong and Winita Punyodom*
Vol.48 No.2 (March 2021) View: 715 Download:434
SDGs:
Intercalated Zn-Cr-[α-SiW12O40] as Removal Agents of Cobalt (II) in Watery Phase: Adsorption and Regeneration Study
page: 545 - 556
Author:Luna Silaen, Neza Rahayu Palapa, Elfita, Risfidian Mohadi and Aldes Lesbani
Vol.48 No.2 (March 2021) View: 1,252 Download:286
page: 545 - 556
Author:Luna Silaen, Neza Rahayu Palapa, Elfita, Risfidian Mohadi and Aldes Lesbani
Vol.48 No.2 (March 2021) View: 1,252 Download:286
Ring-Opening Polymerization of ε-Caprolactone Using Soluble Tin(II) n-Butoxide-L-Lactide Macroinitiators
page: 312 - 322
Author:Manita Dumklang*, Wanich Limwanich, Sawarot Phetsuk, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 793 Download:398
page: 312 - 322
Author:Manita Dumklang*, Wanich Limwanich, Sawarot Phetsuk, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 793 Download:398
SDGs:
Tin(II) n-Hexoxide as New Initiator for the Ring-Opening Polymerization of ε-Caprolactone: Isoconversional Kinetics Analysis by Non-Isothermal DSC
page: 276 - 291
Author:Boontharika Thapsukhon*, Wanich Limwanich, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 803 Download:570
page: 276 - 291
Author:Boontharika Thapsukhon*, Wanich Limwanich, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 803 Download:570
SDGs:
Growth Kinetics of Iron Aluminide Layer on Hot-dip Aluminized AISI 304 Austenitic Stainless Steel
page: 319 - 328
Author:Payoon Senthongkaew, Laksamee Angkurarach and Patiphan Juijerm*
Vol.47 No.2 (Special Issue I : March 2020) View: 682 Download:370
page: 319 - 328
Author:Payoon Senthongkaew, Laksamee Angkurarach and Patiphan Juijerm*
Vol.47 No.2 (Special Issue I : March 2020) View: 682 Download:370
Modified Mangosteen Shell in the Removal of Hg (II) from Aqueous Solution-Isotherm and Kinetic Studies
page: 127 - 136
Author:Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy
Vol.47 No.1 (January 2020) View: 1,222 Download:1,528
page: 127 - 136
Author:Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy
Vol.47 No.1 (January 2020) View: 1,222 Download:1,528
Purification of polycarbonate from aluminum by acid leaching for recycling waste compact discs
page: 693 - 702
Author:Cui Li, Hui Wang*, Yingshuang Zhang*
Vol.46 No.4 (July 2019) View: 679 Download:253
page: 693 - 702
Author:Cui Li, Hui Wang*, Yingshuang Zhang*
Vol.46 No.4 (July 2019) View: 679 Download:253
Predicting the Binding Affinity of P38 Map Kinase Inhibitors using Free Energy Calculations
page: 93 - 105
Author:Warabhorn Boonyarat, Patchreenart Saparpakorn and Supa Hannongbua
Vol.46 No.1 (January 2019) View: 1,066 Download:239
page: 93 - 105
Author:Warabhorn Boonyarat, Patchreenart Saparpakorn and Supa Hannongbua
Vol.46 No.1 (January 2019) View: 1,066 Download:239
Kinetics of Ultrasound-assisted Extraction of Flavonoids and Triterpenes and Structure Characterization of Chinese Northeast Black Bee Propolis
page: 72 - 92
Author:Qingzhi Ding, Ricardo Antonio Wu-Chen, Qi Wu, Hanfei Jiang, Ting Zhang, Lin Luo, Haile Ma*, Shiqiao Ma and Ronghai He
Vol.46 No.1 (January 2019) View: 699 Download:347
page: 72 - 92
Author:Qingzhi Ding, Ricardo Antonio Wu-Chen, Qi Wu, Hanfei Jiang, Ting Zhang, Lin Luo, Haile Ma*, Shiqiao Ma and Ronghai He
Vol.46 No.1 (January 2019) View: 699 Download:347
Kinetic and Thermodynamic Studies of Cationic and Anionic Surfactants Adsorption onto Polyethyleneimine-modified Cotton Cloths
page: 2422 - 2437
Author:Sorapong Janhom
Vol.45 No.6 (September 2018) View: 773 Download:379
page: 2422 - 2437
Author:Sorapong Janhom
Vol.45 No.6 (September 2018) View: 773 Download:379
Modification of Bentonite with Different Surfactants and Substitute as a Mordant in Wool Natural Dyeing
page: 492 - 504
Author:Hossein Barani
Vol.45 No.1 (January 2018) View: 688 Download:501
page: 492 - 504
Author:Hossein Barani
