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The Effect of Substitution of WC by TiC in WC-Co Composite Tool Materials on Microstructure and Mechanical Properties

Paper Type	Contributed Paper
Title	The Effect of Substitution of WC by TiC in WC-Co Composite Tool Materials on Microstructure and Mechanical Properties
Author	Jan Dutkiewicz*, ukasz Rogal, P. Bobrowski, Magorzata Szutkowska,Wojciech Leniewski and Piotr Duzews
Email	j.dutkiewicz@imim.pl
Abstract: WC-Co composites with TiC additions of 5-20 wt.% substituting WC were consolidated using Hot Isostatic Pressing (HIP) method at temperature of 1350°C and pressure between 50-150 MPa. The hardness of WC-Co consolidated samples increase from 1050 HV (without TiC consolidated at 50 MPa) up to 1330 HV at 5% TiC and up to 1600 HV with 20% of TiC. The higher hardness of samples with TiC additions can be explained by a higher consolidation pressure of 150 MPa leading to a lower porosity, but also to hardening due to TiC addition. Young modulus values are lower for samples with TiC attaining 420-490 GPa as compared to 570 GPa for conventional WC-Co samples. Samples with a crack formation behavior allowed to determine fracture toughness KIC using crack length from hardness measurements. Results in the range 10, 9-11, 2 [MPam1/2] for the samples containing 0-10 % TiC, indicated only insignificant decrease of this property with TiC content. Addition of TiC causes also 15-30 % lower density of composites in the range 10-12, 5 g/cm3. The major identified phase is the hexagonal WC carbide separated by a narrow layer of Co binder and accompanied by single particles of TiC within Co. The size of WC particles was the same as applied in conventional composites i.e. 2-4 mm, while that of homogeneously distributed TiC were measured as slightly smaller, below 2 mm. Transmission electron microscopy investigations allowed to identify relatively high dislocation density in both cubic TiC and hexagonal WC carbides and different interfaces between WC and TiC carbides and Co binder however no additional phases were detected there. The crystallographic relationship [01-1] TiC \|\| [100] WC was often observed. The appearance of solid solution of TiC with WC near WC/TiC interfaces was discussed.
Start & End Page	1714 - 1721
Received Date	2015-07-14
Revised Date
Accepted Date	2015-11-16
Full Text	Download
Keyword	WC-TiC-Co composites, mechanical properties, TEM, SEM studies
Volume	Vol.44 No.4 (October 2017)
DOI
Citation	Dutkiewicz* J., Rogal U., Bobrowski P., Szutkowska M., Leniewski W. and Duzews P., The Effect of Substitution of WC by TiC in WC-Co Composite Tool Materials on Microstructure and Mechanical Properties, Chiang Mai Journal of Science, 2017; 44(4): 1714-1721.
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Effects of Tempering Time on Phase Formation and Microstructural Evolution of Zirconia Modified-Dental Porcelain Ceramics
page: 176 - 186
Author:Chayada Sanitnapapong [a], Attavit Pisitanusorn [a], and Supon Ananta*[b]
Vol.38 No.2 (APRIL 2011) View: 656 Download:205

Intelligent Agents Enabling Negotiated Control of Pervasive Environments
page: 99 - 122
Author:Kecheng Liu, Jarunee Duangsuwan*, and Zhutao Huang
Vol.38 (SPECIAL ISSUE 2011) View: 653 Download:199

A Comparative Study of the Cure Characteristics, Processability, Mechanical Properties, Heat Aging, and Morphology of Rice Husk Ash and Silica Fillers in Natural Rubber Compounds
page: 265 - 273
Author:Wanvimon Arayapranee* [a] and Garry L. Rempel [b]
Vol.31 No.3 September 2004 View: 689 Download:231

Performance of Giant Freshwater Prawn (Macrobrachium rosenbergii de Man) Reared in Earthen Ponds Beneath Plastic Film Shelters
page: 89 - 96
Author:Niwooti Whangchai, Thepparath Ungsethaphand, Chanagun Chitmanat, Kriangsak Mengumphan and Supattra
Vol.34 No.1 (JANUARY 2007) View: 656 Download:241

Microstructures and Mechanical Properties of Zirconium-Doped Bismuth Sodium Titanate Ceramics
page: 169 - 173
Author:Anucha Watcharapasorn*, Sukanda Jiansirisomboon and Tawee Tunkasiri
Vol.33 No.2 (MAY 2006) View: 693 Download:179

Preparation of Nanosilica Powder from Rice Husk Ash by Precipitation Method
page: 206 - 211
Author:Nittaya Thuadaij and Apinon Nuntiya
Vol.35 No.1 (JANUARY 2008) View: 1,734 Download:363

A New Analytical Expression of the Gas Conversion for TAP Experiments with Bimodal-Pore-Structure Catalyst
page: 150 - 155
Author:Wisuthchai Boonwatcharapunsakul and Phungphai Phanawadee
Vol.35 No.1 (JANUARY 2008) View: 611 Download:217

