Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

1,647
Articles
Q3 0.80
Impact Factor
Q3 1.3
CiteScore
7 days
Avg. First Decision
Outline
Figures and Tables
ARTICLE METRICS
Views 1,602
Downloads 330

Phase formations, Compressive Strength and Microstructure of Environmentally Friendly Thai Lopburi Calcined Clay-Limestone Cement Mixes

Arnon Chaipanich, Nalintip Sansuthum, Phakin Chomyen, Kornnika Wianglor and Supakporn Aodkeng
* Author for corresponding; e-mail address: arnon.chaipanich@cmu.ac.th
Volume: Vol.51 No.6 (November 2024)
Research Article
DOI: https://doi.org/10.12982/CMJS.2024.089
Received: 10 July 2024, Revised: 31 August 2024, Accepted: 16 September 2024, Published: 28 November 2024

Citation: Chaipanich A., Sansuthum N., Chomyen P., Wianglor K. and Aodkeng S., Phase formations, compressive strength and microstructure of environmentally friendly Thai Lopburi calcined clay-limestone cement mixes, Chiang Mai Journal of Science, 2024; 51(6): e2024089. DOI 10.12982/CMJS.2024.089.

Abstract

       Limestone and calcined clay, due to their abundance and sustainability are seen as feasible materials to be used to replace Portland cement in the future. In this work, Portland cement was replaced with calcined clay and limestone at 50 % by weight. In addition to compressive strength, the microstructure and phase characterizations were investigated at 7 and 28 days to determine hydration and pozzolanic reaction of the mixes using thermogravimetric analysis, X-ray diffraction and scanning electron microscopy. When using 20% calcined clay, the 50PC30LS20CC mix showed an increase in the compressive strength by 225% compared to the 50PC50LS mix. Although the compressive strength was still lower than 100 PC control mix, using calcined clay and limestone together lead to a significant reduction in the water absorption compared to 50% LS mix due to the phases formed and the filling effects, and comparable result to 100PC mix was found when calcined clay was used at 20%. In addition to calcium carbonate detected in mixes with limestone, monocarboaluminate phase was also found at 7 days and became clearer at 28 days, especially when there was a combination of calcined clay and limestone in the mix due to the presence of alumina from calcined clay. Moreover, pozzolanic reaction from the use of calcium clay resulted in the increase of C-S-H and C2ASH8 which increased with calcined clay content and corresponds with a reduction in calcium hydroxide and an increase in compressive strength.

Keywords: cement, limestone, calcined clay, compressive strength, microstructure, phase characterizations

Related Articles

Enhancing Performance of Self-Compacting Concrete Using Fly Ash and Waterproofing Admixture: A Study on Mechanical Strength and Water Resistance
DOI: 10.12982/CMJS.2025.082.

Tzyy Lih Lee, Chun-Chieh Yip, Lloyd Ling, Kok Zee Kwong, Jing-Ying Wong and Foo Wei Lee

Vol.52 No.6 (November 2025)
Research Article View: 670 Download: 403
Development of Lightweight and Thermal Insulation Concrete Based on Agro-industrial Waste
DOI: 10.12982/CMJS.2025.018.

Sutthima Sriprasertsuk and Saijit Daosukho

Vol.52 No.2 (March 2025)
Research Article View: 738 Download: 431
Permeable Blocks with Waste Glass as Coarse Aggregate
DOI: 10.12982/CMJS.2023.062.

Jenjinta Punyasurb, Suthee Wattanasiriwech and Darunee Wattanasiriwech

Vol.50 No.6 (November 2023)
Research Article View: 916 Download: 830
The Effect of Double Solution Treatment on Changes in the Microstructure of Austenitic Manganese Steel
DOI: 10.12982/CMJS.2023.060.

Arif Tjahjono, Nadya Salsabila Frendyta and Permana Andi Paristiawan

Vol.50 No.6 (November 2023)
Research Article View: 1,160 Download: 553
Cement Immobilization of Hazardous and Radioactive Electric Arc Furnace Dust
DOI: 10.12982/CMJS.2022.092.

Sudarat Issarapanacheewin, Klitsadee Yubonmhat, Thunyaras Akharawutchayanon, Umaporn Lamdab, Wipawe Silpradit, Wilasinee Kingkam, Witsanu Katekaew and Nikom Prasertchiewchan

Vol.49 No.5 (September 2022)
Research Article View: 2,133 Download: 784
Microstructure, Tensile, and Fractography Analysis of Al2016 and Al2618 Age Hardened Aluminium Alloys
DOI: 10.12982/CMJS.2022.066.

Arivumani Ravanan, Ilamathi Palanivel and Balamurugan Kulendran

Vol.49 No.4 (July 2022)
Research Article View: 1,881 Download: 880
Strengthening Geopolymer with Selective Sizes of Concrete Block Waste
page: 1657 - 1678

Parinya Somrang, Anucha Wannagon, Pattarawan Choeycharoen, and Watcharee Sornlar

Vol.48 No.6 (November 2021)
Research Article View: 1,842 Download: 501
Influence of Deep Cryogenic Treatment on Microstructure, Hardness, Impact Strength and Wear of CuBeZr Alloy
page: 631 - 647

Nuwan Wannaprawat and Karuna Tuchinda

Vol.48 No.2 (March 2021)
Research Article View: 1,160 Download: 532
Physical and Mechanical Properties of Diatomite/Metakaolin-based Geopolymer for Construction Materials
page: 786 - 795

Suwanan Thammarong, Narumon Lertcumfu, Pharatree Jaita, Nuttaporn Pimpha, Tawee Tunkasiri, Gobwute Rujijanagul and Pruchya Malasri

