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Investigation of Metastable Zone Width and Nucleation Kinetics of 2-cyanoguanidine by Cooling Crystallization


Paper Type 
Contributed Paper
Title 
Investigation of Metastable Zone Width and Nucleation Kinetics of 2-cyanoguanidine by Cooling Crystallization
Author 
Ning Zhang, Yongsheng Ren*, Chengqi Liu and Haipeng Zhao
Email 
renys@nxu.edu.cn; ys-ren@126.com
Abstract:
Metastable zone widths (MSZW) of 2-cyanoguanidine in water, methanol, and ethanol are determined at different cooling rates ((6-30) K×h-1) using polythermal method, respectively. The metastable zone widths of solute in the three solvents increase linearly with the cooling rate increasing. Three nucleation theories are employed to estimate nucleation kinetic parameters based on measured MSZW data. The apparent nucleation order m is computed by Self-consistent Nývlt-like approach and Kubota’s model, which suggests that the nuclei are formed by instantaneous nucleation in methanol and ethanol, while the 2-cyanoguanidine nucleate in water shows the occurrence of progressive nucleation mechanism. The activation energy Esat for nucleation of crystals in solution also is estimated by Arrhenius-type equation.
Start & End Page 
1633 - 1645
Received Date 
2015-10-22
Revised Date 
Accepted Date 
2016-02-24
Full Text 
  Download
Keyword 
2-cyanoguanidine, metastable zone width, nucleation kinetics, model
Volume 
Vol.44 No.4 (October 2017)
DOI 
Citation 
Zhang N., Ren* Y., Liu C. and Zhao H., Investigation of Metastable Zone Width and Nucleation Kinetics of 2-cyanoguanidine by Cooling Crystallization , Chiang Mai Journal of Science, 2017; 44(4): 1633-1645.
View:774 Download:375

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