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Crosslinking Effects on Alginate/Carboxymethyl Cellulose Packaging Film Properties


Paper Type 
Contributed Paper
Title 
Crosslinking Effects on Alginate/Carboxymethyl Cellulose Packaging Film Properties
Author 
Nattapong Pinpru, Somsak Woramongkolchai*
Email 
kwosomsa@gmail.com
Abstract:
We measured the effect of crosslinking with Ba2+, Ca2+ and Zn2+ ions to sodium alginate (SA)
mixed with carboxymethyl cellulose (CMC) film, prepared by solution casting. Although heavy metal
ion crosslinked films had higher tensile strengths than neat SA/CMC films, the elongation at break,
light transmission and swelling had decreased. In crosslinked films, film thickness and thermal stability
also increased. Crosslinking with Ca2+ ion showed the optimum film properties. The effect of Ca2+ ion
concentration between 1 to 4% w/v of CaCl2 to SA/CMC film properties were further investigated.
The 2% w/v of CaCl2 had dominated the highest tensile strength compared to 3% and 4% w/v of
CaCl2. Light transmission, thickness and thermal stability were not affected. In conclusion, the 2%
w/v CaCl2 is the appropriated concentration for film preparation in packaging industry.
Start & End Page 
712 - 722
Received Date 
2019-07-24
Revised Date 
Accepted Date 
2020-04-20
Full Text 
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Keyword 
bio-film, sodium alginate, carboxymethyl cellulose, ionic crosslinking
Volume 
Vol.47 No.4 (Special Issue II : July 2020)
DOI 
Citation 
Pinpru N. and Woramongkolchai S., Crosslinking Effects on Alginate/Carboxymethyl Cellulose Packaging Film Properties, Chiang Mai J. Sci., 2020; 47(4): 712-722.
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