Chiang Mai Journal of Science

Print ISSN: 0125-2526 | eISSN : 2465-3845

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Synthesis of 6/8-Methyl-2-(piperidin-1-yl)quinoline-3-carbaldehydes: A Facile CTAB Catalyzed Protocol

Rubina Munir, Muhammad Makshoof Atha, Muhammad Zia-ur-Rehman and Noman Javid
* Author for corresponding; e-mail address: organist94@gmail.com
Volume: Vol.47 No.1 (January 2020)
Research Article
DOI:
Received: 23 July 2019, Revised: -, Accepted: 20 September 2019, Published: -

Citation: Munir R., Atha M.M., Zia-ur-rehman M. and Javid N., Synthesis of 6/8-Methyl-2-(piperidin-1-yl)quinoline-3-carbaldehydes: A Facile CTAB Catalyzed Protocol, Chiang Mai Journal of Science, 2020; 47(1): 175-180.

Abstract

 An efficient method for nucleophilic aromatic substitution of 2-chloroquinoline-3-carbaldehydes is described for the synthesis of 6/8-methyl-2-(piperidin-1-yl)quinoline-3-carbaldehydes. The protocol involves the effective use of phase transfer catalyst CTAB in combination with polyethyleneglycol-400 to obtain the desired products in less reaction time. The newly developed method is found superior to the previously reported methods due to easy work up and excellent yields.

Keywords: quinoline, nucleophilic aromatic substitution, phase transfer catalyst, CTAB, piperidine

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