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Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
Paper Type  |
Contributed Paper |
Title |
Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate |
Author |
Mohammad Alikarami*[a] Somaye Mohammadnezhad[b] and Zahra Abbasi[c] |
Email |
alikarami58@yahoo.com |
|
Abstract: The reaction of 1,4-dibenzyl-1,4-diabicyclo [2.2.2] octane dichloroiodate (DBDDCI) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols or H2O/CH3CN (1:1)) in mild and under catalyst free condition at room temperature led to the corresponding β-iodoethers and iodohydrines in good to excellent yield. |
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Start & End Page |
957 - 962 |
Received Date |
2013-12-18 |
Revised Date |
|
Accepted Date |
2014-09-18 |
Full Text |
Download |
Keyword |
1,4-dibenzyl-1, 4-diazabicyclo[2.2.2]octane dichloroiodate, co-iodination, iodohydrines, , β-iodoethers, catalyst free |
Volume |
Vol.42 No.4 (OCTOBER 2015) |
DOI |
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Citation |
Mohammadnezhad M.A.S. and Abbasi Z., Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate, Chiang Mai J. Sci., 2015; 42(4): 957-962. |
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