Chiang Mai Journal of Science, Faculty of Science, Chiang Mai University

1.3

2024CiteScore

49th percentile

Journal Volumes

Submit your paper

Download Template

JOURNAL DETAIL

Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide)

Paper Type	Contributed Paper
Title	Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide)
Author	Wanich Limwanich [a], Sawarot Phetsuk [b], Puttinan Meepowpan [b], Nawee Kungwan [b], Winita Punyodom*[b]
Email	winitacmu@gmail.com
Abstract: The non-isothermal melt crystallization kinetics of the synthesized poly(ε-caprolactone) (PCL) and poly(L-lactide) (PLL) with identical number average molecular weight (= 1.8´10⁴) and polydispersity index (PDI = 1.8) was studied by differential scanning calorimetry (DSC). The crystallizations of PCL and PLL were performed under the cooling rates of 5.0, 7.5, 10.0 and 12.5 °C.min^-1. From non-isothermal DSC analysis, the crystallization rates increased with increasing of the cooling rates, while the crystallization time decreased for both polymers. The Avrami, Ozawa and Liu models were applied to describe non-isothermal crystallization and determine kinetic parameters for PCL and PLL crystallizations. From Avrami, Ozawa and Liu models, the crystallization mechanism of PCL and PLL was nucleation with three dimensional growths. From Avrami, Liu and Friedman analysis, the synthesized PCL crystallized faster than PLL with the identical molecular weight and PDI value.
Start & End Page	329 - 338
Received Date	2015-09-15
Revised Date
Accepted Date	2015-11-01
Full Text	Download
Keyword	crystallization, kinetics, differential scanning calorimetry (DSC), poly(L-lactide), poly(ε-caprolactone), biodegradable polymer
Volume	Vol.43 No.2 (SPECIAL ISSUE 1)
DOI
Citation	[a] W.L., [b] S.P., [b] P.M., [b] N.K. and Punyodom[b] W., Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide), Chiang Mai Journal of Science, 2016; 43(2)*: 329-338.
View:892 Download:303

Synthesis, Characterization and In Silico Biological and Anticancer Activity of 3-(2-Fluorophenyl)-N-(4-Fluorophenyl)- 7H-[1,2,4] Triazolo[3,4-b] [1,3,4] Thiadiazin-6-Amine
page: 377 - 386
Author:Fahad Hassan Shah, Balasaheb Daniyal Vanjare and Song Ja Kim
Vol.49 No.2 (March 2022) View: 1,154 Download:639

Investigation of the Initiating and Catalytic Behavior of Tri-n-butyltin(IV) n-Butoxide in Ring-Opening Polymerization of ε-Caprolactone and Transesterification of Poly(L-lactic acid)
page: 27 - 38
Author:Winita Punyodom, Puttinan Meepowpan, Boontharika Thapsukhon, Manita Dumklang and Wanich Limwanich
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,657 Download:551

Kinetic and Mechanistic Studies of Bulk Copolymerization of L-lactide and Glycolide Initiated by Liquid Tin(II) n-Butoxide
page: 489 - 505
Author:Tawan Chaiwon, Montira Sriyai, Puttinan Meepowpan, Robert Molloy, Kanarat Nalampang, Narin Kaabbuathong and Winita Punyodom*
Vol.48 No.2 (March 2021) View: 892 Download:693

Property Enhancement of Polylactide Monofilaments by Cold-Drawing Process and Solvent Infusion
page: 323 - 331
Author:Jirawan Jindakaew, Chalita Ratanatawanate, Takeshi Kikutani, and Pakorn Opaprakasit*
Vol.48 No.2 (March 2021) View: 1,598 Download:1,266

Ring-Opening Polymerization of ε-Caprolactone Using Soluble Tin(II) n-Butoxide-L-Lactide Macroinitiators
page: 312 - 322
Author:Manita Dumklang*, Wanich Limwanich, Sawarot Phetsuk, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 996 Download:591

Tin(II) n-Hexoxide as New Initiator for the Ring-Opening Polymerization of ε-Caprolactone: Isoconversional Kinetics Analysis by Non-Isothermal DSC
page: 276 - 291
Author:Boontharika Thapsukhon*, Wanich Limwanich, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 973 Download:818

Growth Kinetics of Iron Aluminide Layer on Hot-dip Aluminized AISI 304 Austenitic Stainless Steel
page: 319 - 328
Author:Payoon Senthongkaew, Laksamee Angkurarach and Patiphan Juijerm*
Vol.47 No.2 (Special Issue I : March 2020) View: 859 Download:460

Modified Mangosteen Shell in the Removal of Hg (II) from Aqueous Solution-Isotherm and Kinetic Studies
page: 127 - 136
Author:Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy
Vol.47 No.1 (January 2020) View: 1,405 Download:1,575

Ex-situ EBSD Study on the Abnormal Grain Growth in 6063 Aluminum Billet
page: 242 - 258
Author:Kanokwan Uttarasak, Wanchai Chongchitnan, Kenji Matsuda, Julathep Kajornchaiyakul and Chaiyasit Banjongprasert
Vol.47 No.2 (Special Issue I : March 2020) View: 1,046 Download:783