Pressure-Temperature Estimates of the Metamorphosed Sedimentary Rocks on the Eastern Side of Khao Phai, Immediate West of Ban Choeng Chai, Wang Pong, Phetchabun Province, Thailand
page: 283 - 293
Author:Yuenyong Panjasawatwong, Boontarika Srithai and Udomporn Wipakul
Vol.35 No.2 (MAY 2008) View: 696 Download:209

The Effect of Compatibilizing Agents on Mechanical Properties of Natural Rubber-Nanocomposite
page: 391 - 398
Author:Suthinee Netrabukkana and Cattaleeya Pattamaprom*
Vol.32 No.3 (SEPTEMBER 2005) View: 706 Download:210

Artificial Neural Networks Parameters Optimization with Design of Experiments: An Application in Ferromagnetic Materials Modeling
page: 83 - 91
Author:Wimalin Laosiritaworn, and Nantakarn Chotchaithanakorn
Vol.36 No.1 (JANUARY 2009) View: 703 Download:280

Effect of Addition of CuO and Bi2O3 on Low Temperature Sintering of Pb(Zr,Ti)O3 - PbZn1/3Nb2/3O3- Pb(Ni1/3Nb2/3)O3 Based Ceramics
page: 50 - 58
Author:Athipong Ngamjarurojana
Vol.36 No.1 (JANUARY 2009) View: 704 Download:268

Solving First Order Systems of Ordinary Differential Equations Using Parallel R-Point Block Method of Variable Step Size and Order
page: 9 - 23
Author:Zurni B. Omar, and Mohamed Suleiman
Vol.36 No.1 (JANUARY 2009) View: 642 Download:176

Developing Indicators for Floodplain Wetlands: Managing Water in Agricultural Landscapes
page: 224 - 235
Author:Kim Jenkins, Richard Kingsford, and Darren Ryder
Vol.36 No.2 (MAY 2009) View: 678 Download:244

New Positive Temperature Coefficient Effect Based on Bi2O3+Fe2O3 or ZrO2+MnO2 Material and Used as Temperature Sensor
page: 109 - 120
Author:Thongchai Panmatarith* [a], Chiraporn Sriprom [a] and Nanthida Sutthirawuth [b]
Vol.32 No.2 (MAY 2005) View: 683 Download:305

On the Production of Aluminium Foams Stabilised Using Particles of Rice Husk Ash
page: 302 - 311
Author:Seksak Asavavisithchai, and Rath Tantisiriphaiboon
Vol.36 No.3 (SEPTEMBER 2009) View: 676 Download:208

Study of Crack Growth Behavior in Commercially As-Received Lead-Zirconate-Titanate
page: 21 - 29
Author:Sukanda Jiansirisomboon
Vol.29 No.1 (APRIL 2002) View: 667 Download:208

Synthesis and Characterisation of Poly(2-hydroxyethyl methacrylate-co-methyl acrylate) Hydrogels for Use as Temporary Skin Substitutes
page: 71 - 82
Author:Tiwaporn Siriwittayakorn [a], Nantarat Suebsanit [a], Robert Molloy [a], Paisit Siriwittayakorn [b] and Malinee Prasitsilp [c]
Vol.28 No.2 (DECEMBER 2001) View: 697 Download:231

Rough Classifier: Experiments on Two Medical Data Sets
page: 59 - 63
Author:Azuraliza A. Bakar, Md N. Sulaiman, Mohamed Othman and Mohd H. Selamat
Vol.28 No.1 (JUNE 2001) View: 672 Download:163

Determination of Number Density and Volume Fraction of Copper Precipitates Within Proeutectoid Cementite in High-Carbon Copper-Containing Steels Using Transmission Electron Microscopy
page: 31 - 38
Author:Torranin Chairuangsri [a], Rik M. D. Brydson [b], David V. Edmonds [b]
Vol.28 No.1 (JUNE 2001) View: 786 Download:239

Solving First Order Systems of Ordinary Differential Equations Using Parallel R-Point Block Method of Variable Step Size and Order
page: 1 - 13
Author:Zurni B. Omar, and Mohamed Suleiman
Vol.37 No.1 (JANUARY 2010) View: 647 Download:219

Fabrication of Open-Cell Silver Foams Using Disaccharide as Space Holders
page: 222 - 230
Author:Seksak Asavavisithchai, and Ekasit Nisaratanaporn
Vol.37 No.2 (MAY 2010) View: 668 Download:218

Effect of TiC Particles on Foamability and Compressive Properties of Aluminium Foams
page: 213 - 221
Author:Seksak Asavavisithchai, and Apiyut Opa
Vol.37 No.2 (MAY 2010) View: 673 Download:176

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The Effect of Substitution of WC by TiC in WC-Co Composite Tool Materials on Microstructure and Mechanical Properties

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