Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

1,647
Articles
Q3 0.80
Impact Factor
Q3 1.3
CiteScore
7 days
Avg. First Decision
Outline
Figures and Tables
ARTICLE METRICS
Views 1,262
Downloads 651

Optimization of Methyl Oleate Synthesis with Sulfonated Pyrrolidonium Ionic Liquids as Catalysts Using the Response Surface Methodology

Yujie ChenYang, Rui Cai, Kun Yang and Benyong Han
* Author for corresponding; e-mail address: xmcx668@126.com
Volume: Vol.51 No.2 (March 2024)
Research Article
DOI: https://doi.org/10.12982/CMJS.2024.030
Received: 22 May 2023, Revised: 25 January 2024, Accepted: 16 Febuary 2024, Published: -

Citation: ChenYang Y., Cai R., Yang K. and Han B., Optimization of methyl oleate synthesis with sulfonated pyrrolidonium ionic liquids as catalysts using the response surface methodology, Chiang Mai Journal of Science, 2024; 51(2): e2024030. DOI 10.12982/CMJS.2024.030.

Abstract

     In order to improve the efficiency of biodiesel production from esterification of free fatty acids, an alternative to sulfuric acid has been explored in this study. These catalysts including three pyrrolidonium ionic liquids (ILs), 1-methyl-2-pyrrolidonium hydrogen sulfate ([Hnmp]HSO4), 2-pyrrolidonium hydrogen sulfate ([Hnhp]HSO4), and 1-(3-sulfonic acid) propyl-2-pyrrolidonium hydrogen sulfate ([C3SO3Hnhp]HSO4), were applied as catalysts to produce biodiesel through the esterification reaction of oleic acid with methanol. The catalytic performances of the synthesized ILs for the esterification of oleic acid were evaluated, and [C3SO3Hnhp]HSO4 exhibited the best catalytic activity among all tested acidic ILs. Moreover, the esterification of oleic acid with methanol by the [C3SO3Hnhp]HSO4-catalyzed was systematically explored, and the reaction conditions were further optimized through a single-factor experiment, the Plackett-Burman design, and a response surface methodology. It was found that optimum response for oleic acid conversion was 97.4% under reaction condition of using catalyst dosage of 12.5%, methanol/oleic acid molar ratio of 9:1, reaction time at 4 h and reaction temperature at 70 °C. In addition, the catalytic activity of [C3SO3Hnhp]HSO4 still remained high level after 5 cycles. In a conclusion, the IL [C3SO3Hnhp]HSO4 has great potential as a catalyst for producing fatty acid methyl esters via the esterification reaction.

Keywords: ionic liquid, [C3SO3Hnhp]HSO4, oleic acid conversion, response surface methodology

Related Articles

Improving Weld Strength In Friction Stir Welding Of Dissimilar Aluminium Alloys By In Line Cooling
DOI: 10.12982/CMJS.2025.024.

Thalaieswaran Selvam and Ayyappan Solaiyappan

Vol.52 No.3 (May 2025)
Research Article View: 1,024 Download: 420
Performance Evaluation of Forward Osmosis Membranes for Desalination Applications
DOI: 10.12982/CMJS.2024.026.

Mohd Amirul Mukmin Abdullah, Nur Aisyah Shafie, Mazrul Nizam Abu Seman and Syamsul B. Abdullah

Vol.51 No.2 (March 2024)
Research Article View: 1,471 Download: 729
Development of Instant Beverage Powder Based on Sacha Inchi
DOI: 10.12982/CMJS.2024.017.

Sunee Eadmusik, Sabaipear Thongprathuang, Tanimas Luekhuntod, Pimrajika Didbunjong and Chanthima Phungamngoen

Vol.51 No.1 (January 2024)
Research Article View: 6,709 Download: 1,099
Effects of Sodium Nitrite, Potassium Sorbate and α-Tocopherol on Residual Nitrite, Formations of Biogenic Amines and N-Nitrosamines in Turkish Dry Fermented Sausage (Sucuk)
DOI: 10.12982/CMJS.2024.006.

