Submit your paper 
Download Template JOURNAL DETAIL
Conversion of Palm Oil into Biodiesel Production with Heterogeneous Catalyst Derived from Spent Coffee Grounds Ash: Process Optimization Through Response Surface Methodology
Paper Type  |
Contributed Paper |
Title |
Conversion of Palm Oil into Biodiesel Production with Heterogeneous Catalyst Derived from Spent Coffee Grounds Ash: Process Optimization Through Response Surface Methodology |
Author |
Jakkrapong Jitjamnong*, Natthida Numwong, Narinphop Chuaykarn, Chatrawee Direksilp, Apanee Luengnaruemitchai, Napaphat Kongrit and Nonlapan Khantikulanon |
Email |
alekjakkrapong@gmail.com |
|
Abstract: In the present study, the calcination of spent coffee grounds (SCG) supporting potassium hydroxide and potassium carbonate (K2CO3) was used as a novel solid heterogeneous catalyst to convert
palm oil to fatty acid methyl ester. The response surface method based on Box Behnken experimental
design was used to optimize the biodiesel yield. The prepared catalyst was characterized by scanning
electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS), Fourier-transform
infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS)
analyses. EDS analysis of the synthesis catalyst exhibited the presence of active potassium species for
high catalytic activity. The 30K/SCG–600 catalysts exhibited the highest catalytic activity and were rich
in K that formed a basic heterogeneous catalyst and the highest total basicity. The effects of catalyst
loading (4.5–5.5 wt.%), methanol to oil molar ratio (6:1–12:1), and reaction time (60–120 min) on the
transesterification were investigated. The results showed that the predicted optimum response for
biodiesel yield from RSM was 97.01%, which could be obtained using methanol: oil molar ratio of
6.68:1, catalyst loading of 4.94 wt.%, and reaction time at 82.42 min. The actual biodiesel conversion
of 97.08% was achieved under the predicted optimal conditions. The results of various statistics
employed with high R2 (95.07%) and R2adj (88.73%) values indicated that the predicted and actual
biodiesel yield was accurate and reliable. |
|
Start & End Page |
580 - 599 |
Received Date |
2020-04-09 |
Revised Date |
|
Accepted Date |
2020-10-21 |
Full Text |
Download |
Keyword |
spent coffee grounds, biodiesel, transesterification, heterogeneous catalyst, response surface methodology (RSM) |
Volume |
Vol.48 No.2 (March 2021) |
DOI |
|
Citation |
Jitjamnong* J., Numwong N., Chuaykarn N., Direksilp C., Luengnaruemitchai A., Kongrit N., et al., Conversion of Palm Oil into Biodiesel Production with Heterogeneous Catalyst Derived from Spent Coffee Grounds Ash: Process Optimization Through Response Surface Methodology, Chiang Mai Journal of Science, 2021; 48(2): 580-599. |
SDGs |
|
| View:771 Download:193 | |
RELATED ARTICLE
Dyeing Characteristics and Performance of Natural Dye derived from Spent Coffee Ground on Cotton, Silk and Nylon Fabrics using Eco-friendly Dyeing Process
Article ID: e2025002
Author:Jantip Setthayanond, Porntip Tooptompong, Potjanart Suwanruji and Panticha Srisuwan
Vol.52 No.1 (January 2025) View: 266 Download:116
Article ID: e2025002
Author:Jantip Setthayanond, Porntip Tooptompong, Potjanart Suwanruji and Panticha Srisuwan
