e-Journal Chiang Mai Journal of Science, Faculty of Science, Chiang Mai University
 







1.0
2023CiteScore
 
33rd percentile
Powered by  Scopus

SCImago Journal & Country Rank












Journal Volumes


Submit your paper
Download Template

  JOURNAL DETAIL



Applications of Oxidized Chitosan for Scale Prevention in Sugar Evaporators


Paper Type 
 Contributed Paper
Title 
 Applications of Oxidized Chitosan for Scale Prevention in Sugar Evaporators
Author 
 Tu Phuong Pham Le and Wanwipa Siriwatwechakul*
Email 
 wanwipa@siit.tu.ac.th
Abstract:
This study explores the potential use of oxidized chitosan (O.C) as an antiscalant for calcium oxalate (CaOx) and calcium sulfate (CaSO4), which are the main components of scales during sugar processing. Chitosan was selectively oxidized by NaClO/NaBr/TEMPO at pH 10.8 and 30 °C following the procedure by Yoo et al. [1]. The products have oxidation degrees ranging from 31 % to 77 % (by conductivity titration). The antiscaling performance of the O.C. was observed in comparison with a commercial antiscalant, Acumer1050, at the same antiscalant concentration (10 ppm) for two types of scales: CaOx and CaSO4. For CaOx scales, the O.C with 77 % degree of oxidation (O.C-77) shows the highest inhibition (72 %), whereas Acumer1050 and O.C-31 exhibit similar percent inhibition, 46 % and 36 %, respectively. However, in the presence of 13 % sugar (w/v), O.C-77 experiences a dramatic drop in performance to 30 % inhibition, but Acumer1050 only slightly decreases to 40 %. For CaSO4 scales, the results also show that the higher the oxidation degree, the better the antiscaling performance, with O.C-77 showing the highest percent inhibition (80 %) in aqueous solution, whereas Acumer1050 shows the best performance with 90 % inhibition. In 15 % sugar (w/v), the performance slightly drops to 75 % for Acumer1050 and 62 % for O.C-77. For CaOx, sugar strongly affects antiscaling performance of the high molecular weight O.C (O.C HMW), whereas the low molecular weight O.C (O.C LMW) shows consistent performance with increasing sugar concentration. For CaSO4, O.C HMW exhibits better performance, although for both, antiscaling performance is reduced with increasing sugar concentration. The different antiscaling performance may come from the different antiscaling mechanisms involved for CaOx and CaSO4. The results from SEM and XRD suggest that O.C binds with calcium ions to form a metal ion-polymer complex to prevent CaOx scales. On the other hand, O.C prefers to adsorb onto nuclei to prevent CaSO4 crystal growth. The results show that O.C can be a green alternative to the commercial antiscalant from a petroleum-based product.
Start & End Page 
 961 - 972
Received Date 
 2016-07-04
Revised Date 
Accepted Date 
 2016-11-13
Full Text 
   Download
Keyword 
 Oxidized chitosan, TEMPO, oxidation, calcium oxalate, calcium sulfate, bio-based antiscalants, sugar processing
Volume 
 Vol.45 No.2 (March 2018)
DOI 
Citation 
 Le T.P.P. and Siriwatwechakul* W., Applications of Oxidized Chitosan for Scale Prevention in Sugar Evaporators, Chiang Mai Journal of Science, 2018; 45(2): 961-972.
SDGs
View:715 Download:307

