Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

2,424
Articles
Q3 0.80
Impact Factor
Q2 1.6
CiteScore
7 days
Avg. First Decision
Outline
Figures and Tables
ARTICLE METRICS
Views 1,622
Downloads 413

Adsorption of a Highly Toxic Aromatic Pollutant From Aqueous Solution Using Low Cost Activated Carbon: Equilibrium, Kinetic and Thermodynamic Aspects

Muhammad Hamayun*, Sonia Sherazi, Shah Zareen, Abdul Naeem, Muhammad Saeed, Khizar Hussain Shah, Ataf Ali Altaf, Shahzad Murtaza and Muhammad Zubair
* Author for corresponding; e-mail address: hamayunf@uog.edu.pk
Volume: Vol.45 No.3 (May 2018)
Research Article
DOI:
Received: 14 August 2016, Revised: -, Accepted: 25 Febuary 2017, Published: -

Citation: Hamayun M., Sherazi S., Zareen S., Naeem A., Saeed M., Shah K.H., et al., Adsorption of a Highly Toxic Aromatic Pollutant From Aqueous Solution Using Low Cost Activated Carbon: Equilibrium, Kinetic and Thermodynamic Aspects, Chiang Mai Journal of Science, 2018; 45(3): 1471-1485.

Abstract

Peanut husk (agricultural waste) was used as a precursor for the development of activated carbons by chemical activation with H3PO4 abbreviated as H3PO4-APHDC [Phosphoric acid Activated Peanut Husk Derived Carbon] and by physical activation with CO2 designated as CO2-APHDC [Carbon dioxide Activated Peanut Husk Derived Carbon]. Both H3PO4-APHDC and CO2-APHDC were found to have a high BET surface area of 1070.766 and 960.931 m2g-1. The prepared activated carbons were tested for the removal of a highly toxic aromatic compound (pyridine). Batch experiments were performed for the detoxification of notorious pyridine from aqueous solution as a function of various experimental parameters like effect of initial pH, contact time, initial concentration and temperature. Maximum adsorption of pyridine was observed in the pH range of 8-10 where 83.66% pyridine adsorption was observed at pH 9.0 by H3PO4-APHDC and 72.13% by CO2- APHDC. The rate limiting step in the adsorption kinetics data was interpreted by intraparticle and Boyd models which suggested film diffusion to be the rate controlling step. Langmuir isotherm model fitted well with the adsorption isotherm data. The adsorption capacities were found to increase with the increase in temperature indicating that adsorption is favorable at high temperature. Different thermodynamic parameters were evaluated which showed that the adsorption process was feasible, spontaneous and endothermic in nature. 

Keywords: peanut husk, phosphoric acid, activated carbon, pyridine, adsorption, langmuir

Related Articles

Adsorption Performance of Spherical Porous SiO2 on Heavy Metal Cu2+ in Wastewater
DOI: 10.12982/CMJS.2025.075.

Yan-Min Chen, Zhen-Zhen Chen, Bei-Bei Qi, Ye-Xuan Cai, Jia-Meng Li and Yi-Fan Han

Vol.52 No.5 (September 2025)
Research Article View: 1,406 Download: 121
Barite Adsorption Efficiency for Removal of Mannose. Experimental Measurements and Equilibrium Study
DOI: 10.12982/CMJS.2025.034.

Mustafa Jaip Allah Abdelmageed Abualreish

Vol.52 No.3 (May 2025)
Research Article View: 628 Download: 274
A Rhizobacterium Kitasatospora nipponensis Demonstrates Antifungal Activity against Basal Stem Rot Disease and Promotes Plant Growth in Oil Palm (Elaeis guineensis) Seedlings
DOI: 10.12982/CMJS.2025.033.

Anurag Sunpapao, Supaporn Pithakkit and Prisana Wonglom

Vol.52 No.3 (May 2025)
Research Article View: 1,081 Download: 363
Removal of Chromium (III) Heavy Metal Ions from Aqueous Solutions by Green Synthesized Calix[6]arene
DOI: 10.12982/CMJS.2025.005.

