Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

1,647
Articles
Q3 0.80
Impact Factor
Q3 1.3
CiteScore
7 days
Avg. First Decision
Outline
Figures and Tables
ARTICLE METRICS
Views 649
Downloads 298

Catalytic Degradation Performance of Manganese-Zinc Ferrite Nanoparticles Coated With Eggshell-Derived Calcium Oxide For Rhodamine B Removal

Walaa Alharbi, Khadija Alharbi, Abdullah Alotaibi and Sami Abdel Azeem
* Author for corresponding; e-mail address: sami_a@su.edu.sa, sma13@fayoum.edu.eg
Volume: Vol.52 No.1 (January 2025)
Research Article
DOI: https://doi.org/10.12982/CMJS.2025.006
Received: 27 Febuary 2024, Revised: 25 November 2024, Accepted: 15 December 2024, Published: 29 January 2025

Citation: Alharbi W., Alharbi K., Alotaibi A. and Azeem S.A., Catalytic degradation performance of manganese-zinc ferrite nanoparticles coated with eggshell-derived calcium oxide for rhodamine B removal. Chiang Mai Journal of Science, 2025; 52(1): e2025006. DOI 10.12982/CMJS.2025.006.

Abstract

     Low-cost natural materials-mediated adsorbents for the removal of dye pollutants from water are gaining popularity over chemical adsorbents due to their eco-friendliness, widespread availability, and ease of manufacture. A CaO-derived from eggshell was used to alter the surface of zinc-manganese-ferrite (Zn0.6Mn0.4Fe2O4) nanoparticles by the post-precipitation method. The CaO/Zn0.6Mn0.4Fe2O4 nanocomposite was studied using FT-IR , XRD and SEM, and utilized for the removal of Rhodamine B dye. The adsorption efficiency of 10 mg L-1 RhB reached 75% at pH 4.0, 60 min of shaking, and 2.0 g L-1 of adsorbent. The intra-particle diffusion process was a rate-limiting phase, and the results matched the pseudo-second-order kinetics model. Adsorption data were well-fitting by the Langmuir isotherm model, with R2=0.989, KL =0.232, and maximal monolayer capacity (qmax) of 30.7mg.g-1.The Tempkin isotherm revealed that the lateral repulsive forces are non-significant. The D-R model revealed positive adsorption-free energy confirming an endothermic chemical adsorption process. The Fenton-like catalytic degradation showed a removal of 98% at 80 min and increased by increasing the TDS of the medium.

Keywords: eggshell-CaO, Manganese-zinc-ferrite, removal, Rhodamine B

Related Articles

A Rhizobacterium Kitasatospora nipponensis Demonstrates Antifungal Activity against Basal Stem Rot Disease and Promotes Plant Growth in Oil Palm (Elaeis guineensis) Seedlings
DOI: 10.12982/CMJS.2025.033.

Anurag Sunpapao, Supaporn Pithakkit and Prisana Wonglom

Vol.52 No.3 (May 2025)
Research Article View: 798 Download: 334
Assessment of Cationic Salts and Inorganic Acids as Washing Agents for Cs-137 Removal from Radioactively Contaminated Electric Arc Furnace Dust
DOI: 10.12982/CMJS.2024.108.

Thunyaras Akharawutchayanon, Pichittra Thawong, Poonnaphob Sopapan, Klitsadee Yubonmhat, Sudarat Issarapanacheewin, Kewalee Nilgumhang, Nikom Prasertchiewchan and Witsanu Katekaew

Vol.51 No.6 (November 2024)
Research Article View: 829 Download: 230
Isolation and Identification of Lipase-producing Bacteria from Wastewater Treatment Pond for the Removal of Oil and Grease in Wastewater Treatment
DOI: 10.12982/CMJS.2024.096.

Ganogwan Sukplang, Chaiyanut Narasettiti, Orawan Chunhachart, Moltira Srithaworn, Wanlapa Lorliam, Sukhumaporn Krajangsang and Titiporn Panyachanakul

Vol.51 No.6 (November 2024)
Research Article View: 957 Download: 1,028
Reduction of the Low Zinc-containing EAF Dust and Coke
DOI: 10.12982/CMJS.2024.082.

Anh-Hoa Bui, Thi-Ha Nguyen, Cao-Son Nguyen and Youn-Bae Kang

Vol.51 No.5 (September 2024)
Research Article View: 786 Download: 498
Preparation of Porous Silica Nanoparticles by Chemical Etching for Removal of Paraquat from Aqueous Solution
DOI: 10.12982/CMJS.2023.009.

Kanokwan Darasoon, Supawitch Hoijang, Tanapong Kunakham, Sorapong Janhom, Supon Ananta, Gyu Leem and Laongnuan Srisombat

Vol.50 No.1 (January 2023)
Research Article View: 1,625 Download: 1,187
Sorption Studies of Cesium on Kunipia-F Bentonite and Silicon Dioxide
DOI: 10.12982/CMJS.2022.093.

