Synthesis and Characterization of Dioxo-molybdenum (VI) Complexes of Some Dithiocarbamates.
Didarul A. Chowdhury, Mohammad N. Uddin* and Abul K.M. L. Rahman* Author for corresponding; e-mail address: nasiru_cu@yahoo.com
Volume: Vol.33 No.3 (SEPTEMBER 2006)
Research Article
DOI:
Received: 15 July 2005, Revised: -, Accepted: 10 Febuary 2006, Published: -
Citation: Chowdhury D.A., Uddin M.N. and Rahman A.K.L., Synthesis and Characterization of Dioxo-molybdenum (VI) Complexes of Some Dithiocarbamates., Chiang Mai Journal of Science, 2006; 33(3): 357-362.
Abstract
Some Dioxo-molybdenum(VI) complexes of the type MoO2(dtc)2 have been prepared (where dtcH = is the uninegatively charged bidentate ligand of diamine-monodithiocarbamate). The prepared complexes are characterized by various physicochemical techniques. On the basis of analytical data, molar conductance, magnetic and spectral studies the molecular formula and structure of the complexes have been elucidated. Distorted octahedral geometry was proposed where oxygen atoms are in cis-position.