Vol.47 No.4 (Special Issue II : July 2020)
Research Article View: 1,129 Download: 565
Fabrication of Open-cell Aluminum Foams by Pressure Infiltration and Salt Leaching Method from Commercial Grade Alloys
page: 673 - 685

Pat Sooksaen* and Pathompong Puathawee

Vol.47 No.4 (Special Issue II : July 2020)
Research Article View: 1,111 Download: 1,092
Humidity Control Ability of Porous Ceramics Prepared by Thermal Decomposition of Limestone and Dolomite
page: 217 - 228

Parinya Somrang, Rung-Arun Sanngam and Anucha Wannagon

Vol.47 No.1 (January 2020)
Research Article View: 1,030 Download: 503
Physical Properties and Microstructure of a Fe-Ni-Co Alloy Prepared by Sintering Metal Powders Under Nitrogen Gas Atmosphere
page: 17 - 25

Sirisak Seansukato and Torranin Chairuangsri*

Vol.31 No.1 (JANUARY 2004)
Research Article View: 946 Download: 286
Influence of Calcium Salts on Quality and Microstructure of Minimally-processed Litchi Fruit
page: 46 - 61

Putkrong Phanumong, Sang Moo Kim, Jurmkwan Sangsuwan, Noppol Leksawasdi and Nithiya Rattanapanone

Vol.46 No.1 (January 2019)
Research Article View: 1,005 Download: 426
Effects of Cobalt Dopant on Microstructure and Electrical Properties of Bi0.5Na0.5TiO3 Ceramics
page: 2481 - 2490

Suwapitcha Buntham, Paitoon Boonsong, Panupong Jaiban, Nittaya Keawprak and Anucha Watcharapasorn

Vol.45 No.6 (September 2018)
Research Article View: 1,000 Download: 347
Microstructure and Wear Behavior of Hardfacing with Ferro-alloy Powder Addition Using Submerged Arc Welding
page: 2034 - 2047

Buntoeng Srikarun and Prapas Muangjunburee*

Vol.45 No.5 (Special 2018)
Research Article View: 1,069 Download: 529
Utilization of Sugarcane Bagasse Ash to Improve Properties of Fired Clay Brick
page: 1855 - 1862

Nonthaphong Phonphuak and Prinya Chindaprasirt

Vol.45 No.4 (July 2018)
Research Article View: 1,061 Download: 1,057
Fabrication of Porous Ceramics from Non-metallic Residue Obtained from Aluminum Recycling Plant
page: 1099 - 1110

Pat Sooksaen* and Pathompong Puathawee

Vol.45 No.2 (March 2018)
Research Article View: 1,094 Download: 331
Characteristics and Flavor Retention of Structured Emulsion from Pomelo (Citrus maxima) Residue
page: 949 - 960

Yot Boontongkong, Jaruwan Yaemsiri and Pawadee Methacanon*

Vol.45 No.2 (March 2018)
Research Article View: 1,075 Download: 426
Effect of Heat Treatment on High Temperature Damping Capacity of ZK60 Sheet Produced by Twin-roll Casting and hot-rolling
page: 351 - 357

Chen Hongmei* [a], Liu Zhongming [a], Zang Qianhao [a, b], Yu Xin [a], Zhang Jing [c] and Jin Yunxue [a]

Vol.43 No.2 (SPECIAL ISSUE 1)
Research Article View: 993 Download: 286
Microstructure and Mechanical Properties of As-cast and Heat-treated 935AgCuBeSn Alloys
page: 206 - 214

Siriwan Sakultanchareonchai [a], Torranin Chairuangsri [b] and Ekasit Nisaratanaporn*[a]

Vol.43 No.1 (JANUARY 2016)
Research Article View: 1,012 Download: 462
Study of Pozzolonic Reactions in Bagasse Ash Cementitious System with and Without Quicklime as a Chemical Activator
page: 429 - 435

Noor-ul-Amin

Vol.42 No.2 (APRIL 2015)
Research Article View: 859 Download: 284
Effect of Isothermal Heat Treatment at 650, 750 and 850°C on the Microstructures of Lean Duplex Stainless Steel S32101 Welds
page: 874 - 885

Zbigniew Brytan* and Jerzy Niagaj

Vol.40 No.5 SPECIAL ISSUE 1
Research Article View: 1,007 Download: 260
Characteristics of Microstructure, Microhardness, and Oxidation of FSW and MIG Welded Steels
page: 831 - 838

Seul Ki Kim, Seung Boo Jung and Dong Bok Lee*

Vol.40 No.5 SPECIAL ISSUE 1
Research Article View: 1,025 Download: 291
Effects of Al2O3 Nano-Particulates Addition on Barium Titanate Ceramics
page: 175 - 182

Sukanda Jiansirisomboon*, Anucha Watcharapasorn and Tawee Tunkasiri

Vol.33 No.2 (MAY 2006)
Research Article View: 1,049 Download: 233
A Novel Method to Produce Silver Foams with Multilevel Porosities
page: 296 - 301

Seksak Asavavisithchai, Ekasit Nisaratanaporn, and Yuttanant Boonyongmaneerat

Vol.36 No.3 (SEPTEMBER 2009)
Research Article View: 1,027 Download: 238
Effects of Beryllium on Microstructure and Resiliency of Silver-Copper Alloy
page: 260 - 268

Torranin Chairuangsri, and Ekasit Nisaratanaporn

Vol.37 No.2 (MAY 2010)
Research Article View: 1,040 Download: 293
Outline
Figures