  RELATED ARTICLE

Exploring Microbiota and Metabolome Dynamics During the Production of Dried Salted Mackerel (Pneumatophorus japonicus)
Article ID: e2025022
Author:Mingjia Yu, Jiannan Liu, Xiaobo Wang, Ming Qi and Minfu Wu
Vol.52 No.2 (March 2025) View: 158 Download:66
Anatomical Characteristics of Leaf and Petiole and Presence of Calcium Oxalate Crystals in Giant Elephant Ear (Colocasia gigantea (Blume) Hook. f.)
Article ID: e2025016
Author:Yupadee Paopun, Piyanan Thanomchat and Nustsaba Kronburee
Vol.52 No.2 (March 2025) View: 187 Download:52
Spatio-temporal Prediction of Air Quality Using Spatio-temporal Clustering and Hierarchical Bayesian Model
Article ID: e2024083
Author:Feiyun Wang, Yao Hu and Yutao Qin
Vol.51 No.5 (September 2024) View: 480 Download:260
Formation of High Hardness ZnO/Cu Nanocomposite by Thermal Oxidation from Cu-Zn Alloy Strips
Article ID: e2024045
Author:Minh-Tan Ha, Pham Mai Khanh and Nguyen Hong Hai
Vol.51 No.3 (May 2024) View: 569 Download:458
Liquid Phase Styrene Epoxidation Catalyzed by Rice Husk Ash Silica Derived Mesoporous Calcium Silicate and Calcite-type Calcium Carbonate Catalyst
page: 611 - 630
Author:Anwar Iqbal*, Kok-Hou Tan, Farook Adam, Noor Hana Hanif Abu Bakar, Mohammad Norazmi Ahmad and Muhammad Rahimi Yusop*
Vol.48 No.2 (March 2021) View: 1,248 Download:438
Synthesis of Porous Cobalt Doped Titania-Silica by Using Cattail Leaves as Template and its Catalytic Oxidation of Tertralin
page: 207 - 220
Author:Zhongbiao Zhai, Yingchun Miao*, Shanshan Yang, Yachong Yang, Jing Chen, Gang Xie and Shixiong Wang
Vol.48 No.1 (January 2021) View: 787 Download:274
Transformation of Lignin Model Compound and Lignin by Graphene Oxide Immobilized Laccase
page: 176 - 184
Author:Xue-Fei Zhou*
Vol.48 No.1 (January 2021) View: 707 Download:385
Biomimetic One-Pot Mediated Oxygenolysis of Dibenzodioxocin Lignin Model and Organosolv Lignin Using M([H4]salen) Complexes
page: 1230 - 1240
Author:Xue-Fei Zhou
Vol.47 No.6 (November 2020) View: 634 Download:206
Catalytic Activity of Bimetallic Au@Pt Core-Shell Over CeO2-Al2O3 for CO Oxidation Reaction
page: 278 - 287
Author:Wichet Lamai and Akkarat Wongkaew*
Vol.47 No.2 (Special Issue I : March 2020) View: 1,550 Download:682
Factors Affecting Phytoplankton Removal by Electro-Oxidation of Artificial Seawater
page: 255 - 259
Author:Niwooti Whangchai*, Nakao Nomura and Masatoshi Matsumura
Vol.30 No.3 (DECEMBER 2003) View: 639 Download:191
Enhanced Growth and Ethanol Oxidation by Overexpressed caiA Gene Encoding acyl-CoA Dehydrogenase in Komagataeibacter medellinensis NBRC 3288
page: 196 - 206
Author:Phisurang Konjanda, Toshiharu Yakushi, Kazunobu Matsushita and Gunjana Theeragool
Vol.46 No.2 (March 2019) View: 740 Download:247
Photocatalysis Using Titanium Dioxide for Treatment of Textile Wastewater Containing Disperse Dyes
page: 2730 - 2739
Author:Shumaila Kiran, Sofia Nosheen, Sarosh Iqbal, Shazia Abrar, Fatima Jalal, Tahsin Gulzar, Ammara Mukhtar, Shumaila Maqsood, Waqas Ahmad and Nabigha Naseer
Vol.45 NO.7 (November 2018) View: 696 Download:256
Phytochemical Investigation and Antioxidant Properties of Different Extracts from Artabotrys harmandii Finet & Gagnep
page: 2338 - 2347
Author:Wararut Bunchareon, Supaporn Pamok, Supap Saenphet and Kanokporn Saenphet
Vol.45 No.6 (September 2018) View: 763 Download:353
Synthesis and Characterization of Mechanochemically Synthesized Cobalt Oxide and Evaluation of its Catalytic Performance for Degradation of Congo Red Dye in Aqueous Medium
page: 1901 - 1908
Author:Mohsin Siddique, Mohammad Ilyas and Muhammad Saeed
Vol.45 No.4 (July 2018) View: 762 Download:225
Simple Medium Formulation for Manganese Remediation by Green Microalga Pediastrum duplex AARLG060