Vol.45 No.1 (January 2018) View: 688 Download:501
Effect of Microbial Consortia on Photosynthetic Efficiency of Arabidopsis thaliana under drought stress
page: 1 - 10
Author:Hazem M. Kalaji, Wasu Pathom-aree, Ramin Lotfi, Panchal Balaji, Nabil Elshery, Ewa Beata Grska, Michal Swiatek, Tomasz Horaczek, JacekMojski, Henryk Kociel, Michal Miroslaw Rytel and Sada Yoosathaporn
Vol.45 No.1 (January 2018) View: 689 Download:256
page: 1 - 10
Author:Hazem M. Kalaji, Wasu Pathom-aree, Ramin Lotfi, Panchal Balaji, Nabil Elshery, Ewa Beata Grska, Michal Swiatek, Tomasz Horaczek, JacekMojski, Henryk Kociel, Michal Miroslaw Rytel and Sada Yoosathaporn
Vol.45 No.1 (January 2018) View: 689 Download:256
Investigation of Metastable Zone Width and Nucleation Kinetics of 2-cyanoguanidine by Cooling Crystallization
page: 1633 - 1645
Author:Ning Zhang, Yongsheng Ren*, Chengqi Liu and Haipeng Zhao
Vol.44 No.4 (October 2017) View: 666 Download:345
page: 1633 - 1645
Author:Ning Zhang, Yongsheng Ren*, Chengqi Liu and Haipeng Zhao
Vol.44 No.4 (October 2017) View: 666 Download:345
Evaluation of Treated and Untreated Sludge from Yarn Processing Factory as Adsorbent Candidates for Dye Removal
page: 508 - 517
Author:Muhammad Abbas Ahmad Zaini* [a,b] and Noor Yuhana Jusoh [b]
Vol.44 No.2 (April 2017) View: 1,146 Download:190
page: 508 - 517
Author:Muhammad Abbas Ahmad Zaini* [a,b] and Noor Yuhana Jusoh [b]
Vol.44 No.2 (April 2017) View: 1,146 Download:190
Theory of Doping in Indirect Determination of Concentration and Mobility of Native Point Defects in Metal Oxides
page: 365 - 374
Author:Zbigniew Grzesik
Vol.43 No.2 (SPECIAL ISSUE 1) View: 663 Download:212
page: 365 - 374
Author:Zbigniew Grzesik
Vol.43 No.2 (SPECIAL ISSUE 1) View: 663 Download:212
Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide)
page: 329 - 338
Author:Wanich Limwanich [a], Sawarot Phetsuk [b], Puttinan Meepowpan [b], Nawee Kungwan [b], Winita Punyodom*[b]
Vol.43 No.2 (SPECIAL ISSUE 1) View: 754 Download:257
page: 329 - 338
Author:Wanich Limwanich [a], Sawarot Phetsuk [b], Puttinan Meepowpan [b], Nawee Kungwan [b], Winita Punyodom*[b]
Vol.43 No.2 (SPECIAL ISSUE 1) View: 754 Download:257
Validating Adsorptive Capacity of Areca Husk Carbon onto Methylene Blue & ANOVA Modelling
page: 183 - 194
Author:Arumugam Basker[a]*, Syed shabudeen[b], Appavoo Ponnuraju Shekhar[c] and Savarimuthu Daniel[b]
Vol.43 No.1 (JANUARY 2016) View: 1,147 Download:215
page: 183 - 194
Author:Arumugam Basker[a]*, Syed shabudeen[b], Appavoo Ponnuraju Shekhar[c] and Savarimuthu Daniel[b]
Vol.43 No.1 (JANUARY 2016) View: 1,147 Download:215
Kinetic Study of Reduction of N-[4-[Bis[4-dimethylamino)-phenyl]-methylene]-2,5-cyclohexadiene-1-ylidene]-methanaminium Chloride with Iodide in Aqueous Ethanol System
page: 963 - 971
Author:Maria Ashfaq, Rehana Saeed, Summyia Masood and Sameera Razi Khan
Vol.42 No.4 (OCTOBER 2015) View: 655 Download:211
page: 963 - 971
Author:Maria Ashfaq, Rehana Saeed, Summyia Masood and Sameera Razi Khan
Vol.42 No.4 (OCTOBER 2015) View: 655 Download:211
Removal of Methylene Blue from Aqueous Solution by Coffee Residues
page: 407 - 416
Author:Walaikorn Nitayaphat, Thanut Jintakosol, Kamontip Engkaseth and Yada Wanrakakit
Vol.42 No.2 (APRIL 2015) View: 768 Download:263
page: 407 - 416
Author:Walaikorn Nitayaphat, Thanut Jintakosol, Kamontip Engkaseth and Yada Wanrakakit
Vol.42 No.2 (APRIL 2015) View: 768 Download:263
Combustion of Moist Coal Briquettes
page: 35 - 42
Author:Prodpran Siritheerasas, Chomthida Chunniyom and Piyaporn Sethabunjong Putarat Nimmanpipug, Ancalee
Vol.35 No.1 (JANUARY 2008) View: 672 Download:226
page: 35 - 42
Author:Prodpran Siritheerasas, Chomthida Chunniyom and Piyaporn Sethabunjong Putarat Nimmanpipug, Ancalee
Vol.35 No.1 (JANUARY 2008) View: 672 Download:226
Copyrights © Since 2021 All Rights Reserved by Chiang Mai Journal of Science