Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
Mohammad Alikarami*[a] Somaye Mohammadnezhad[b] and Zahra Abbasi[c]* Author for corresponding; e-mail address: alikarami58@yahoo.com
Volume: Vol.42 No.4 (OCTOBER 2015)
Research Article
DOI:
Received: 18 December 2013, Revised: -, Accepted: 18 September 2014, Published: -
Citation: Mohammadnezhad M.A.S. and Abbasi Z., Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate, Chiang Mai Journal of Science, 2015; 42(4): 957-962.
Abstract
The reaction of 1,4-dibenzyl-1,4-diabicyclo [2.2.2] octane dichloroiodate (DBDDCI) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols or H2O/CH3CN (1:1)) in mild and under catalyst free condition at room temperature led to the corresponding β-iodoethers and iodohydrines in good to excellent yield.