page: 1247 - 1256
Author:Jakkapong Thongpitak, Jeeraporn Pekkoh and Chayakorn Pumas*
Vol.45 No.3 (May 2018) View: 888 Download:273
Iron Reduces Iron: A Spectroelectrochemical Insight of Ligand Effect on Iron Redox Potential
page: 1087 - 1098
Author:Shabnum Bashir, Mohammad Mustafa, Syed Wasim Safvi, Nisar Ahmad Farhad and Masood Ahmad Rizvi*
Vol.45 No.2 (March 2018) View: 656 Download:447
Toluene Oxidation using K-OMS 2 Synthesized Via Hydrothermal Process by Central Composite Design
page: 1030 - 1038
Author:Jessa Marie Millanar, Mark Daniel de Luna, Aummara Yodsa-nga and Kitirote Wantala*
Vol.45 No.2 (March 2018) View: 738 Download:177
In vitro Antioxidant Evaluation of Wood Vinegars from Carbonization of Wood and Bamboo
page: 868 - 880
Author:Yongyuth Theapparat*, Chanita Ponglimanont, Ausa Chandumpai and Nikhom Laemsak
Vol.45 No.2 (March 2018) View: 699 Download:297
In vitro Anti-aging Activities of Centotheca lappacea (L) desv. (Ya Repair) Extract
page: 846 - 857
Author:Thavatchai Kamoltham, Jiradej Manosroi, Charinya Chankhampan, Worapaka Manosroi and Aranya Manosroi*
Vol.45 No.2 (March 2018) View: 839 Download:580
Proliferation of Embryogenic Callus of Oil Palm (Elaeis guineensis Jacq.) Using Different Culture Systems and Genetic Instability Assay by Simple Sequence Repeat (SSR) Technique
page: 784 - 796
Author:Stapaporn Kerdsuwan and Sompong Te-chato*
Vol.45 No.2 (March 2018) View: 665 Download:201
Properties of Plasticized Polylactic Acid Films with Epoxidized Rubber Seed Oil
page: 1591 - 1600
Author:Jutamas Kantee and Somjai Kajorncheappunngam*
Vol.44 No.4 (October 2017) View: 679 Download:304
Total Phenolic and Ascorbic Acid Contents and Antioxidant Activities of Twelve Different Ecotypes of Phyllanthus emblica from Pakistan
page: 904 - 911
Author:Syed Mubashar Sabir*, Rashad Hussain Shah and Asad Hussain Shah
Vol.44 No.3 (July 2017) View: 706 Download:292
Lipid Peroxidation of Escherichia coli by Triplet Non-thermal Atmospheric Pressure Plasma Jet
page: 678 - 687
Author:A. Hossienzadeh Colagar* [a,b], O. Alavi [a], F. Sohbatzadeh [b, c]
Vol.44 No.2 (April 2017) View: 676 Download:195
Temporal Fuzzy Case-based Reasoning Retrieval
page: 267 - 278
Author:Tawin Tanawong
Vol.44 No.1 (JANUARY 2017) View: 634 Download:224
Catalytic Oxidation of Glucose with Hydrogen Peroxide and Colloidal Gold as Pseudo-Homogenous Catalyst: A Combined Experimental and Theoretical Investigation
page: 825 - 833
Author:Jitrayut Jitonnom [a] and Christoph Sontag *[a]
Vol.43 No.4 (JULY 2016) View: 684 Download:439
Successive Reduction for Preparation of Various PdxPty-MWCNTs Catalysts for Formic Acid Oxidation
page: 600 - 609
Author:Pitak Wongthep [a], Paralee Waenkaew [a, b], Thapanee Sarakonsri [a, b], Somchai Lapanantnoppakhun [a, c] and Surin Saipanya*[a, b]
Vol.43 No.3 (APRIL 2016) View: 661 Download:334
Theory of Doping in Indirect Determination of Concentration and Mobility of Native Point Defects in Metal Oxides
page: 365 - 374
Author:Zbigniew Grzesik
Vol.43 No.2 (SPECIAL ISSUE 1) View: 675 Download:215
Ameliorating Reactive Oxygen Species-Induced in vitro Lipid Peroxidation in Liver, Carbohydrate and DNA Damage by Dendrocalamus hamiltonii Different Leaf Extracts
page: 80 - 88
Author:Arvind Kumar Goyal [a,b], Sushil Kumar Middha [c], Talambedu Usha [c] and Arnab Sen*[a]
Vol.43 No.1 (JANUARY 2016) View: 707 Download:158
Preparation of Pt/ATO Catalysts for Electrocatalysis in Direct Alcohol Fuel Cell
page: 169 - 175
Author:Li Fang *[a], Surin Saipanya *[b,c], Xuemei Luo [a], Xiaoping Huang [a] and Feifei Li [a]
Vol.43 No.1 (JANUARY 2016) View: 683 Download:213