Bıçakcı Gülsüme and Eren Ömer

Vol.51 No.1 (January 2024)
Research Article View: 1,638 Download: 754
Investigation and Desirability Function Analysis for Optimization of Welding Process Parameters For Friction Stir Welding of Aluminium Metal Matrix Composite
DOI: 10.12982/CMJS.2022.089.

Seenivasan Murugesan, Kathiravan Nanjundan, Santhanakrishnan Raman and Ganesan Thirumalai

Vol.49 No.5 (September 2022)
Research Article View: 1,523 Download: 456
Assessment of Optimum Mechanical Properties for Friction Stir Welding of Pure Copper and Aluminium Bronze
DOI: 10.12982/CMJS.2022.059.

Ajaymanikandan Nagalingam, Ilamathi Palanivel and Thirumalai Ramanathan

Vol.49 No.4 (July 2022)
Research Article View: 4,941 Download: 502
Conversion of Palm Oil into Biodiesel Production with Heterogeneous Catalyst Derived from Spent Coffee Grounds Ash: Process Optimization Through Response Surface Methodology
page: 580 - 599

Jakkrapong Jitjamnong*, Natthida Numwong, Narinphop Chuaykarn, Chatrawee Direksilp, Apanee Luengnaruemitchai, Napaphat Kongrit and Nonlapan Khantikulanon

Vol.48 No.2 (March 2021)
Research Article View: 1,218 Download: 194
Optimization of Corilagin and Geraniin Extraction from Phyllanthus urinaria L. by Response Surface Methodology
page: 513 - 529

Qin Ou-Yang, Hui-Ling Yang and Wei Zhu

Vol.47 No.3 (May 2020)
Research Article View: 1,038 Download: 615
Multi-response Optimization of Ultrasonic Assisted Enzymatic Extraction of Antioxidant Polysaccharides from Waste Ginkgo biloba Sarcotesta
page: 499 - 512

Gui-Sheng Zhou, Yu-Ping Tang, Yao Li and Jin-Ao Duan

Vol.47 No.3 (May 2020)
Research Article View: 1,211 Download: 2,104
Optimization of Culture Conditions for Xylanase Production from Cellulase-free Xylanase-producing Thermophilic Fungus, Thermomyces dupontii KKU−CLD−E2−3
page: 391 - 402

Wasan Seemakram, Santhaya Boonrung, Urachart Kokaew, Tadanori Aimi and Sophon Boonlue

Vol.47 No.3 (May 2020)
Research Article View: 1,275 Download: 785
Optimization of Oleic Acid Esterification for Biodiesel Production using Brønsted Acidic Ionic Liquid as a Catalyst
page: 714 - 726

Benyong Han, Fang Yin*, Shiqing Liu, Xingling Zhao, Jing Liu, Changmei Wang, Hong Yang, Wudi Zhang*

Vol.46 No.4 (July 2019)
Research Article View: 1,033 Download: 636
Solid Phase-assisted Determination of trace Copper(ll) and Iron(lll) in Food and Water Samples by Cloud Point Extraction: Response Surface Methodology Optimization
page: 1960 - 1974

Farzin Nekouei and Shahram Nekouei

Vol.45 No.4 (July 2018)
Research Article View: 1,057 Download: 307
The Catalytic Investigation of Supported Imidazolium-chloroaluminate (AlCl3-lLs) in Friedel-Craft Acylation of Anisole
page: 1953 - 1959

Thiti Junpirom, Praput Thavornyutikarn and Puttinan Meepowpan

Vol.45 No.4 (July 2018)
Research Article View: 943 Download: 633
Utilization of Agro-waste and Non-conventional Eruca sativa Seed Oil for Getting Optimized Process to Acquire Better Yield of Biodiesel by Using Response Surface Methodology (RSM)
page: 1507 - 1518

