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Synthesis and Characterization of Mechanochemically Synthesized Cobalt Oxide and Evaluation of its Catalytic Performance for Degradation of Congo Red Dye in Aqueous Medium


Paper Type 
Contributed Paper
Title 
Synthesis and Characterization of Mechanochemically Synthesized Cobalt Oxide and Evaluation of its Catalytic Performance for Degradation of Congo Red Dye in Aqueous Medium
Author 
Mohsin Siddique, Mohammad Ilyas and Muhammad Saeed
Email 
mohsin_phychem@bkuc.edu.pk
Abstract:
 

Catalytic oxidation/degradation of azo dye congo red (CR) was investigated at room temperature using lab synthesized cobalt oxide by a facile solid phase mechanochemical method. The catalyst was characterized by various techniques including X-Ray Diffraction (XRD), Fourier Transform Infrared (spectroscopy) (FT-IR), Scanning Electron Microscopy (SEM) and Surface area analysis. The catalyst showed excellent degradation ability in the presence of molecular oxygen and more than 85% of the dye was degraded in the first 10 minutes of the reaction at room temperature. It was observed that slight increase in the temperature enhances the degradation ability of the catalyst. The method of using cobalt oxide as catalyst shows many advantages including high degradation ratios, short reaction time, low cost; it may fit to deal with various other azo dyes in waste water on large scale.

Start & End Page 
1901 - 1908
Received Date 
2016-11-03
Revised Date 
Accepted Date 
2017-03-18
Full Text 
  Download
Keyword 
Cobalt Oxide, Azo dyes, Degradation, Congo Red, Oxidation
Volume 
Vol.45 No.4 (July 2018)
DOI 
Citation 
Siddique M., Ilyas M. and Saeed M., Synthesis and Characterization of Mechanochemically Synthesized Cobalt Oxide and Evaluation of its Catalytic Performance for Degradation of Congo Red Dye in Aqueous Medium, Chiang Mai Journal of Science, 2018; 45(4): 1901-1908.
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