Vol.52 No.1 (January 2025) View: 266 Download:116
Optimizing Process Parameters through Response Surface Methodology for Transesterification Using an Innovative Extruded Catalyst
Article ID: e2024046
Author:Jutaporn Chanathaworn and Sommai Saramath
Vol.51 No.3 (May 2024) View: 410 Download:239
Article ID: e2024046
Author:Jutaporn Chanathaworn and Sommai Saramath
Vol.51 No.3 (May 2024) View: 410 Download:239
Biodiesel Production from Waste Cooking Oil using Heterogeneous CaO/Zn Catalyst: Yield and Reusability Performance
Article ID: e2023070
Author:Nur Afiqah Ali and Nozieana Khairuddin
Vol.50 No.6 (November 2023) View: 542 Download:550
Article ID: e2023070
Author:Nur Afiqah Ali and Nozieana Khairuddin
Vol.50 No.6 (November 2023) View: 542 Download:550
Study the Stable Diatomite-supported Catalyst for Biodiesel Production
page: 1332 - 1343
Author:Wilasinee Kingkam, Kewalee Nilgumhang, Sasikarn Nuchdang, Bheechanat Duangdee, Vichai Puripunyavanich and Dussadee Rattanaphra
Vol.49 No.5 (September 2022) View: 1,041 Download:418
page: 1332 - 1343
Author:Wilasinee Kingkam, Kewalee Nilgumhang, Sasikarn Nuchdang, Bheechanat Duangdee, Vichai Puripunyavanich and Dussadee Rattanaphra
Vol.49 No.5 (September 2022) View: 1,041 Download:418
Optimization of Melt-mixing Transesterification of Polylactide by Polyethylene Glycol Employing Response Surface Methodology
page: 69 - 80
Author:Narisara Jaikaew, Rafael Auras and Pakorn Opaprakasit
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,250 Download:592
page: 69 - 80
Author:Narisara Jaikaew, Rafael Auras and Pakorn Opaprakasit
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,250 Download:592
Investigation of the Initiating and Catalytic Behavior of Tri-n-butyltin(IV) n-Butoxide in Ring-Opening Polymerization of ε-Caprolactone and Transesterification of Poly(L-lactic acid)
page: 27 - 38
Author:Winita Punyodom, Puttinan Meepowpan, Boontharika Thapsukhon, Manita Dumklang and Wanich Limwanich
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,356 Download:309
page: 27 - 38
Author:Winita Punyodom, Puttinan Meepowpan, Boontharika Thapsukhon, Manita Dumklang and Wanich Limwanich
Vol.49 No.1 (Special Issue I : Jan 2022) View: 1,356 Download:309
SDGs:
Acceleration of Acid-catalyzed Transesterification Reaction by Minimizing Glycerol to Fatty Acid Methyl Ester Ratio
page: 1381 - 1393
Author:Watcharin Rattanapong, Kulchanat Prasertsit and Chakrit Tongurai
Vol.48 No.5 (September 2021) View: 1,149 Download:295
page: 1381 - 1393
Author:Watcharin Rattanapong, Kulchanat Prasertsit and Chakrit Tongurai
Vol.48 No.5 (September 2021) View: 1,149 Download:295
Effect of Calcination Temperature of Musa sapientum Linn Peels as a Novel Biobased Heterogeneous Catalyst for Soybean Oil-derived Fatty Acid Methyl Ester Formation
page: 484 - 498
Author:Jakkrapong Jitjamnong, Chachchaya Thunyaratchatanon, Apanee Luengnaruemitchai, Napaphat Kongrit, Naparat Kasetsomboon, Narinphop Chuaykarn and Nonlapan Khantikulanon
Vol.47 No.3 (May 2020) View: 775 Download:592
page: 484 - 498
Author:Jakkrapong Jitjamnong, Chachchaya Thunyaratchatanon, Apanee Luengnaruemitchai, Napaphat Kongrit, Naparat Kasetsomboon, Narinphop Chuaykarn and Nonlapan Khantikulanon
Vol.47 No.3 (May 2020) View: 775 Download:592
