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Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate


Paper Type 
Contributed Paper
Title 
Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
Author 
Mohammad Alikarami*[a] Somaye Mohammadnezhad[b] and Zahra Abbasi[c]
Email 
alikarami58@yahoo.com
Abstract:

 The reaction of 1,4-dibenzyl-1,4-diabicyclo [2.2.2] octane dichloroiodate (DBDDCI) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols or  H2O/CH3CN (1:1)) in mild and under catalyst free condition at room temperature led to the corresponding β-iodoethers and iodohydrines in good to excellent yield.

Start & End Page 
957 - 962
Received Date 
2013-12-18
Revised Date 
Accepted Date 
2014-09-18
Full Text 
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Keyword 
1,4-dibenzyl-1, 4-diazabicyclo[2.2.2]octane dichloroiodate, co-iodination, iodohydrines, , β-iodoethers, catalyst free
Volume 
Vol.42 No.4 (OCTOBER 2015)
DOI 
SDGs
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Chiang Mai Journal of Science

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