Submit your paper 
Download Template JOURNAL DETAIL
Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide)
Paper Type  |
Contributed Paper |
Title |
Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide) |
Author |
Wanich Limwanich [a], Sawarot Phetsuk [b], Puttinan Meepowpan [b], Nawee Kungwan [b], Winita Punyodom*[b] |
Email |
winitacmu@gmail.com |
|
Abstract: The non-isothermal melt crystallization kinetics of the synthesized poly(ε-caprolactone) (PCL) and poly(L-lactide) (PLL) with identical number average molecular weight (
 = 1.8´104) and polydispersity index (PDI = 1.8) was studied by differential scanning calorimetry (DSC). The crystallizations of PCL and PLL were performed under the cooling rates of 5.0, 7.5, 10.0 and 12.5 °C.min-1. From non-isothermal DSC analysis, the crystallization rates increased with increasing of the cooling rates, while the crystallization time decreased for both polymers. The Avrami, Ozawa and Liu models were applied to describe non-isothermal crystallization and determine kinetic parameters for PCL and PLL crystallizations. From Avrami, Ozawa and Liu models, the crystallization mechanism of PCL and PLL was nucleation with three dimensional growths. From Avrami, Liu and Friedman analysis, the synthesized PCL crystallized faster than PLL with the identical molecular weight and PDI value.
|
|
Start & End Page |
329 - 338 |
Received Date |
2015-09-15 |
Revised Date |
|
Accepted Date |
2015-11-01 |
Full Text |
Download |
Keyword |
crystallization, kinetics, differential scanning calorimetry (DSC), poly(L-lactide), poly(ε-caprolactone), biodegradable polymer |
Volume |
Vol.43 No.2 (SPECIAL ISSUE 1) |
DOI |
|
Citation |
[a] W.L., [b] S.P., [b] P.M., [b] N.K. and Punyodom*[b] W., Kinetics Studies of Non-Isothermal Melt Crystallization of Poly(ε-caprolactone) and Poly(L-lactide), Chiang Mai Journal of Science, 2016; 43(2): 329-338. |
SDGs |
|
| View:753 Download:256 | |
RELATED ARTICLE
Synthesis, Characterization and In Silico Biological and Anticancer Activity of 3-(2-Fluorophenyl)-N-(4-Fluorophenyl)- 7H-[1,2,4] Triazolo[3,4-b] [1,3,4] Thiadiazin-6-Amine
page: 377 - 386
Author:Fahad Hassan Shah, Balasaheb Daniyal Vanjare and Song Ja Kim
Vol.49 No.2 (March 2022) View: 926 Download:456
page: 377 - 386
Author:Fahad Hassan Shah, Balasaheb Daniyal Vanjare and Song Ja Kim
Vol.49 No.2 (March 2022) View: 926 Download:456
Investigation of the Initiating and Catalytic Behavior of Tri-n-butyltin(IV) n-Butoxide in Ring-Opening Polymerization of ε-Caprolactone and Transesterification of Poly(L-lactic acid)
page: 27 - 38
Author:Winita Punyodom, Puttinan Meepowpan, Boontharika Thapsukhon, Manita Dumklang and Wanich Limwanich
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,374 Download:322
page: 27 - 38
Author:Winita Punyodom, Puttinan Meepowpan, Boontharika Thapsukhon, Manita Dumklang and Wanich Limwanich
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,374 Download:322
SDGs:
Kinetic and Mechanistic Studies of Bulk Copolymerization of L-lactide and Glycolide Initiated by Liquid Tin(II) n-Butoxide
page: 489 - 505
Author:Tawan Chaiwon, Montira Sriyai, Puttinan Meepowpan, Robert Molloy, Kanarat Nalampang, Narin Kaabbuathong and Winita Punyodom*
Vol.48 No.2 (March 2021) View: 713 Download:411
page: 489 - 505
Author:Tawan Chaiwon, Montira Sriyai, Puttinan Meepowpan, Robert Molloy, Kanarat Nalampang, Narin Kaabbuathong and Winita Punyodom*
Vol.48 No.2 (March 2021) View: 713 Download:411
SDGs:
Property Enhancement of Polylactide Monofilaments by Cold-Drawing Process and Solvent Infusion
page: 323 - 331
Author:Jirawan Jindakaew, Chalita Ratanatawanate, Takeshi Kikutani, and Pakorn Opaprakasit*
Vol.48 No.2 (March 2021) View: 1,425 Download:1,144
page: 323 - 331
Author:Jirawan Jindakaew, Chalita Ratanatawanate, Takeshi Kikutani, and Pakorn Opaprakasit*
Vol.48 No.2 (March 2021) View: 1,425 Download:1,144
Ring-Opening Polymerization of ε-Caprolactone Using Soluble Tin(II) n-Butoxide-L-Lactide Macroinitiators