Biodiesel Production from Canola Oil and Methanol Using Ba Impregnated Calcium Oxide with Microwave
Irradiation-Assistance
page: 987 - 1000
Author:Jakkrapong Jitjamnong*, Apanee Luengnaruemitchai, Napaphat Samanwonga and Narinphop Chuaykarn
Vol.46 No.5 (September 2019) View: 701 Download:330
page: 987 - 1000
Author:Jakkrapong Jitjamnong*, Apanee Luengnaruemitchai, Napaphat Samanwonga and Narinphop Chuaykarn
Vol.46 No.5 (September 2019) View: 701 Download:330
Optimization of Culture Conditions for Oil Production by the Double Mutant of Chlorella sorokiniana DMKU5202-D223
page: 1055 - 1068
Author:Mathurin Vichachucherd, Wichien Yongmanitchai and Duenrut Chonudomkul *
Vol.46 No.6 (November 2019) View: 1,134 Download:413
page: 1055 - 1068
Author:Mathurin Vichachucherd, Wichien Yongmanitchai and Duenrut Chonudomkul *
Vol.46 No.6 (November 2019) View: 1,134 Download:413
Optimization of Oleic Acid Esterification for Biodiesel Production using Brønsted Acidic Ionic Liquid as a Catalyst
page: 714 - 726
Author:Benyong Han, Fang Yin*, Shiqing Liu, Xingling Zhao, Jing Liu, Changmei Wang, Hong Yang, Wudi Zhang*
Vol.46 No.4 (July 2019) View: 719 Download:369
page: 714 - 726
Author:Benyong Han, Fang Yin*, Shiqing Liu, Xingling Zhao, Jing Liu, Changmei Wang, Hong Yang, Wudi Zhang*
Vol.46 No.4 (July 2019) View: 719 Download:369
Bioconversion of Crude Glycerol into 1,3-propanediol by an Anaerobic Mixed Microbial Consortium
page: 1 - 14
Author:Sureewan Sittijunda and Alissara Reungsang
Vol.46 No.1 (January 2019) View: 685 Download:247
page: 1 - 14
Author:Sureewan Sittijunda and Alissara Reungsang
Vol.46 No.1 (January 2019) View: 685 Download:247
Enhancement of Biomass, Lipid and Hydrocarbon Production from Green Microalga, Botryococcus braunii AARL G037, by UV-C Induction
page: 2637 - 2651
Author:Theera Thurakit, Chayakorn Pumas, Wasu Pathom-aree, Jeeraporn Pekkoh and Yuwadee Peerapornpisal
Vol.45 NO.7 (November 2018) View: 1,261 Download:292
page: 2637 - 2651
Author:Theera Thurakit, Chayakorn Pumas, Wasu Pathom-aree, Jeeraporn Pekkoh and Yuwadee Peerapornpisal
Vol.45 NO.7 (November 2018) View: 1,261 Download:292
Synthesis and Characterization of Biolubricant from POME Oil and Hepatopancreas Lipase from Pacific White Shrimp (Litopenaeus vannamei)
page: 2438 - 2453
Author:Thanaphorn Rakkan, Nisa Paichid, Tewan Yunu, Sappasith Klomklao and Kanokphorn Sangkharak
Vol.45 No.6 (September 2018) View: 1,179 Download:350
page: 2438 - 2453
Author:Thanaphorn Rakkan, Nisa Paichid, Tewan Yunu, Sappasith Klomklao and Kanokphorn Sangkharak
Vol.45 No.6 (September 2018) View: 1,179 Download:350
Efficient Conversion of Oils to Biodiesel Catalyzed by Uncalcined Disodium Metasilicate Granules
page: 1888 - 1900
Author:Wuttichai Roschat, Mattana Kacha, Boonyawan Yoosuk, Preecha Moonsin, Taweesak Sudyoadsuk and Vinich Promarak
Vol.45 No.4 (July 2018) View: 761 Download:221
page: 1888 - 1900
Author:Wuttichai Roschat, Mattana Kacha, Boonyawan Yoosuk, Preecha Moonsin, Taweesak Sudyoadsuk and Vinich Promarak
Vol.45 No.4 (July 2018) View: 761 Download:221
Utilization of Agro-waste and Non-conventional Eruca sativa Seed Oil for Getting Optimized Process to Acquire Better Yield of Biodiesel by Using Response Surface Methodology (RSM)
page: 1507 - 1518
