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Transformation of Lignin Model Compound and Lignin by Graphene Oxide Immobilized Laccase


Paper Type 
 Contributed Paper
Title 
 Transformation of Lignin Model Compound and Lignin by Graphene Oxide Immobilized Laccase
Author 
 Xue-Fei Zhou*
Email 
 lgdx602@sina.com
Abstract:

 In the present study, laccase (Lac) was immobilized into molecular sieves (Lac/NaY, Lac/

SSZ, Lac/MCM) and graphene oxide (Lac/GO). The activities of these laccase preparations were
comparatively studied on phenolic lignin model compound (vanillyl alcohol), nonphenolic lignin
model compound (veratryl alcohol) and organosolv lignin, in the presence of ABTS. GO immobilized
laccase (Lac/GO) afforded better performance in terms of conversion rate and reusability than the
molecular sieves during oxidation of vanillyl alcohol and veratryl alcohol. GPC and 31P-NMR were
used to characterize the structural modifications induced in the organosolv lignin. Compared to the
molecular sieves, the GO-immobilized laccase was found to be more reactive, displaying higher distinct
reaction selectivities in the oxidative pattern of the lignin.
Start & End Page 
 176 - 184
Received Date 
 2020-07-19
Revised Date 
Accepted Date 
 2020-10-04
Full Text 
   Download
Keyword 
 laccase, lignin model compound, immobilization, oxidation, lignin
Volume 
 Vol.48 No.1 (January 2021)
DOI 
Citation 
 Zhou X., Transformation of Lignin Model Compound and Lignin by Graphene Oxide Immobilized Laccase, Chiang Mai J. Sci., 2021; 48(1): 176-184.
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