page: 312 - 322
Author:Manita Dumklang*, Wanich Limwanich, Sawarot Phetsuk, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 793 Download:398
page: 312 - 322
Author:Manita Dumklang*, Wanich Limwanich, Sawarot Phetsuk, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 793 Download:398
SDGs:
Tin(II) n-Hexoxide as New Initiator for the Ring-Opening Polymerization of ε-Caprolactone: Isoconversional Kinetics Analysis by Non-Isothermal DSC
page: 276 - 291
Author:Boontharika Thapsukhon*, Wanich Limwanich, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 802 Download:568
page: 276 - 291
Author:Boontharika Thapsukhon*, Wanich Limwanich, Puttinan Meepowpan and Winita Punyodom
Vol.48 No.2 (March 2021) View: 802 Download:568
SDGs:
Growth Kinetics of Iron Aluminide Layer on Hot-dip Aluminized AISI 304 Austenitic Stainless Steel
page: 319 - 328
Author:Payoon Senthongkaew, Laksamee Angkurarach and Patiphan Juijerm*
Vol.47 No.2 (Special Issue I : March 2020) View: 680 Download:370
page: 319 - 328
Author:Payoon Senthongkaew, Laksamee Angkurarach and Patiphan Juijerm*
Vol.47 No.2 (Special Issue I : March 2020) View: 680 Download:370
Modified Mangosteen Shell in the Removal of Hg (II) from Aqueous Solution-Isotherm and Kinetic Studies
page: 127 - 136
Author:Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy
Vol.47 No.1 (January 2020) View: 1,221 Download:1,527
page: 127 - 136
Author:Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy
Vol.47 No.1 (January 2020) View: 1,221 Download:1,527
Ex-situ EBSD Study on the Abnormal Grain Growth in 6063 Aluminum Billet
page: 242 - 258
Author:Kanokwan Uttarasak, Wanchai Chongchitnan, Kenji Matsuda, Julathep Kajornchaiyakul and Chaiyasit Banjongprasert
Vol.47 No.2 (Special Issue I : March 2020) View: 869 Download:708
page: 242 - 258
Author:Kanokwan Uttarasak, Wanchai Chongchitnan, Kenji Matsuda, Julathep Kajornchaiyakul and Chaiyasit Banjongprasert
Vol.47 No.2 (Special Issue I : March 2020) View: 869 Download:708
SDGs:
Purification of polycarbonate from aluminum by acid leaching for recycling waste compact discs
page: 693 - 702
Author:Cui Li, Hui Wang*, Yingshuang Zhang*
Vol.46 No.4 (July 2019) View: 679 Download:253
page: 693 - 702
Author:Cui Li, Hui Wang*, Yingshuang Zhang*
Vol.46 No.4 (July 2019) View: 679 Download:253
Poly(L-lactide)-Degrading Enzyme from Laceyella sacchari LP175: Cloning, Sequencing, Expression, Characterization and Its Hydrolysis of Poly(L-lactide) Polymer
page: 417 - 430
Author:Thanasak Lomthong, Marie Guicherd, Gianluca Cioci, Sophie Duquesne, Alain Marty, Saisamorn Lumyong and Vichien Kitpreechavanich
Vol.46 No.3 (May 2019) View: 717 Download:381
page: 417 - 430
Author:Thanasak Lomthong, Marie Guicherd, Gianluca Cioci, Sophie Duquesne, Alain Marty, Saisamorn Lumyong and Vichien Kitpreechavanich
Vol.46 No.3 (May 2019) View: 717 Download:381
Kinetics of Ultrasound-assisted Extraction of Flavonoids and Triterpenes and Structure Characterization of Chinese Northeast Black Bee Propolis
page: 72 - 92
Author:Qingzhi Ding, Ricardo Antonio Wu-Chen, Qi Wu, Hanfei Jiang, Ting Zhang, Lin Luo, Haile Ma*, Shiqiao Ma and Ronghai He
Vol.46 No.1 (January 2019) View: 698 Download:346
page: 72 - 92
Author:Qingzhi Ding, Ricardo Antonio Wu-Chen, Qi Wu, Hanfei Jiang, Ting Zhang, Lin Luo, Haile Ma*, Shiqiao Ma and Ronghai He
Vol.46 No.1 (January 2019) View: 698 Download:346
Kinetic and Thermodynamic Studies of Cationic and Anionic Surfactants Adsorption onto Polyethyleneimine-modified Cotton Cloths
page: 2422 - 2437
Author:Sorapong Janhom
Vol.45 No.6 (September 2018) View: 772 Download:378
page: 2422 - 2437
Author:Sorapong Janhom
Vol.45 No.6 (September 2018) View: 772 Download:378
Disintegration Testing of Biodegradable Poly(L-lactide) / Thermoplastic Polyurethane Melt Blended Films
page: 2079 - 2091
Author:Kanyarat Suthapakti, Robert Molloy and Thanawadee Leejarkpai
Vol.45 No.5 (Special 2018) View: 729 Download:329
