Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

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Preparation and Properties of Woven Carbon Fiber Mat-Epoxy Composites Containing Dispersed Base-Functionalized Multi-Walled Carbon Nanotubes

Darunee Aussawasathien*, Chanpen Teerawattananon
* Author for corresponding; e-mail address: daruneea@mtec.or.th
Volume: Vol.39 No.3 (JULY 2012)
Research Article
DOI:
Received: 4 October 2011, Revised: -, Accepted: 9 March 2012, Published: -

Citation: Aussawasathien D. and Teerawattananon C., Preparation and Properties of Woven Carbon Fiber Mat-Epoxy Composites Containing Dispersed Base-Functionalized Multi-Walled Carbon Nanotubes , Chiang Mai Journal of Science, 2012; 39(3): 524-539.

Abstract

Composite plates consisting of woven carbon fiber mats, epoxy resin, and conductive fillers, either pristine multi-walled carbon nanotubes (MWCNTs) or chemical modified MWCNTs, were prepared by hand-lay-up and compression molding processes. The MWCNTs were purified by acetone treatment and then non-covalently functionalized by 2-aminoethanol in the presence of sodium hydroxide. The characterization of chemical modified MWCNTs was carried out by using transmission electron microscopy (TEM), Raman spectrometry, and thermogravimetric analysis (TGA). Amounts of conductive fillers from 0.5-2.0 wt% were included in the epoxy matrix to improve the properties of the composites in the through thickness direction. Base-functionalized purified MWCNTs had a better distribution in the resin than did pristine MWCNTs. Results demonstrate that the dispersion of MWCNTs determined the properties of the composite plates. The optimum composite contained 1.5 wt% of base-functionalized purified MWCNTs in epoxy and had a bulk electrical conductivity of 93 S cm-1, a tensile strength of 0.65 GPa, a flexural strength of 0.70 GPa, a coefficient of thermal expansion (CTE) of 43.65 x 10-6 oC-1, a water contact angle of 88.6o, a corrosion current density of 0.43 µA cm-2, and a density of 1.592 g cm-3.

Keywords: Carbon fiber mat, Carbon nanotube, Epoxy resin, Composite plate

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