Susy Yunita Prabawati, Nina Hamidah and Afifah Mufidati

Vol.52 No.1 (January 2025)
Research Article View: 979 Download: 379
H2S Removal from Biogas using Steel Wool (Fe2O3) Adsorption Combined with Water Absorption: Experimental and Modelling via RSM
DOI: 10.12982/CMJS.2024.027.

Jiraporn Paoaiang, Prukraya Pongyeela, Nirana Chairerk and Juntima Chungsiriporn

Vol.51 No.2 (March 2024)
Research Article View: 1,866 Download: 1,780
Water-based Synthesis of MIL-53(Al) at Room Temperature: An Effective Adsorbent for Oxytetracycline (OTC) Antibiotic Removal from Water
DOI: 10.12982/CMJS.2024.010.

Parnuch Hongsawat, Phuri Kalnaowakul and Panida Prarat

Vol.51 No.1 (January 2024)
Research Article View: 1,980 Download: 667
Development and Optimization of an Amperometric Bi-enzyme Biosensor for Aspartame Determination
DOI: 10.12982/CMJS.2023.064.

Tanaporn Tangtawewipat and Saipin Thanachasai

Vol.50 No.6 (November 2023)
Research Article View: 1,460 Download: 597
Preparation of Porous Silica Nanoparticles by Chemical Etching for Removal of Paraquat from Aqueous Solution
DOI: 10.12982/CMJS.2023.009.

Kanokwan Darasoon, Supawitch Hoijang, Tanapong Kunakham, Sorapong Janhom, Supon Ananta, Gyu Leem and Laongnuan Srisombat

Vol.50 No.1 (January 2023)
Research Article View: 1,833 Download: 1,221
Hydrochar from Lansium domesticum and Salacca zalacca Peel as Adsorbent on Rhodamine-B Removal: Adsorption Process and Regeneration Studies
DOI: 10.12982/CMJS.2022.108.

Mauizatul Hasanah, Alfan Wijaya, Risfidian Mohadi, Fitri Suryani Arsyad and Aldes Lesbani

Vol.49 No.6 (November 2022)
Research Article View: 1,875 Download: 458
2-Methylimidazole-modified Iron Metal-organic Framework as an Efficient Methylene Blue Adsorbent
DOI: 10.12982/CMJS.2022.104.

Yingxin Zhao, Hao Hu, Shengyu Zhang, Shiya Feng, Yun Yang, Xiongjian Li and Shuijin Yang

Vol.49 No.6 (November 2022)
Research Article View: 1,831 Download: 492
Process Optimization and Modeling of Low-cost Activated Carbon Preparation and Its Application in Chromium(VI) Removal
DOI: 10.12982/CMJS.2022.100.

Theeradit Phothitontimongkol and Kanyarak Prasertboonyai

Vol.49 No.6 (November 2022)
Research Article View: 1,755 Download: 544
Sorption Studies of Cesium on Kunipia-F Bentonite and Silicon Dioxide
DOI: 10.12982/CMJS.2022.093.

Anan O-Manee, Youichi Enokida and Kayo Sawada

Vol.49 No.5 (September 2022)
Research Article View: 1,821 Download: 647
Cigarette Butts Valorization: Activated Hydrochar for Methylene Blue Removal
DOI: 10.12982/CMJS.2022.062.

Naphatsarnan Phasukarratchai, Budsarin Yattipat, Parichat Muengkrajang, Sasishai Permpoon and Alissara Reungsang

Vol.49 No.4 (July 2022)
Research Article View: 2,070 Download: 1,315
Non-Covalent Interactions between Graphene and Cluster of Ruthenium Oxides and Vanadium Oxides : A Dispersioncorrected Density Functional Theory Study
page: 1606 - 1619

Paphawarin Kheownil, Parameat Seesopha, Sawitree Chuaychoocherd, Panichakorn Jaiyong and Yuthana Tantirungrotechai

Vol.48 No.6 (November 2021)
Research Article View: 1,742 Download: 948
Density Functional Theory Study of Methane Adsorption on LaCoO3 (001) Surface
page: 1645 - 1656

