Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

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Humidity Effects on Cs0.17FA0.83Pb(I0.83Br0.17)3 Thin Films for Carbon-based Perovskite Solar Cells

Wongsathon Musikpan, Warunee Khampa, Woraprom Passatorntaschakorn, Chukwuebuka Emmanuel Usulor, Athipong Ngamjarurojana, Atcharawon Gardchareon, Pipat Ruankham and Duangmanee Wongratanaphisan
* Author for corresponding; e-mail address: duangmanee.wong@cmu.ac.th
Volume: Vol.51 No.4 (July 2024)
Research Article
DOI: https://doi.org/10.12982/CMJS.2024.058
Received: 15 Febuary 2024, Revised: 19 April 2024, Accepted: 30 May 2024, Published: -

Citation: Musikpan W., Khampa W., Passatorntaschakorn W., Usulor C.E., Ngamjarurojana A., Gardchareon A., et al., Humidity effects on Cs0.17FA0.83Pb(I0.83Br0.17)3 thin films for carbon-based perovskite solar cells, Chiang Mai Journal of Science, 2024; 51(4): e2024058. DOI 10.12982/CMJS.2024.058.

Abstract

     Organic-inorganic hybrid perovskites have captivated the attention of researchers worldwide due to their remarkable potential for low-cost, high-efficiency solar cells. However, the reliance on controlled environments, such as dry boxes, poses a significant barrier for smaller laboratories wishing to participate in perovskite research. In this study, we investigate the influence of ambient humidity of Cs0.17FA0.83Pb(I0.83Br0.17)3 during the film formation process. Our experiments involved the fabrication of perovskite films using spin-coating techniques under different controlled humidity conditions with identical precursor preparation. The results revealed a significant decrease in film thickness under higher humidity, accompanied by a noticeable alteration in perovskite grain morphology, suggesting a complex interplay between humidity and grain formation. Furthermore, the photovoltaic performance of device with perovskite film formed in different humidity was measured. Surprisingly, despite the challenges posed by high humidity during fabrication, the solar cell efficiency only moderately decreased from 13.17% to 9.55% in average, indicating a remarkable potential of the Cs0.17FA0.83Pb(I0.83Br0.17)3 perovskite formula under adverse ambient conditions. These findings hint at the feasibility of their application in real-world, ambient air conditions, paving the way for their integration into diverse environmental settings, enabling a wider research community to engage in the exciting realm of perovskite solar cell technology.

Keywords: ambient humidity, film formation, perovskite, carbon-based perovskite solar cells

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