Submit your paper 
Download Template JOURNAL DETAIL
Catalytic Oxidation of Glucose with Hydrogen Peroxide and Colloidal Gold as Pseudo-Homogenous Catalyst: A Combined Experimental and Theoretical Investigation
Paper Type  |
Contributed Paper |
Title |
Catalytic Oxidation of Glucose with Hydrogen Peroxide and Colloidal Gold as Pseudo-Homogenous Catalyst: A Combined Experimental and Theoretical Investigation |
Author |
Jitrayut Jitonnom [a] and Christoph Sontag *[a] |
Email |
c.sontag@web.de |
|
Abstract: Gold nanoparticles have been proved to act as oxidation catalyst for glucose oxidation, offering a “chemical” synthetic route to gluconic acid and gluconates - nowadays commercially produced by an enzyme catalyzed oxidation. Our investigations of the gold catalyzed oxidation route showed that gold nanoparticles produced by a modified Turkevich method have a high activity for this pseudo-homogenous catalytic reaction. Under mild reaction conditions, glucose could be oxidized in good yields (~70%) and the resulting gluconate could be isolated by column chromatography and precipitation as calcium salt. The catalytic oxidation reaction was found to follow the first-order kinetic with a rate constant of 4.95 h-1, in good agreement with previous finding. The underlying reaction mechanism is discussed, assuming that the formation of a gold-glucose cluster intermediate is a key catalytic step. Several structures of the gold-glucose intermediates were examined using density functional theory methods. The molecular behavior of glucose adsorption in gold colloid solution is present.
|
|
Start & End Page |
825 - 833 |
Received Date |
2013-07-10 |
Revised Date |
|
Accepted Date |
2014-04-25 |
Full Text |
Download |
Keyword |
colloidal gold catalyst, glucose oxidation, gold nanoparticle, gluconic acid, DFT |
Volume |
Vol.43 No.4 (JULY 2016) |
DOI |
|
Citation |
[a] J.J. and *[a] C.S., Catalytic Oxidation of Glucose with Hydrogen Peroxide and Colloidal Gold as Pseudo-Homogenous Catalyst: A Combined Experimental and Theoretical Investigation, Chiang Mai Journal of Science, 2016; 43(4): 825-833. |
SDGs |
|
| View:669 Download:433 | |
RELATED ARTICLE
Antioxidant and Cytotoxicity Activities of Butylated Hydroxytoluene Ligands Capped Gold Nanoparticles
page: 405 - 419
Author:Mohd Hafiz Ahmad, Wageeh A. Yehye, Noorsaadah Abd. Rahman, Lina A. Al-Ani, Mohd Rafie Johan, Jun Lu and Najihah M. Hashim*
Vol.48 No.2 (March 2021) View: 1,569 Download:444
page: 405 - 419
Author:Mohd Hafiz Ahmad, Wageeh A. Yehye, Noorsaadah Abd. Rahman, Lina A. Al-Ani, Mohd Rafie Johan, Jun Lu and Najihah M. Hashim*
Vol.48 No.2 (March 2021) View: 1,569 Download:444
Preparation of Gold Nanoparticles-Bacterial Cellulose Nanopaper and Its Application as 2D-Microcuvette for Spectrophotometric Determination of Hydrogen Peroxide
page: 185 - 195
Author:Aurachat Lert-itthiporn, Saranya Phunpruch, Munlika Prommajun, Pongpichet Srikritsadawong* and Nathawut Choengchan*
Vol.48 No.1 (January 2021) View: 702 Download:449
page: 185 - 195
Author:Aurachat Lert-itthiporn, Saranya Phunpruch, Munlika Prommajun, Pongpichet Srikritsadawong* and Nathawut Choengchan*
Vol.48 No.1 (January 2021) View: 702 Download:449
The DFT Study of Electronic and Optical Properties of the Surface Functional SiGe, GeSn and GeSn Nanostructures
page: 796 - 814
Author:Roohan Thirayatorn, Pornsawan Sikam, Pairot Moontragoon* and Zoran Ikonic
Vol.47 No.4 (Special Issue II : July 2020) View: 774 Download:424
page: 796 - 814
Author:Roohan Thirayatorn, Pornsawan Sikam, Pairot Moontragoon* and Zoran Ikonic
Vol.47 No.4 (Special Issue II : July 2020) View: 774 Download:424
Photophysical Properties of Various Substituted Thiophene-based Heterocyclic Chalcone: Experimental and DFT Studies
page: 1176 - 1190
Author:Nikorn Saengsuwan, Nutjarin Klinhom, Buchita Nakwanich, Suwannee Sriyab, Panida Prompinit, Songwut Suramitr, and Supa Hannongbua*
Vol.46 No.6 (November 2019) View: 944 Download:574
page: 1176 - 1190
Author:Nikorn Saengsuwan, Nutjarin Klinhom, Buchita Nakwanich, Suwannee Sriyab, Panida Prompinit, Songwut Suramitr, and Supa Hannongbua*