Purification of polycarbonate from aluminum by acid leaching for recycling waste compact discs
page: 693 - 702
Author:Cui Li, Hui Wang*, Yingshuang Zhang*
Vol.46 No.4 (July 2019) View: 851 Download:327

Poly(L-lactide)-Degrading Enzyme from Laceyella sacchari LP175: Cloning, Sequencing, Expression, Characterization and Its Hydrolysis of Poly(L-lactide) Polymer
page: 417 - 430
Author:Thanasak Lomthong, Marie Guicherd, Gianluca Cioci, Sophie Duquesne, Alain Marty, Saisamorn Lumyong and Vichien Kitpreechavanich
Vol.46 No.3 (May 2019) View: 925 Download:445

Kinetics of Ultrasound-assisted Extraction of Flavonoids and Triterpenes and Structure Characterization of Chinese Northeast Black Bee Propolis
page: 72 - 92
Author:Qingzhi Ding, Ricardo Antonio Wu-Chen, Qi Wu, Hanfei Jiang, Ting Zhang, Lin Luo, Haile Ma*, Shiqiao Ma and Ronghai He
Vol.46 No.1 (January 2019) View: 927 Download:413

Kinetic and Thermodynamic Studies of Cationic and Anionic Surfactants Adsorption onto Polyethyleneimine-modified Cotton Cloths
page: 2422 - 2437
Author:Sorapong Janhom
Vol.45 No.6 (September 2018) View: 924 Download:423

Disintegration Testing of Biodegradable Poly(L-lactide) / Thermoplastic Polyurethane Melt Blended Films
page: 2079 - 2091
Author:Kanyarat Suthapakti, Robert Molloy and Thanawadee Leejarkpai
Vol.45 No.5 (Special 2018) View: 882 Download:388

Thermal and Acid Activation (TAA) of Bentonite as Adsorbent for Removal of Methylene Blue: A Kinetics and Thermodynamic Study
page: 1770 - 1781
Author:Tarmizi Taher, Dedi Rohendi, Risfidian Mohadi and Aldes Lesbani
Vol.45 No.4 (July 2018) View: 941 Download:305

Effect of Microbial Consortia on Photosynthetic Efficiency of Arabidopsis thaliana under drought stress
page: 1 - 10
Author:Hazem M. Kalaji, Wasu Pathom-aree, Ramin Lotfi, Panchal Balaji, Nabil Elshery, Ewa Beata Grska, Michal Swiatek, Tomasz Horaczek, JacekMojski, Henryk Kociel, Michal Miroslaw Rytel and Sada Yoosathaporn
Vol.45 No.1 (January 2018) View: 841 Download:295

Investigation of Metastable Zone Width and Nucleation Kinetics of 2-cyanoguanidine by Cooling Crystallization
page: 1633 - 1645
Author:Ning Zhang, Yongsheng Ren*, Chengqi Liu and Haipeng Zhao
Vol.44 No.4 (October 2017) View: 823 Download:382

Theory of Doping in Indirect Determination of Concentration and Mobility of Native Point Defects in Metal Oxides
page: 365 - 374
Author:Zbigniew Grzesik
Vol.43 No.2 (SPECIAL ISSUE 1) View: 809 Download:251

Effect of Pectin Contents on Properties of Biodegradable Thermoplastic Mung Bean Starch/low-density Polyethylene Blends Using Injection Molding Technique
page: 215 - 225
Author:Jutarat Prachayawarakorn*[a,b] and Luxana Hommanee [a]
Vol.43 No.1 (JANUARY 2016) View: 852 Download:278

Kinetic Study of Reduction of N-[4-[Bis[4-dimethylamino)-phenyl]-methylene]-2,5-cyclohexadiene-1-ylidene]-methanaminium Chloride with Iodide in Aqueous Ethanol System
page: 963 - 971
Author:Maria Ashfaq, Rehana Saeed, Summyia Masood and Sameera Razi Khan
Vol.42 No.4 (OCTOBER 2015) View: 805 Download:243

Plasma Assisted Immobilization of TiO2 nanoparticles onto PLA Surface to Promote the Antimicrobial Activity
page: 1361 - 1374
Author:Chonlada Theerakarunwong*[a], Somruthai Tunma[b] and Dheerawan Boonyawan[c]
Vol.41 No.5/2 (OCTOBER 2014) View: 778 Download:241

Combustion of Moist Coal Briquettes
page: 35 - 42
Author:Prodpran Siritheerasas, Chomthida Chunniyom and Piyaporn Sethabunjong Putarat Nimmanpipug, Ancalee
Vol.35 No.1 (JANUARY 2008) View: 814 Download:307

Crystallization and Analysis of Perovskite Crystals in Ferroelectric-based Glasses
page: 427 - 436
Author:Pat Sooksaen, Jiraporn Hongart, Tippawan Arsawuth,and Utumporn Meesukon
Vol.35 No.3 (SEPTEMBER 2008) View: 806 Download:727

Search in this journal

Document Search

Author Search

A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z

Chiang Mai Journal of Science

Journal Volumes

JOURNAL DETAIL

Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide)

RELATED ARTICLE

Search in this journal

Popular Search

Chiang Mai Journal of Science