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Chiang Mai Journal of Science, Faculty of Science, Chiang Mai University
 


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Microscopy Investigation of Streblus asper Lour. Leaves-derived SiO2/C with Polypyrrole Nanocomposites as Sustainable Anode Materials for Lithium-ion Batteries


Paper Type 
Contributed Paper
Title 
Microscopy Investigation of Streblus asper Lour. Leaves-derived SiO2/C with Polypyrrole Nanocomposites as Sustainable Anode Materials for Lithium-ion Batteries
Author 
Kittiched Khunpakdee, Thanapat Autthawong, Natthakan Ratsameetammajak and Thapanee Sarakonsri
Email 
thapanee.s@cmu.ac.th
Abstract:

     Lithium-ion batteries (LIBs) are chemically reactive rechargeable energy storages. Silica (SiO2) is one of the most popular alternative materials to replace graphite as an anode material in LIBs due to its higher specific capacity, non-toxicity, and natural resources. Streblus asper Lour. (Khoi) is widely grown in Southeast Asia and contains high SiO2 and SiO2/C levels in its leaves. In order to overcome the volume change issue of Si-based materials and enhance cycle stability, carbon (C) and polypyrrole (PPy) were utilized to reinforce the SiO2 structure during the lithiation/delithiation process. X-ray diffraction (XRD) was utilized to investigate the SiO2, C, and PPy amorphous phases of the synthesized products. Fourier transform infrared spectroscopy (FT-IR), which confirmed the formation of PPy in composites. The scanning electron microscopy (SEM) images revealed different morphologies of SiO2 aggregates, SiO2/C with plate layers, the network structure of PPy and in the composites with PPy. Transmission electron microscopy (TEM) revealed the aggregation of nano-sized SiO2, SAED phase confirmation, and demonstrated the coating of PPy on SiO2/C (KSCPy composites), indicating the presence of C and PPy as supporters. In addition, the performance of synthesized composites as anodes was investigated by assembling them into half-coin cells and performing electrochemical tests. Khoi-SiO2/C/PPy (KSCPy) obtained a specific capacity of 497.9 mA g−1 for 400 cycles at 0.1 A g−1 and the lowest charge transfer resistance. Furthermore, these materials have the potential to be used as sustainable anode materials in LIBs due to their use of natural materials, a non-toxic synthesis method, and C and PPy as both support materials and conductive polymers, which can enhance electrical performance as anode materials.

