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Use of by-product Sulfur from Petroleum Refinery as Vulcanizing Agent in Natural Rubber


Paper Type 
 Contributed Paper
Title 
 Use of by-product Sulfur from Petroleum Refinery as Vulcanizing Agent in Natural Rubber
Author 
 Pathompong Pangamol [a], Pongdhorn Sae-oui [b], Chakrit Sirisinha*[a,c]
Email 
 chakrit.sir@mahidol.ac.th
Abstract:
 Sulfur is typically required for rubber vulcanization in order to achieve enhanced mechanical strength and elastic behavior. Basically, the sulfur used in rubber industry originates from natural resource and petroleum-based refinery. The petroleum-based sulfur (PS) generally treated as by-product from refinery process was investigated in this work. Its influence on cure characteristics, viscoelastic properties as well as crosslink density was compared with conventional rhombic sulfur. Results obtained reveal inferiority in mechanical properties of the system with as-received PS. By reducing average particle size of as-received PS via a ball-milling process under optimal milling conditions, the ground PS (GPS) exhibits significant improvement in mechanical properties of rubber vulcanizates to be comparable to the conventional rhombic sulfur.

Start & End Page 
 570 - 577
Received Date 
 2013-10-28
Revised Date 
Accepted Date 
 2014-09-19
Full Text 
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Keyword 
 rubber, sulfur, vulcanization, mechanical properties, cure behavior
Volume 
 Vol.43 No.3 (APRIL 2016)
DOI 
Citation 
 [a] P.P., [b] P.S., Sirisinha*[a C. and C] , Use of by-product Sulfur from Petroleum Refinery as Vulcanizing Agent in Natural Rubber, Chiang Mai Journal of Science, 2016; 43(3): 570-577.
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