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Synthesis of (+/-) 3-Acetoxy-2-methylene-4-cyclopentenone, Pentenomycin II and Epipentenomycin II Precursors


Paper Type 
 Contributed Paper
Title 
 Synthesis of (+/-) 3-Acetoxy-2-methylene-4-cyclopentenone, Pentenomycin II and Epipentenomycin II Precursors
Author 
 Theeraphan Machan and Apiwat Baramee*
Email 
 chlapiba@science.cmu.ac.th
Abstract:
 A two steps synthesis of (+) 3-acetoxy-2-methylene-4-cyclopentenone was achieved, starting from epoxy-2-methylenecyclopentanone anthracene adduct. The key reaction involved flash vacuum pyrolysis of epoxy-2-methylenecyclopentanone anthracene adduct and acetylation of the resulting product.
Start & End Page 
 41 - 45
Received Date 
 2002-11-27
Revised Date 
Accepted Date 
 2003-03-19
Full Text 
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Keyword 
 cyclopentenones, pentenomycin, epipentenomycin, synthesis
Volume 
 Vol.30 No.1 (APRIL 2003)
DOI 
Citation 
 Machan T. and Baramee* A., Synthesis of (+/-) 3-Acetoxy-2-methylene-4-cyclopentenone, Pentenomycin II and Epipentenomycin II Precursors, Chiang Mai Journal of Science, 2003; 30(1): 41-45.
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