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Disintegration Testing of Biodegradable Poly(L-lactide) / Thermoplastic Polyurethane Melt Blended Films


Paper Type 
Contributed Paper
Title 
Disintegration Testing of Biodegradable Poly(L-lactide) / Thermoplastic Polyurethane Melt Blended Films
Author 
Kanyarat Suthapakti, Robert Molloy and Thanawadee Leejarkpai
Email 
kanyarat.cmu@gmail.com
Abstract:
Poly(L-lactide) (PLL) has been blended with a polycaprolactone-based thermoplastic polyurethane (TPU) elastomer as a toughening agent for potential use as a biodegradable film packaging material. The effects of adding a synthesized poly(L-lactide-co-caprolactone) (PLLCL) copolymer as a compatibilizer was also studied. Both 2-component (PLL/TPU) and 3-component (PLL/TPU/PLLCL) blends were prepared by melt mixing, hot-pressed into thin films and their compostability characterized in a standard ISO disintegration test under controlled laboratory-scale conditions. The results showed that both the 2- and 3-component blended film samples (25 ด 25 mm) disintegrated completely (100%) to fragments less than 2 mm in size within 30 days. These results were similar to those for PLL alone which indicated that neither the TPU nor the PLLCL had retarding effects on the PLL’s biodegradability. It is concluded that both the PLL/TPU and PLL/TPU/PLLCL blends meet the criteria for disintegration and compostability under simulated composting conditions.     
Start & End Page 
2079 - 2091
Received Date 
2017-11-01
Revised Date 
Accepted Date 
2018-04-30
Full Text 
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Keyword 
Poly(L-lactide), thermoplastic polyurethane elastomer, poly(L-lactide-co-caprolactone, immiscible blend, disintegration test, compostability, biodegradable film
Volume 
Vol.45 No.5 (Special 2018)
DOI 
Citation 
Suthapakti K., Molloy R. and Leejarkpai T., Disintegration Testing of Biodegradable Poly(L-lactide) / Thermoplastic Polyurethane Melt Blended Films , Chiang Mai Journal of Science, 2018; 45(5): 2079-2091.
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