Anan O-Manee, Youichi Enokida and Kayo Sawada

Vol.49 No.5 (September 2022)
Research Article View: 1,625 Download: 637
Acceleration of Acid-catalyzed Transesterification Reaction by Minimizing Glycerol to Fatty Acid Methyl Ester Ratio
page: 1381 - 1393

Watcharin Rattanapong, Kulchanat Prasertsit and Chakrit Tongurai

Vol.48 No.5 (September 2021)
Research Article View: 1,440 Download: 571
Adsorptive Removal of Malachite Green from Aqueous Solution over Graphite-layered Double Hydroxides Composite
page: 1351 - 1362

Neza Rahayu Palapa, Tarmizi Taher, Shahibul Fajri and Aldes Lesbani

Vol.48 No.5 (September 2021)
Research Article View: 1,577 Download: 1,085
Hydrogen Sulfide Removal from Biogas Using Immobilized Sulfur Oxidizing Bacterium Paracoccus versutus CM1 in Biofilters
page: 872 - 886

Dolruedee Jirachaisakdeacha, Ladapa Kumdhitiahutsawakul, Patiroop Pholchan, Uthen Kantha, Wasu Pathom-aree and Sakunnee Bovonsombut

Vol.47 No.5 (September 2020)
Research Article View: 1,107 Download: 809
Factors Affecting Phytoplankton Removal by Electro-Oxidation of Artificial Seawater
page: 255 - 259

Niwooti Whangchai*, Nakao Nomura and Masatoshi Matsumura

Vol.30 No.3 (DECEMBER 2003)
Research Article View: 861 Download: 259
Decolorization of Methylene Blue Solution by Electrocoagulation Using Aluminum Electrodes
page: 2238 - 2243

Waraporn Pantorlao, Duangdao Channei, Wilawan Khanitchaidecha and Auppatham Nakaruk

Vol.45 No.5 (Special 2018)
Research Article View: 965 Download: 408
Removal of Pb2+ Ion from Industrial Wastewater by New Efficient Biosorbents of Oyster Plant (Tradescantia spathacea Steam) and Negkassar Leaf (Mammea siamensis T. Anderson)
page: 369 - 379

Kannika Keawkim and Achjana Khamthip

Vol.45 No.1 (January 2018)
Research Article View: 894 Download: 357
Agrowaste Based Ecofriendly Bio-adsorbent for the Removal of Phenol: Adsorption and Kinetic Study by Acacia Tortilis Pod Shell
page: 355 - 368

Mohammad Malakootian, Amir Hossein Mahvi, Hossein Jafari Mansoorian and Narges Khanjani

Vol.45 No.1 (January 2018)
Research Article View: 1,486 Download: 411
Nitrogen Removal Efficiency of Salt-tolerant Heterotrophic Nitrifying Bacteria
page: 11 - 20

Sunipa Chankaew, Sompong O-Thong and Yutthapong Sangnoi

Vol.45 No.1 (January 2018)
Research Article View: 1,054 Download: 699
Pt/Al2O3Catalyzed Decolorization of Rhodamine B Dye in Aqueous Medium
page: 730 - 744

Muhammad Saeed, Shahid Adeel, Muhammad Azhar Shahzad, Atta Ul-Haq, Majid Muneer, Muhammad Younas

Vol.42 No.3 (JULY 2015)
Research Article View: 1,439 Download: 293
Removal of Methylene Blue from Aqueous Solution by Coffee Residues
page: 407 - 416

Walaikorn Nitayaphat, Thanut Jintakosol, Kamontip Engkaseth and Yada Wanrakakit

Vol.42 No.2 (APRIL 2015)
Research Article View: 1,238 Download: 330
Culturable Bacterial Community in a High Temperature EBPR Reactor
page: 970 - 980

Ying Hui Ong 1a, Adeline Seak May Chua 2a*, Geok Yuan Annie Tan3b, and Gek Cheng Ngoh 4a

Vol.41 No.5/1 (OCTOBER 2014)
Research Article View: 1,006 Download: 383
Modeling and Optimization of Removal of Rhodamine – B from Wastewaters by Adsorption on Modified Clay
page: 1230 - 1240

Morteza Bahram, Robabeh Talebi, Abdolhossein Naseri* , Sirous Nouri

Vol.41 No.5/2 (OCTOBER 2014)
Research Article View: 1,388 Download: 519
Adsorption Equilibrium of Zinc Ions from Aqueous Solution by Using Modified Clinoptilolite
page: 56 - 62

Achanai Buasri, Phetcharat Yongbut, Nattawut Chaiyut and Kittiya Phattarasirichot

Vol.35 No.1 (JANUARY 2008)
Research Article View: 1,414 Download: 337
Outline
Figures