Author:Tahir Mehmood*, Sadia Fareed, Mudassir Iqbal, Adeela Naseem and Faiza Siddique
Vol.45 No.3 (May 2018) View: 667 Download:222
page: 1507 - 1518
Author:Tahir Mehmood*, Sadia Fareed, Mudassir Iqbal, Adeela Naseem and Faiza Siddique
Vol.45 No.3 (May 2018) View: 667 Download:222
The Study of Activity and Selectivity of Calcium Oxide Nanocatalyst for Transesterification of High Free Fatty Acid Crude Palm Oil
page: 973 - 983
Author:Rattana Thaoklua, Jaroon Janjaroen and Karaked Tedsree*
Vol.45 No.2 (March 2018) View: 662 Download:328
page: 973 - 983
Author:Rattana Thaoklua, Jaroon Janjaroen and Karaked Tedsree*
Vol.45 No.2 (March 2018) View: 662 Download:328
Production of Whole-cell Lipase from Aspergillus nomius ST57 and Optimization of Methyl Esters Synthesis from Palm Oil in One Step
page: 746 - 761
Author:Naruemon Rakchai, Aran H-Kittikun* and Wolfgang Zimmermann
Vol.45 No.2 (March 2018) View: 1,157 Download:191
page: 746 - 761
Author:Naruemon Rakchai, Aran H-Kittikun* and Wolfgang Zimmermann
Vol.45 No.2 (March 2018) View: 1,157 Download:191
1, 3-Propanediol Production from Crude Glycerol by Klebsiella pneumoniae
page: 718 - 725
Author:Jiaxin Wu*[a], Fenghuan Wang[b], Zheng Wang[b], Hua Ye[c] and Peiyi Liu[d]
Vol.43 No.4 (JULY 2016) View: 654 Download:226
page: 718 - 725
Author:Jiaxin Wu*[a], Fenghuan Wang[b], Zheng Wang[b], Hua Ye[c] and Peiyi Liu[d]
Vol.43 No.4 (JULY 2016) View: 654 Download:226
Assessment of genetic diversity of Jatropha curcas L. using AFLP and ISSR markers
page: 614 - 625
Author:Sirisak Soonthornyatara, Prapa Sripichitt, Rugsarit Kaveeta and Vipa Hongtrakul
Vol.42 No.3 (JULY 2015) View: 1,014 Download:217
page: 614 - 625
Author:Sirisak Soonthornyatara, Prapa Sripichitt, Rugsarit Kaveeta and Vipa Hongtrakul
Vol.42 No.3 (JULY 2015) View: 1,014 Download:217
β-Carotene Production by Sporobolomyces pararoseus TISTR5213 Using Crude Glycerol as the Sole Carbon Source
page: 17 - 33
Author:Atchara Manowattana [a], Charin Techapun [b], Phisit Seesuriyachan [b], Prasert Hanmoungjai [b] and
Vol.42 No.1 (JANUARY 2015) View: 652 Download:173
page: 17 - 33
Author:Atchara Manowattana [a], Charin Techapun [b], Phisit Seesuriyachan [b], Prasert Hanmoungjai [b] and
Vol.42 No.1 (JANUARY 2015) View: 652 Download:173
Preparing Activated Carbon from Palm Shell for Biodiesel Fuel Production
page: 572 - 578
Author:Achanai Buasri, Nattawut Chaiyut and Chaiwut Nakweang
Vol.38 No.4 (OCTOBER 2011) View: 632 Download:299
page: 572 - 578
Author:Achanai Buasri, Nattawut Chaiyut and Chaiwut Nakweang
Vol.38 No.4 (OCTOBER 2011) View: 632 Download:299
Biodiesel Synthesis from Transesterification by
Clay-based Catalyst
page: 201 - 207
Author:Manut Jaimasith and Satit Phiyanalinmat
Vol.34 No.2 (MAY 2007) View: 688 Download:205
page: 201 - 207
Author:Manut Jaimasith and Satit Phiyanalinmat
Vol.34 No.2 (MAY 2007) View: 688 Download:205
Production Methyl Esters from Palm Fatty Acids in
Supercritical Methanol
page: 23 - 28
Author:Duangkamol Yujaroen, Artiwan Shotipruk, Motonobu Goto and Mitsuru Sasaki
Vol.35 No.1 (JANUARY 2008) View: 697 Download:215
page: 23 - 28
Author:Duangkamol Yujaroen, Artiwan Shotipruk, Motonobu Goto and Mitsuru Sasaki
Vol.35 No.1 (JANUARY 2008) View: 697 Download:215
Copyrights © Since 2021 All Rights Reserved by Chiang Mai Journal of Science