Xuefeng Wang, Hongyan Zhang,Cunbao Deng, Ling Qiao and Shuangli Du

Vol.48 No.6 (November 2021)
Research Article View: 1,715 Download: 493
Preparation of Cattail-derived Activated Carbon and Its Adsorption Performance toward Ibuprofen and Diclofenac in Water
page: 1538 - 1554

Suhua Han, Qiannan Cao, Dongxu Qian, Ye Yang and Minbo Lu

Vol.48 No.6 (November 2021)
Research Article View: 1,732 Download: 334
Intercalated Zn-Cr-[α-SiW12O40] as Removal Agents of Cobalt (II) in Watery Phase: Adsorption and Regeneration Study
page: 545 - 556

Luna Silaen, Neza Rahayu Palapa, Elfita, Risfidian Mohadi and Aldes Lesbani

Vol.48 No.2 (March 2021)
Research Article View: 1,626 Download: 389
A Novel Polyacrylamide-divinylbenzene Functionalized Fe3O4/Coconut Shell Adsorbent with Superior Capacity for Removal of Acridine Orange
page: 520 - 532

Huan Wang*, Wei Zhao, Youning Chen, Xiaoling Yang and Xiaohua Meng

Vol.48 No.2 (March 2021)
Research Article View: 1,450 Download: 356
A Novel Acrylic Intercalated Hydrotalcite for the Removal of Heavy Metal Ions from Aqueous Solution: Isotherm, Kinetics, Thermodynamics and Mechanism
page: 1055 - 1067

Wei Zhao, Youning Chen and Yuhong Li

Vol.47 No.5 (September 2020)
Research Article View: 1,576 Download: 426
Batch Removal of Pb (II) from Aqueous Solution using Activated Carbon Prepared from Mangosteen Shell Activated with H2SO4
page: 554 - 566

Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy

Vol.47 No.3 (May 2020)
Research Article View: 1,809 Download: 640
Adsorption of 2,4-Dichlorophenoxyacetic acid by Magnesium Ferrite Magnetic Nanoparticles Modified with Amine Functional Groups
page: 137 - 146

Supawitch Hoijang, Jeeranan Nonkumwong, Burapol Singhana, Sunanta Wangkarn, Supon Ananta and Laongnuan Srisombat

Vol.47 No.1 (January 2020)
Research Article View: 1,691 Download: 487
Modified Mangosteen Shell in the Removal of Hg (II) from Aqueous Solution-Isotherm and Kinetic Studies
page: 127 - 136

Anitha Devasahayam, Ramadevi Abbai Ramanujam and Seetharaman Ramasamy

Vol.47 No.1 (January 2020)
Research Article View: 1,642 Download: 1,599
Prospective Sorption Evaluation of Hydrothermally Carbonized Lepironia Articulata (Grey sedge) for the Removal of Ni (II) from Aqueous Solution
page: 2220 - 2231

Asadullah, Lupong Kaewsichan and Kanogwan Tohdee

Vol.45 No.5 (Special 2018)
Research Article View: 1,618 Download: 609
Achieving Adsorption of Cationic Dyes by the Composites Based on H3PMo12O40 Decorating Metal Organic Frameworks
page: 1486 - 1498

Wenpeng Gong, Xiaogang Du, Xiaoxia Liu, Xiaofen Ke and Shuijin Yang*

Vol.45 No.3 (May 2018)
Research Article View: 1,704 Download: 374
Preparation of Eco-friendly and Low-cost Activated Carbon from Gracilaria corticata Seaweeds for the Removal of Crystal Violet Dye from Aqueous Solution: Equilibrium and Modeling Studies
page: 1039 - 1051

Duraipandian Jayganesh, Rengasamy Tamilarasan*, Muthiyan Kumar, Mani Murugavelu and Vadivelu Sivakumar

Vol.45 No.2 (March 2018)
Research Article View: 1,641 Download: 343
Preparation and Properties of Activated Carbon from Palm Shell by Potassium Hydroxide Impregnation: Effects of Processing Parameters
page: 462 - 473

Sathaporn Bhungthong, Darunee Aussawasathien, Kittipong Hrimchum and Sa-Nguansak Sriphalang

Vol.45 No.1 (January 2018)
Research Article View: 973 Download: 543
Laboratory-based Investigation into the Removal Behaviour of Asphalt in Porous Asphalt Mixture on Zinc Ions from Road Runoff
page: 1601 - 1610

Yao Zhao*, Chen Zhao, Kelly Hill and Xun Qian Xu

Vol.44 No.4 (October 2017)
Research Article View: 1,598 Download: 312
Removal of p-Nitrophenol from Aqueous Solution Using Synthesized Silica-Magnetite Composite
page: 1028 - 1039

Adekola F.A.*, Orimolade B.O.** and Adebayo G.B.