Article ID
e2024099
Received Date 
2024-08-07
Revised Date 
2024-10-17
Accepted Date 
2024-10-17
Published Date 
2024-11-29
Full Text 
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Keyword 
biomass, silica, carbon, nanocomposites, conductive polymer, anode materials, lithium-ion batteries
Volume 
Vol.51 No.6 (November 2024)
DOI 
https://doi.org/10.12982/CMJS.2024.099
Citation 
Khunpakdee K., Autthawong T., Ratsameetammajak N. and Sarakonsri T., Microscopy Investigation of Streblus asper Lour. Leaves-derived SiO2/C with Polypyrrole Nanocomposites as Sustainable Anode Materials for Lithium-ion Batteries, Chiang Mai Journal of Science, 2024; 51(6): e2024099. DOI 10.12982/CMJS.2024.099.
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Author:Achanai Buasri, Nattawut Chaiyut and Chaiwut Nakweang
Vol.38 No.4 (OCTOBER 2011) View: 659 Download:306
A Comparative Study of the Cure Characteristics, Processability, Mechanical Properties, Heat Aging, and Morphology of Rice Husk Ash and Silica Fillers in Natural Rubber Compounds
page: 265 - 273
Author:Wanvimon Arayapranee* [a] and Garry L. Rempel [b]
Vol.31 No.3 September 2004 View: 690 Download:231
Synthesis and Applications of Silica Supported Dichlorotriazine (Si-DCT) in Nucleophilic Scavenging
page: 203 - 209
Author:Mookda Pattarawarapan* and Sunantanee Singhatana
Vol.33 No.2 (MAY 2006) View: 659 Download:196
Adhesion of Borosilicate Glass and Fe-Ni-Co Alloy Joined by Direct Fusion
page: 191 - 202
Author:Waraporn Piyavit [a], Chutimun Chanmuang [a], Manat Jaimasit [b], Warrapong Thiemsorn [b], Akadech
Vol.33 No.2 (MAY 2006) View: 672 Download:167
Preparation of Nanosilica Powder from Rice Husk Ash by Precipitation Method
page: 206 - 211
Author:Nittaya Thuadaij and Apinon Nuntiya
Vol.35 No.1 (JANUARY 2008) View: 1,734 Download:363
Catalytic Study of Iron, Aluminum, Vanadium and Cobalt Modified Titanium Silicalites-1 in the Hydroxylation of Benzene and Alkyl Benzene by Hydrogen Peroxide
page: 178 - 187
Author:Pornnapa Kasemsiri, Kriangkrai Shenchunthichai, Patchanee Chammingkwanand Tharathon Mongkhonsi
Vol.35 No.1 (JANUARY 2008) View: 689 Download:283
Catalytic Activity of TS-1 on the Hydroxylation of Benzene and Toluene with Hydrogen Peroxide in a Bubble Reactor
page: 163 - 170
Author:Suchitraporn Sakullimcharoen, Panas Manit and Tharathon Mongkhonsi
Vol.35 No.1 (JANUARY 2008) View: 727 Download:255
Experiments and Statistical Analysis of Supercritical Carbon Dioxide Extraction
page: 109 - 115
Author:Wipawee Yothipitak, Praiya Thana, Motonobu Goto and Artiwan Shotipruk
Vol.35 No.1 (JANUARY 2008) View: 680 Download:227
Development of Fuel Briquettes from Biomass-Lignite Blends
page: 43 - 50
Author:Suparin Chaiklangmuang, Suwit Supa and Prattana Kaewpet
Vol.35 No.1 (JANUARY 2008) View: 642 Download:267
Fabrication and Characterization of High Strength Dental Porcelain Nanocomposite from Thailandís Raw Materials
page: 549 - 553
Author:Attavit Pisitanusorn*[a], Supon Ananta [a], Rattikorn Yimnirun [a] and Sakdipown Thiansem [b]
Vol.32 No.3 (SEPTEMBER 2005) View: 649 Download:195
Lithofacies and Fossils of Carboniferous and Permian Carbonate Rocks from the Chiang Dao Area, Northern Thailand
page: 294 - 310
Author:Sutee Jongautchariyakul and Wutti Uttamo
Vol.35 No.2 (MAY 2008) View: 710 Download:999
Pressure-Temperature Estimates of the Metamorphosed Sedimentary Rocks on the Eastern Side of Khao Phai, Immediate West of Ban Choeng Chai, Wang Pong, Phetchabun Province, Thailand
page: 283 - 293
Author:Yuenyong Panjasawatwong, Boontarika Srithai and Udomporn Wipakul
Vol.35 No.2 (MAY 2008) View: 696 Download:209
Preparation of Carbon Nanotubes by Catalytic Decomposition of Alcohol at Low Pressure
page: 427 - 432
Author:Pisanunak Chiwsitthiprapai [a], Sutichai Chaisitsak*[a] and Pavan Siamchai [b]
Vol.32 No.3 (SEPTEMBER 2005) View: 656 Download:205
The Uniformity of Carbon Nanotubes Synthesized by Hot Carbon-filament Enhanced CVD
page: 411 - 416
Author:Sutichai Chaisitsak*[a], Akira Y Yamada amada [b] and Mak Makoto oto K Konagai onagai [b]
Vol.32 No.3 (SEPTEMBER 2005) View: 670 Download:188
Synthesis of Carbon Nanoparticles Using Thermal Co-pyrolysis of Ferrocene and Naphthalene Mixture
page: 379 - 383
Author:Tawatchai Charinpanitkul [a]*, Noriaki Sano [b], P ramote Puengjinda [a] +, P oonlasak Muthak arn [
Vol.32 No.3 (SEPTEMBER 2005) View: 1,147 Download:183
Potential of Nanocomposite Technique for Fabrication of Smart Ceramics
page: 179 - 187
Author:Rewadee Wongmaneerung, Laongnuan Srisombat, Rattikorn Yimnirun, and Supon Ananta
Vol.36 No.2 (MAY 2009) View: 685 Download:187
Chemical Analysis of Airborne Particulates for Air Pollutants in Chiang Mai and Lamphun Provinces, Thailand
page: 123 - 135
Author:Somporn Chantara, Sunanta Wangkarn, Urai Tengcharoenkul, Walaya Sangchan and Mongkon Rayanakorn
Vol.36 No.2 (MAY 2009) View: 717 Download:229
Self-Reduction of Gold on Activated Carbon Cloth
page: 99 - 105
Author:Surin Saipanya and Thapanee Sarakonsri
Vol.37 No.1 (JANUARY 2010) View: 651 Download:243
A Microscopical Investigation of the Interface Between Borosilicate Glass and Fe-Ni-Co Alloy Joined by Direct Fusion of Glass to Metal
page: 15 - 19
Author:Torranin Chairuangsri*[a], Manat Jaimasith [a], Worapong Thiemsorn [a] and John T.H. Pearce [b] and John T. H. Pearce [b]
Vol.29 No.1 (APRIL 2002) View: 688 Download:224
Determination of Copper by Slurry-Sampling Electro-thermal Atomic Absorption Spectrometry After Pre-concentration on Activated Carbon
page: 65 - 70
Author:Khuanjit Benyatian
Vol.27 No.2 (DECEMBER 2000) View: 702 Download:195
A Barium-Calcium Silicate Glass for Use as Seals in Planar SOFCs
page: 231 - 242
Author:Prachaya Namwong, Nattapol Laorodphan, Worapong Thiemsorn, Manat Jaimasith, Anucha Wannakon, and Tor
Vol.37 No.2 (MAY 2010) View: 746 Download:248



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