Morphology and Catalytic Activity of Gold Core-Platinum Shell Nanoparticles
page: 481 - 489
Author:Kontee Thongthai, Laongnuan Srisombat, Surin Saipanya and Supon Ananta
Vol.42 No.2 (APRIL 2015) View: 649 Download:233
Characteristics of Microstructure, Microhardness, and Oxidation of FSW and MIG Welded Steels
page: 831 - 838
Author:Seul Ki Kim, Seung Boo Jung and Dong Bok Lee*
Vol.40 No.5 SPECIAL ISSUE 1 View: 634 Download:241
Antioxidant Potential of Pleurotus porrigens Extract and Application in Sunflower Oil during Accelerated Storage
page: 34 - 48
Author:Hip Seng Yim*[a, b], Fook Yee Chye [b], Mei Lian Liow [a], and Chun Wai Ho [a]
Vol.40 No.1 (JANUARY 2013) View: 707 Download:253
In vitro INHIBITION OF LIPID PEROXIDATION AND THE ANTIOXIDANT SYSTEM OF ENDOPHYTIC FUNGI FROM THAI MEDICINAL PLANTS
page: 429 - 444
Author:Teerayut Theantana [a,b], Duangta Kanjanapothi [c], Saisamorn Lumyong* [b]
Vol.39 No.3 (JULY 2012) View: 707 Download:194
Comparative Analysis of Aqueous Extracts of Amaranth and Coriander in Scavenging Free Radical Activity and Protection of DNA against Oxidative Damage
page: 560 - 571
Author:Asmita Dutta and Mukesh Singh
Vol.38 No.4 (OCTOBER 2011) View: 679 Download:291
Stability of Vancomycin 31 mg/mL in Extemporaneous Eye Drops Determined with Capillary Electrophoresis
page: 533 - 540
Author:Anutra Khangtragool, Sineenart Santidherakul and Phuriwat Leesawat
Vol.38 No.4 (OCTOBER 2011) View: 739 Download:393
Effect of Solution on Growth of Zinc Oxide Tetrapod by Thermal Oxidation Technique
page: 187 - 192
Author:Chawalit Bhoomanee, Niyom Hongsith, Ekasiddh Wongrat, Supab Choopun, and Duangmanee Wongratanaphisa
Vol.38 No.2 (APRIL 2011) View: 650 Download:196
Zinc Oxide Whiskers by Thermal Oxidation Method
page: 39 - 46
Author:Kiattipoom Kongjai, Supab Choopun, Niyom Hongsith, Atcharawon Gardchareon
Vol.38 No.1 (JANUARY 2011) View: 687 Download:199
Applying of Aluminium Deoxidation in Iron Roll Casting
page: 196 - 198
Author:Teerapong Harnwirojkul, Mana Polboon, John Pearce and Thanaporn Korad
Vol.35 No.1 (JANUARY 2008) View: 655 Download:260
Effect of Cerium Oxide and Zirconium Oxide to Activity of Catalysts
page: 156 - 162
Author:Akkarat Wongkaew
Vol.35 No.1 (JANUARY 2008) View: 655 Download:273
A New Analytical Expression of the Gas Conversion for TAP Experiments with Bimodal-Pore-Structure Catalyst
page: 150 - 155
Author:Wisuthchai Boonwatcharapunsakul and Phungphai Phanawadee
Vol.35 No.1 (JANUARY 2008) View: 603 Download:213
Degradation of Congo Red Dye by Ozonation
page: 63 - 68
Author:Thirachitra Tapalad, Arthit Neramittagapong, Sutasinee Neramittagapong and Mallika Boonmee
Vol.35 No.1 (JANUARY 2008) View: 3,116 Download:309
Aluminization of High Purity Nickel by Powder Liquid Coating
page: 331 - 339
Author:Patama Visuttipitukul, Nantiya Limvanutpong, Niti Yongvanich, Prasonk Srichroenchai and Panyawat Wan
Vol.36 No.3 (SEPTEMBER 2009) View: 646 Download:278
Synthesis and Characterisation of Poly(2-hydroxyethyl methacrylate-co-methyl acrylate) Hydrogels for Use as Temporary Skin Substitutes
page: 71 - 82
Author:Tiwaporn Siriwittayakorn [a], Nantarat Suebsanit [a], Robert Molloy [a], Paisit Siriwittayakorn [b] and Malinee Prasitsilp [c]
Vol.28 No.2 (DECEMBER 2001) View: 690 Download:229



Search in this journal


Document Search


Author Search

A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z

Popular Search






Chiang Mai Journal of Science

Faculty of Science, Chiang Mai University
239 Huaykaew Road, Tumbol Suthep, Amphur Muang, Chiang Mai 50200 THAILAND
Tel: +6653-943-467




Faculty of Science,
Chiang Mai University




EMAIL
cmjs@cmu.ac.th




Copyrights © Since 2021 All Rights Reserved by Chiang Mai Journal of Science