Tahir Mehmood*, Sadia Fareed, Mudassir Iqbal, Adeela Naseem and Faiza Siddique

Vol.45 No.3 (May 2018)
Research Article View: 1,055 Download: 298
Synthesis Study of High Oleic Palm Oil-based Trimethylolpropane Triesters: Response Surface Methodology Based Optimization
page: 984 - 996

Hamidah Abd Hamid, Robiah Yunus*, Umer Rashid, Thomas S.Y. Choong, Salmiaton Ali and Azhari Muhammad Syam

Vol.45 No.2 (March 2018)
Research Article View: 1,030 Download: 604
Biohydrogen Production from Crude Glycerol Using Anaerobic Mixed Cultures: Media Compositions Optimization
page: 653 - 667

Sureewan Sittijunda and Alissara Reungsang*

Vol.45 No.2 (March 2018)
Research Article View: 1,067 Download: 361
Greener, Rapid and Reliable UHPLC using 1-alkyl-3-methylimidazolium-based Ionic Liquids as the Mobile Phase Additives for Simultaneous Determination of Steroids and Antihistamines Residues in Herbal Medicines
page: 380 - 403

Krittaya Nusai and Prayong Doungdee

Vol.45 No.1 (January 2018)
Research Article View: 976 Download: 364
Enhanced Production of Cordycepin by Solid State Fermentation of Cordyceps militaris using Additives
page: 972 - 984

Ting-Chi Wen [a]+, Chao Kang [b]+, Ze-Bing Meng [a], Yong-Bin Qi [a], Kevin D. Hyde [c, d] and Ji-Chuan Kang* [a]

Vol.43 No.5 (OCTOBER 2016)
Research Article View: 1,291 Download: 312
Application of Ultrasonic Assisted Extraction of Bioactive Compounds from the Fruits of Antidesma puncticulatum Miq. and Evaluation of Its Antityrosinase Activity
page: 519 - 534

Bancha Yingngam, Marlene Monschein and Adelheid H. Brantner *

Vol.43 No.3 (APRIL 2016)
Research Article View: 1,315 Download: 448
Analysis of Chitin, Chitosan, and Optimization for Carotenoids Extraction Yield with Rice Bran Oil from Thai Fairy Shrimp
page: 918 - 929

Tanyarat Poothawan and Khomsorn Lomthaisong

Vol.42 No.4 (OCTOBER 2015)
Research Article View: 1,001 Download: 408
Statistical Optimization for the Production of D-Mannose Isomerase by Saccharothrix sp. CMU-K747 Using Response Surface Methodology
page: 52 - 61

ApiradeeSiangsuepchart [a] and SaisamornLumyong*[a, b]

Vol.42 No.1 (JANUARY 2015)
Research Article View: 1,021 Download: 315
One-pot Green Procedure for the Mannich Reaction Catalyzed by a Task-specific Ionic Liquid
page: 49 - 58

Guozheng Zhao and Ming Lu

Vol.39 No.1 (JANUARY 2012)
Research Article View: 935 Download: 611
Non-chloroaluminate lonic Liquids Supported the Synthesis of Substisuted Imidazoles using Microwave Irradiation
page: 601 - 607

Xiaobing Liu, Ming Lu and Yu Wang

Vol.38 No.4 (OCTOBER 2011)
Research Article View: 904 Download: 281
An Efficient Protocol for the Synthesis of3,4-Dihydropyrimidine-2-(1H)-ones Catalyzed byFunctionalized Ionic Liquid [DDPA][HSO4]
page: 263 - 269

Xiaobing Liu, Ming Lu and Tingting Lu

Vol.38 No.2 (APRIL 2011)
Research Article View: 1,108 Download: 1,526
Retention Behavior of Aromatic Amines with Some Ionic Liquids Mobile Phase in Semi-micro HPLC
page: 384 - 396

Yuppadee Nusai, Hitoshi Koizumi, Masaki Tachibana, Kazue Tani, and Nobutoshi Kiba

Vol.37 No.3 (SEPTEMBER 2010)
Research Article View: 979 Download: 303
Outline
Figures