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Synthesis of Porous Cobalt Doped Titania-Silica by Using Cattail Leaves as Template and its Catalytic Oxidation of Tertralin


Paper Type 
Contributed Paper
Title 
Synthesis of Porous Cobalt Doped Titania-Silica by Using Cattail Leaves as Template and its Catalytic Oxidation of Tertralin
Author 
Zhongbiao Zhai, Yingchun Miao*, Shanshan Yang, Yachong Yang, Jing Chen, Gang Xie and Shixiong Wang
Email 
miaoyingchun1979@126.com
Abstract:

 Cobalt doped titania-silica prepared by using cattail (Typha latifolia Linn) leaves as template

and aqueous TiOCl2 solution as titania source presented good product for the catalytic oxidation of
tetralin. The effects of reaction temperature, reaction time, catalyst concentration, and age of catalyst
were investigated. Under the optimum Ti/Si molar ratio: 0.6, reaction temperature: 370 k, reaction
time: 10 h, and the amount of catalyst: 5 0mg, cobalt doped titania-silica was used as a catalyst for the
oxidation of tetralin and exhibited high substrate conversion (97.6%) and good product (tetralon)
selectivity (78.5%). Recycling of the catalyst indicates that the catalyst can be used a number of times
without losing its activity to a greater extent.
Start & End Page 
207 - 220
Received Date 
2020-04-22
Revised Date 
Accepted Date 
2020-07-21
Full Text 
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Keyword 
selective oxidation, tetralin, tetralone, Co-TiO2-SiO2, cattail leaves
Volume 
Vol.48 No.1 (January 2021)
DOI 
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Chiang Mai Journal of Science

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