Vol.44 No.3 (July 2017)
Research Article View: 1,662 Download: 404
Effects of Processing Parameters on Properties of Activated Carbon from Palm Shell: Sodium Hydroxide Impregnation
page: 544 - 556

Sathaporn Bhungthong [a], Darunee Aussawasathien* [b], Kittipong Hrimchum [b] and Sa-Nguansak Srip

Vol.44 No.2 (April 2017)
Research Article View: 968 Download: 566
Characteristics and Stability of the Phosphoric Acid-tributyl Phosphate Emulsions
page: 518 - 532

Yuqing Cao, Yang Jin*, Jun Li, Da Zou and Yujing Ma

Vol.44 No.2 (April 2017)
Research Article View: 998 Download: 566
Evaluation of Treated and Untreated Sludge from Yarn Processing Factory as Adsorbent Candidates for Dye Removal
page: 508 - 517

Muhammad Abbas Ahmad Zaini* [a,b] and Noor Yuhana Jusoh [b]

Vol.44 No.2 (April 2017)
Research Article View: 1,572 Download: 267
Towards the Adsorption of Propylene and Propane on Cu(I)X and Cu(I)Y Zeolites: Effects of Zeolite Preparation
page: 591 - 599

Suwichak Phutthapatimok [a,b], Pattaraporn Sridechparsat [a,b], Pramoch Rangsunvigit* [a,b] and Santi Kulprathipanja [c]

Vol.43 No.3 (APRIL 2016)
Research Article View: 1,632 Download: 344
Validating Adsorptive Capacity of Areca Husk Carbon onto Methylene Blue & ANOVA Modelling
page: 183 - 194

Arumugam Basker[a]*, Syed shabudeen[b], Appavoo Ponnuraju Shekhar[c] and Savarimuthu Daniel[b]

Vol.43 No.1 (JANUARY 2016)
Research Article View: 1,567 Download: 283
Modeling and Optimization of Removal of Rhodamine – B from Wastewaters by Adsorption on Modified Clay
page: 1230 - 1240

Morteza Bahram, Robabeh Talebi, Abdolhossein Naseri* , Sirous Nouri

Vol.41 No.5/2 (OCTOBER 2014)
Research Article View: 1,525 Download: 532
Synthesis and Use of Zeolite Na-A from Waste Sludge of Water Treatment Plant for Ammonium Removal
page: 1262 - 1273

Jeatana Wongwichien [a], Suwimol Asavapisit [a] and Kwannate Sombatsompop* [b]

Vol.41 No.5/2 (OCTOBER 2014)
Research Article View: 1,503 Download: 276
Preparing Activated Carbon from Palm Shell for Biodiesel Fuel Production
page: 572 - 578

Achanai Buasri, Nattawut Chaiyut and Chaiwut Nakweang

Vol.38 No.4 (OCTOBER 2011)
Research Article View: 1,048 Download: 348
Adsorption Equilibrium of Zinc Ions from Aqueous Solution by Using Modified Clinoptilolite
page: 56 - 62

Achanai Buasri, Phetcharat Yongbut, Nattawut Chaiyut and Kittiya Phattarasirichot

Vol.35 No.1 (JANUARY 2008)
Research Article View: 1,556 Download: 347
Determination of Copper by Slurry-Sampling Electro-thermal Atomic Absorption Spectrometry After Pre-concentration on Activated Carbon
page: 65 - 70

Khuanjit Benyatian

Vol.27 No.2 (DECEMBER 2000)
Opinion View: 1,089 Download: 242
Outline
Figures