page: 2079 - 2091
Author:Kanyarat Suthapakti, Robert Molloy and Thanawadee Leejarkpai
Vol.45 No.5 (Special 2018) View: 729 Download:329
Thermal and Acid Activation (TAA) of Bentonite as Adsorbent for Removal of Methylene Blue: A Kinetics and Thermodynamic Study
page: 1770 - 1781
Author:Tarmizi Taher, Dedi Rohendi, Risfidian Mohadi and Aldes Lesbani
Vol.45 No.4 (July 2018) View: 763 Download:250
page: 1770 - 1781
Author:Tarmizi Taher, Dedi Rohendi, Risfidian Mohadi and Aldes Lesbani
Vol.45 No.4 (July 2018) View: 763 Download:250
Effect of Microbial Consortia on Photosynthetic Efficiency of Arabidopsis thaliana under drought stress
page: 1 - 10
Author:Hazem M. Kalaji, Wasu Pathom-aree, Ramin Lotfi, Panchal Balaji, Nabil Elshery, Ewa Beata Grska, Michal Swiatek, Tomasz Horaczek, JacekMojski, Henryk Kociel, Michal Miroslaw Rytel and Sada Yoosathaporn
Vol.45 No.1 (January 2018) View: 688 Download:255
page: 1 - 10
Author:Hazem M. Kalaji, Wasu Pathom-aree, Ramin Lotfi, Panchal Balaji, Nabil Elshery, Ewa Beata Grska, Michal Swiatek, Tomasz Horaczek, JacekMojski, Henryk Kociel, Michal Miroslaw Rytel and Sada Yoosathaporn
Vol.45 No.1 (January 2018) View: 688 Download:255
Investigation of Metastable Zone Width and Nucleation Kinetics of 2-cyanoguanidine by Cooling Crystallization
page: 1633 - 1645
Author:Ning Zhang, Yongsheng Ren*, Chengqi Liu and Haipeng Zhao
Vol.44 No.4 (October 2017) View: 665 Download:344
page: 1633 - 1645
Author:Ning Zhang, Yongsheng Ren*, Chengqi Liu and Haipeng Zhao
Vol.44 No.4 (October 2017) View: 665 Download:344
Theory of Doping in Indirect Determination of Concentration and Mobility of Native Point Defects in Metal Oxides
page: 365 - 374
Author:Zbigniew Grzesik
Vol.43 No.2 (SPECIAL ISSUE 1) View: 662 Download:211
page: 365 - 374
Author:Zbigniew Grzesik
Vol.43 No.2 (SPECIAL ISSUE 1) View: 662 Download:211
Effect of Pectin Contents on Properties of Biodegradable Thermoplastic Mung Bean Starch/low-density Polyethylene Blends Using Injection Molding Technique
page: 215 - 225
Author:Jutarat Prachayawarakorn*[a,b] and Luxana Hommanee [a]
Vol.43 No.1 (JANUARY 2016) View: 679 Download:246
page: 215 - 225
Author:Jutarat Prachayawarakorn*[a,b] and Luxana Hommanee [a]
Vol.43 No.1 (JANUARY 2016) View: 679 Download:246
Kinetic Study of Reduction of N-[4-[Bis[4-dimethylamino)-phenyl]-methylene]-2,5-cyclohexadiene-1-ylidene]-methanaminium Chloride with Iodide in Aqueous Ethanol System
page: 963 - 971
Author:Maria Ashfaq, Rehana Saeed, Summyia Masood and Sameera Razi Khan
Vol.42 No.4 (OCTOBER 2015) View: 654 Download:210
page: 963 - 971
Author:Maria Ashfaq, Rehana Saeed, Summyia Masood and Sameera Razi Khan
Vol.42 No.4 (OCTOBER 2015) View: 654 Download:210
Plasma Assisted Immobilization of TiO2 nanoparticles onto PLA Surface to Promote the Antimicrobial Activity
page: 1361 - 1374
Author:Chonlada Theerakarunwong*[a], Somruthai Tunma[b] and Dheerawan Boonyawan[c]
Vol.41 No.5/2 (OCTOBER 2014) View: 613 Download:202
page: 1361 - 1374
Author:Chonlada Theerakarunwong*[a], Somruthai Tunma[b] and Dheerawan Boonyawan[c]
Vol.41 No.5/2 (OCTOBER 2014) View: 613 Download:202
Combustion of Moist Coal Briquettes
page: 35 - 42
Author:Prodpran Siritheerasas, Chomthida Chunniyom and Piyaporn Sethabunjong Putarat Nimmanpipug, Ancalee
Vol.35 No.1 (JANUARY 2008) View: 670 Download:224
page: 35 - 42
Author:Prodpran Siritheerasas, Chomthida Chunniyom and Piyaporn Sethabunjong Putarat Nimmanpipug, Ancalee
Vol.35 No.1 (JANUARY 2008) View: 670 Download:224
Crystallization and Analysis of Perovskite Crystals in
Ferroelectric-based Glasses
page: 427 - 436
Author:Pat Sooksaen, Jiraporn Hongart, Tippawan Arsawuth,and Utumporn Meesukon
Vol.35 No.3 (SEPTEMBER 2008) View: 653 Download:684
page: 427 - 436
Author:Pat Sooksaen, Jiraporn Hongart, Tippawan Arsawuth,and Utumporn Meesukon
Vol.35 No.3 (SEPTEMBER 2008) View: 653 Download:684
Copyrights © Since 2021 All Rights Reserved by Chiang Mai Journal of Science