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Application of Smartphone as a Digital Image Colorimetric Detector for Batch and Flow-based Acid-Base Titration


Paper Type 
Contributed Paper
Title 
Application of Smartphone as a Digital Image Colorimetric Detector for Batch and Flow-based Acid-Base Titration
Author 
Janejira Chanla, Miki Kanna, Jaroon Jakmunee, and Sarawut Somnam*
Email 
sarawut_som@cmru.ac.th, wut_080@hotmail.com
Abstract:
 In this research, we have developed the batch and flow-based system of titrimetric
analysis by using a mobile phone as a detector. The digital image colorimetric detection system
was set up with economic devices and to be easy to use by taking photograph with mobile phone
camera, then the RGB signals were read from the RGB color picker application to calculate the
RGB-based value and plot titration curve for evaluating the equivalence point. This method was
applied to analyze samples of acid-base on daily basis, compared with the potentiometric and
photometric titrations that using pH meter and spectrophotometer as a detector, respectively.
The method was highly reproducible with the relative standard deviation of 1.14 % (n=11)
for 0.5 %w/v of acetic acid standard solution. The proposed method was applied to the
determination of acetic acid in vinegar and titratable acidity in fruit juices. Concentrations of
acetic acid were found to be in a range of 5.23-5.35 %w/v. Concentrations of titratable acidity
in the juice samples were found to be in a range of 0.27-0.50 %w/v. Thereafter, an analytical
application involving the determination of the total alkalinity in mineral waters was performed,
and it was found in the range of 11.50-18.50 mg/L of CaCO3 which were in good agreement
with the results obtained from the standard method at the 95 % confidence level.
Start & End Page 
975 - 986
Received Date 
2019-03-10
Revised Date 
Accepted Date 
2019-04-24
Full Text 
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Keyword 
Titration, Flow-based analysis, Smartphone, RGB color system, Application RGB color picker
Volume 
Vol.46 No.5 (September 2019)
DOI 
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