Vol.46 No.6 (November 2019) View: 944 Download:574
Computational Study of Structure and Photophysical Properties Relationship of Carbazoles with Four Anchoring Groups for DSSC: Consideration for Light Harvesting and Electron Injection
page: 1219 - 1228
Author:Yuly Kusumawati*, Atthar L. Ivansyah, Muhamad A. Martoprawiro and Linda W. Oktavia
Vol.46 No.6 (November 2019) View: 863 Download:768
page: 1219 - 1228
Author:Yuly Kusumawati*, Atthar L. Ivansyah, Muhamad A. Martoprawiro and Linda W. Oktavia
Vol.46 No.6 (November 2019) View: 863 Download:768
Gold Nanoparticles Decorated on Carbon Nanotube Modified Screen-printed Electrode for Flow Injection Amperometric Determination of Methyldopa
page: 537 - 546
Author:Jantima Upan, Suwaphid Themsirimongkon, Surin Saipanya and Jaroon Jakmunee
Vol.46 No.3 (May 2019) View: 776 Download:214
page: 537 - 546
Author:Jantima Upan, Suwaphid Themsirimongkon, Surin Saipanya and Jaroon Jakmunee
Vol.46 No.3 (May 2019) View: 776 Download:214
Determination of Inorganic Arsenic by Anodic Stripping Voltammetry with Gold Nanoparticles Modified Screen-printed Carbon Electrode and Anion Exchange Column Preconcentration
page: 106 - 117
Author:Pipoon Boonpeng, Ponlayuth Sooksamiti, Somchai Lapanantnoppakhun and Jaroon Jakmunee
Vol.46 No.1 (January 2019) View: 686 Download:306
page: 106 - 117
Author:Pipoon Boonpeng, Ponlayuth Sooksamiti, Somchai Lapanantnoppakhun and Jaroon Jakmunee
Vol.46 No.1 (January 2019) View: 686 Download:306
Gold-Nanoparticle-Based Fiber Optic Sensor for Sensing the Refractive Index of Environmental Solutions
page: 2168 - 2177
Author:Nongluck Houngkamhang, Sittan Charoensuwan, Onanong Sonthipakdee, Kawin Nawattanapaiboon, Armote Somboonkaew and Ratthasart Amarit
Vol.45 No.5 (Special 2018) View: 1,051 Download:380
page: 2168 - 2177
Author:Nongluck Houngkamhang, Sittan Charoensuwan, Onanong Sonthipakdee, Kawin Nawattanapaiboon, Armote Somboonkaew and Ratthasart Amarit
Vol.45 No.5 (Special 2018) View: 1,051 Download:380
Structural and Spectroscopic Properties of AlAs Diamondoids: An Approach to Nanocrystals and Bulk Properties
page: 547 - 555
Author:Mudar Ahmed Abdulsattar, Hayder M. Abduljalil and Mustafa Kamil Khaleel
Vol.45 No.1 (January 2018) View: 602 Download:223
page: 547 - 555
Author:Mudar Ahmed Abdulsattar, Hayder M. Abduljalil and Mustafa Kamil Khaleel
Vol.45 No.1 (January 2018) View: 602 Download:223
Protective Effect of Propolis Against Pulmonary Histological Alterations Induced by 10 nm Naked Gold Nanoparticles
page: 449 - 461
Author:Mansour I. Almansour* [a] and Bashir M. Jarrar [b]
Vol.44 No.2 (April 2017) View: 652 Download:185
page: 449 - 461
Author:Mansour I. Almansour* [a] and Bashir M. Jarrar [b]
Vol.44 No.2 (April 2017) View: 652 Download:185
Monodispersity and Stability of Gold Nanoparticles Stabilized by Using Polyvinyl Alcohol
page: 31 - 38
Author:Pichitchai Pimpang, Supab Choopun
Vol.38 No.1 (JANUARY 2011) View: 624 Download:185
page: 31 - 38
Author:Pichitchai Pimpang, Supab Choopun
Vol.38 No.1 (JANUARY 2011) View: 624 Download:185
Effect of Stabilizer on Preparation of Silver and Gold
Nanoparticle Using Grinding Method
page: 250 - 257
Author:Pichitchai Pimpang, Withun Sutham, Nikorn Mangkorntong, Pongsri Mangkorntong and Supab Choopun
Vol.35 No.2 (MAY 2008) View: 669 Download:315
page: 250 - 257
Author:Pichitchai Pimpang, Withun Sutham, Nikorn Mangkorntong, Pongsri Mangkorntong and Supab Choopun
Vol.35 No.2 (MAY 2008) View: 669 Download:315
Theoretical Study of the Bombyx mori Silk Surface
Functionalization: Quantum Mechanical Calculation
of the Glycine-Alanine Unit Reacting with Fluorine
and Molecular Dynamic Simulation of Wettability
page: 106 - 115
Author:Padungsee Khomhoi, Waleepan Sangprasert, Vannajan S. Lee, and Piyarat Nimmanpipug
Vol.37 No.1 (JANUARY 2010) View: 656 Download:216
page: 106 - 115
Author:Padungsee Khomhoi, Waleepan Sangprasert, Vannajan S. Lee, and Piyarat Nimmanpipug
Vol.37 No.1 (JANUARY 2010) View: 656 Download:216
Copyrights © Since 2021 All Rights Reserved by Chiang Mai Journal of Science