Submit your paper 
Download Template JOURNAL DETAIL
Iron Reduces Iron: A Spectroelectrochemical Insight of Ligand Effect on Iron Redox Potential
Paper Type  |
Contributed Paper |
Title |
Iron Reduces Iron: A Spectroelectrochemical Insight of Ligand Effect on Iron Redox Potential |
Author |
Shabnum Bashir, Mohammad Mustafa, Syed Wasim Safvi, Nisar Ahmad Farhad and Masood Ahmad Rizvi* |
Email |
masoodku2@gmail.com |
|
Abstract: The electron transfer reaction between two oxidation states of a transition metal redox couple is amazingly interesting. The present study describes a combined spectropho- tometric and potentiometric investigation of redox reaction involving iron (III) and iron(II) oxidation states. The electron transfer reaction is seen to occur between iron-(III)phenanthroline complex and a series of iron-(II) complexes with water, EDTA, DPTA, NTA, Tiron and diphosphate ligands. The relative propensity of selected ligands towards this reaction, displayed in the potentiometric titration plots can be corroborated with the redox potential modification of Fe(III)-Fe(II) redox couple. The ligand effect on redox potential of the iron redox couple as the underlying concept of the reaction, has been thoroughly investigated and thermodynamically modeled. The differing abilities of EDTA and Tiron ligands towards the spontaneity of this reaction under different pH conditions were potentiometerically observed and spectrophotometrically rationalized with the degree of ligand chelation vis-a-vis complex stability and the resultant redox potential. The experiment can serve as a model for unique environmental and biological redox reactions and can be explored further for designing of novel redox systems for redox flow cells. |
|
Start & End Page |
1087 - 1098 |
Received Date |
2017-01-04 |
Revised Date |
|
Accepted Date |
2017-03-28 |
Full Text |
Download |
Keyword |
Iron oxidation states, Ligand effect, Potentiometric titrations, Spectrophotometry, EDTA, DPTA, Tiron, Speciation analysis, Thermochemical cycle, Iron redox couple |
Volume |
Vol.45 No.2 (March 2018) |
DOI |
|
Citation |
Bashir S., Mustafa M., Safvi S.W., Farhad N.A. and Rizvi* M.A., Iron Reduces Iron: A Spectroelectrochemical Insight of Ligand Effect on Iron Redox Potential , Chiang Mai Journal of Science, 2018; 45(2): 1087-1098. |
SDGs |
|
| View:647 Download:440 | |
RELATED ARTICLE
Preparation of Gold Nanoparticles-Bacterial Cellulose Nanopaper and Its Application as 2D-Microcuvette for Spectrophotometric Determination of Hydrogen Peroxide
page: 185 - 195
Author:Aurachat Lert-itthiporn, Saranya Phunpruch, Munlika Prommajun, Pongpichet Srikritsadawong* and Nathawut Choengchan*
Vol.48 No.1 (January 2021) View: 702 Download:449
page: 185 - 195
Author:Aurachat Lert-itthiporn, Saranya Phunpruch, Munlika Prommajun, Pongpichet Srikritsadawong* and Nathawut Choengchan*
Vol.48 No.1 (January 2021) View: 702 Download:449
Mixed Micelle-mediated Cloud Point Extraction Coupled to Spectrophotometry for Fast Screening of Salbutamol in Wastewater, Pig Feed and Pork Samples
page: 542 - 553
Author:Jitlada Vichapong, Yanawath Santaladchaiyakit, Rodjana Burakham and Supalax Srijaranai
Vol.47 No.3 (May 2020) View: 752 Download:1,230
page: 542 - 553
Author:Jitlada Vichapong, Yanawath Santaladchaiyakit, Rodjana Burakham and Supalax Srijaranai
Vol.47 No.3 (May 2020) View: 752 Download:1,230
Determination of Cadmium in Vegetables by Sequential Injection Analysis Method Using 8-Hydroxyquinoline as Complexing Agent
page: 308 - 321
Author:Kanokwan Chaiyasing, Boonsom Liawruangrath, Surapol Natakankitkul, Sakchai Satienperakul, Wasan Sirisungworawong, Narabhats Rannurags and Saisunee Liawruangrath*
Vol.46 No.2 (March 2019) View: 1,750 Download:187
page: 308 - 321
Author:Kanokwan Chaiyasing, Boonsom Liawruangrath, Surapol Natakankitkul, Sakchai Satienperakul, Wasan Sirisungworawong, Narabhats Rannurags and Saisunee Liawruangrath*
Vol.46 No.2 (March 2019) View: 1,750 Download:187
Chemometric Profiling of Clinacanthus nutans Leaves Possessing Antioxidant Activities using Ultraviolet-visible Spectrophotometry
page: 1519 - 1530
Author:Hui Wen Chong, Khansa Rezaei, Bee Lynn Chew and Vuanghao Lim*
Vol.45 No.3 (May 2018) View: 684 Download:271
page: 1519 - 1530
Author:Hui Wen Chong, Khansa Rezaei, Bee Lynn Chew and Vuanghao Lim*
Vol.45 No.3 (May 2018) View: 684 Download:271
Standardization of Gardenia jasminoides Fruits and Crocin Content Analysis Using UV/visible Spectrophotometry
page: 1453 - 1462
Author:Onuma Zongram, Nijsiri Ruangrungsi, Chanida Palanuvej and Kanchana Rungsihirunrat*
Vol.44 No.4 (October 2017) View: 641 Download:389
page: 1453 - 1462
Author:Onuma Zongram, Nijsiri Ruangrungsi, Chanida Palanuvej and Kanchana Rungsihirunrat*
Vol.44 No.4 (October 2017) View: 641 Download:389
Effect of Morinda citrifolia Linn. leaf extracts on in vitro lipase activity
page: 1182 - 1193
Author:Aurasorn Saraphanchotiwitthaya*[a], Pattana Sripalakit [b]
Vol.41 No.5/1 (OCTOBER 2014) View: 1,082 Download:249
page: 1182 - 1193
Author:Aurasorn Saraphanchotiwitthaya*[a], Pattana Sripalakit [b]
Vol.41 No.5/1 (OCTOBER 2014) View: 1,082 Download:249
Simple Spectrophotometric Method for Determination of Iodine Value of Vegetable Oils
page: 419 - 426
Author:Thidarat Kruatian [a] and Kritsana Jitmanee*[a,b,c]
Vol.40 No.3 (JULY 2013) View: 695 Download:482
page: 419 - 426
Author:Thidarat Kruatian [a] and Kritsana Jitmanee*[a,b,c]
Vol.40 No.3 (JULY 2013) View: 695 Download:482
Application of Horseradish Peroxidase Mediated Oxidative Coupling Reaction for the Determination of Mesalazine
page: 551 - 559
Author:Shaik Shakeela, Bandakavi Sita Ram, Chandra Bala Sekaran
Vol.38 No.4 (OCTOBER 2011) View: 623 Download:232
page: 551 - 559
Author:Shaik Shakeela, Bandakavi Sita Ram, Chandra Bala Sekaran
Vol.38 No.4 (OCTOBER 2011) View: 623 Download:232
Copyrights © Since 2021 All Rights Reserved by Chiang Mai Journal of Science